Biomass ash (BA) contains alkaline cations such as K, Ca, and Mg. Due to its high pH, direct application to the soil may result in soil salinization. Composting of BA with organic matter is an effective strategy, but the composting cycle is long and there is a large amount of insoluble residue in the product.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
October 2024
The utilization of electroplating sludge (ES) to derive metal oxide functional materials is a key strategy, as it enables the recycling of valuable elements, mitigates environmental risks, and aligns with green, low-carbon development strategies. Nevertheless, the development of metal oxide composite functional materials with distinctive structures and properties derived from ES continues to present several challenges. Herein, we synthesized CuFeO/MgFeO metal oxide composites from ES by one-step hydrothermal method.
View Article and Find Full Text PDFEnvironmental pollution has been widely considered by researchers, especially the heavy metals damage to the human and ecological environment is irreversible. Adsorption is an important method to remove heavy metal ions from the environment. In this paper, humic acid (HA) was functionalized by the improved Hummers method, and its adsorption capacity for Pb(II) was studied.
View Article and Find Full Text PDFConjugated polymers have gained considerable interest due to their unique structures and promising applications in areas such as optoelectronics, photovoltaics, and flexible electronics. This review focuses on the structure-property relationship, glass transition, and crystallization behaviors of conjugated polymers. Understanding the relationship between the molecular structure of conjugated polymers and their properties is essential for optimizing their performance.
View Article and Find Full Text PDFCoal gangue (CG) is one of the largest industrial solid wastes in the world produced during the process of coal mining. The accumulation of CG is easy to cause ion leakage, which is harmful to the environment and human body. The recovery and utilization of CG are imminent.
View Article and Find Full Text PDFThis work demonstrated that electroplating sludges (EPS) of specific composition may be used for the synthesis of layered double hydroxide (LDH) materials for energy applications after appropriate treatment. The unique composition and structure of EPS render it with good electrochemical energy storage performance. The EPS containing Ni, Fe, and Al was dissolved by acid and added with urea precipitator.
View Article and Find Full Text PDFBinary PtBi decorated nanoporous gold (NPG-PtBi) electrocatalyst is specially designed and prepared for the anode in direct glucose fuel cells (DGFCs). By using electroless and electrochemical plating methods, a dense Pt layer and scattered Bi particles are sequentially coated on NPG. A simple DGFC with NPG-PtBi as anode and commercial Pt/C as cathode is constructed and operated to study the effect of operating temperatures and concentrations of glucose and NaOH.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2014
Here we report on the synthesis of novel dendritic Pt3Cu triangular pyramid caps via a solvothermal coreduction method. These caps had three-dimensional caved structures with ultrathin branches, as evidenced by high-resolution transmission electron microscopy (HRTEM) and HAADF-STEM characterization. Tuning the reduction kinetics of two metal precursors by an iodide ion was believed to be the key for the formation of an alloyed nanostructure.
View Article and Find Full Text PDFMn3O4/Ni foam composites were synthesized by a one-step hydrothermal method in an aqueous solution containing only Mn(NO3)2 and C6H12N4. It was found that Mn3O4 nanorods with lengths of 2 to 3 μm and diameters of 100 nm distributed on Ni foam homogeneously. Detailed reaction time-dependent morphological and component evolution was studied to understand the growth process of Mn3O4 nanorods.
View Article and Find Full Text PDFPolyaniline (PANI) and MnO2/PANI composites are simply fabricated by one-step interfacial polymerization. The morphologies and components of MnO2/PANI composites are modulated by changing the pH of the solution. Formation procedure and capacitive property of the products are investigated by XRD, FTIR, TEM, and electrochemical techniques.
View Article and Find Full Text PDFDealloyed nanoporous gold leaves (NPGLs) are found to exhibit high electrocatalytic properties toward both hydrazine (N(2)H(4)) oxidation and hydrogen peroxide (H(2)O(2)) reduction. This observation allows the implementation of a direct hydrazine-hydrogen peroxide fuel cell (DHHPFC) based on these novel porous membrane catalysts. The effects of fuel and oxidizer flow rate, concentration and cell temperature on the performance of DHHPFC are systematically investigated.
View Article and Find Full Text PDFBackground: Applications involving biomolecules, such as enzymes, antibodies, and other proteins as well as whole cells, are often hampered by their unstable nature at extremely high temperature and in organic solvents.
Methodology/principal Findings: We constructed enzyme-NPG biocomposites by assembling various enzymes onto the surface of nanoporous gold (NPG), which showed much enhanced biocatalytic performance and stability. Various enzymes with different molecular sizes were successfully tethered onto NPG, and the loadings were 3.
Nanoscale Res Lett
April 2011
Exploiting electrocatalysts with high activity for glucose oxidation is of central importance for practical applications such as glucose fuel cell. Pt-decorated nanoporous gold (NPG-Pt), created by depositing a thin layer of Pt on NPG surface, was proposed as an active electrode for glucose electrooxidation in neutral and alkaline solutions. The structure and surface properties of NPG-Pt were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), and cyclic voltammetry (CV).
View Article and Find Full Text PDFYing Yong Sheng Tai Xue Bao
July 2006
Based on the analysis of species important values and Shannon-Wiener index of Artemisia halodendron community on different type sandy lands in Horqin, A. halodendron community was classified into three types, i. e.
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