Lead toxicity has hindered the wide applications of lead halide perovskites in optoelectronics and bioimaging. A significant amount of effort has been made to synthesize lead-free halide perovskites as alternatives to lead halide perovskites. In this work, we demonstrate the feasibility of synthesizing CsSnI-based powders mechanochemically with dual light emissions under ambient conditions from CsI and SnI powders.
View Article and Find Full Text PDFBlue emitting Sn-based lead-free halide perovskite nanocrystals (NCs) are considered to be a promising material in lighting and displays. However, industrialised fabrication of blue-emitting NCs still remains a significant challenge due to the use of toxic solvents and optical instability, not mentioning in large-scale synthesis. In this work, a green-route synthesis of blue-emitting lead-free halide perovskite CsSnCl powders is developed, in which deionized water with a small amount of inorganic acid is used as the solvent and the synthesis of the CsSnCl powders is achieved on a microfluidic platform.
View Article and Find Full Text PDFIn this work, we develop an environmental-friendly approach to produce organic-inorganic hybrid MAPbBr(MA = CHNH) perovskite nanocrystals (PeNCs) and PMMA-MAPbBrNC films with excellent compression-resistant PL characteristics. Deionized water is used as the solvent to synthesize MAPbBrpowder instead of conventionally-used hazardous organic solvents. The MAPbBrPeNCs derived from the MAPbBrpowder exhibit a high photoluminescence quantum yield (PLQY) of 93.
View Article and Find Full Text PDFUsing cold rolling, we plastically deform AA6061 sheets at room temperature and investigate the variations of the microstructures, textures and local deformation of the cold-rolled AA6061 sheets as functions of thickness reduction (Δt/t₀, t₀ and t are the thicknesses of the AA6061 sheet before and after the cold rolling, respectively). The volume fraction of total deformation texture is relatively independent of the thickness reduction for Δt/t₀ ≤ 30%, and becomes an approximately linearly increasing function of the thickness reduction for Δt/t₀ > 30%. Increasing the thickness reduction causes the increase of the Vickers hardness of the cross-section of the cold-rolled sheets, which exhibits a similar increase trend to the volume fraction of total deformation texture for Δt/t₀ > 30%.
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