Fertilization and planting practices in crop systems have become important ways to reduce the uptake of heavy metals in polluted soils. However, the relative effectiveness of different management modes and the underlying mechanisms are not fully understood. In this study, we conducted experiments to assess how fertilization and planting modes affect the bioavailability of lead (Pb) in soil and its accumulation in plants.
View Article and Find Full Text PDFOrganic photoelectrochemical transistor (OPECT)-based sensors that use light-sensitive semiconductor materials as the gate have recently garnered increasing interest in various fields ranging from biological analysis to environmental monitoring. However, so far, the working principle and representative applications of OPECT sensors have not been discussed and reviewed systematically. In this review, we aim to present a comprehensive overview of the working principle and sensing mechanisms of OPECT-based sensors and various inorganic and organic photoactive gate materials used in OPECTs, with a focus on the representative applications and recent progress of these sensors in the fields of enzyme sensing, immunoassays, and nucleic acid-based sensing.
View Article and Find Full Text PDFIn lead (Pb)-contaminated soil, inoculating phosphate-solubilizing bacteria (PSB) to reduce the phytoavailability of Pb and to change the soil nutrients is an important way to inhibit the Pb uptake by plants. In this study, we isolated the native Pb-resistant Pantoea rwandensis from a tailings site. We employed broth culture and pot experiments to investigate the effect of the inoculation of P.
View Article and Find Full Text PDFIt is urgent to pursue appropriate gate photoactive materials for gate-to-channel signal modulation to achieve superior transconductance performances of organic photoelectrochemical transistor (OPECT) sensors. Notably, a hole transfer layer (HTL) participant CdZnS/sulfur-doped TiC MXene (S-MXene) gate was designed and developed in this work, which exhibited a remarkable signal modulation performance by up to 3 orders of magnitude. Because of the incorporation of S-MXene with an enhanced electrical conductivity as the effective HTL, the signal modulation capabilities of the CdZnS/S-MXene photoactive gate were superior to those of CdZnS and CdZnS/MXene.
View Article and Find Full Text PDFLow temperatures occurring at the booting stage in rice (Oryza sativa L.) often result in yield loss by impeding male reproductive development. However, the underlying mechanisms by which rice responds to cold at this stage remain largely unknown.
View Article and Find Full Text PDFRevolutionary developments in analytical chemistry have led to the rapid development of self-powered photoelectrochemical (PEC) sensors. Different from conventional PEC sensors, self-powered PEC sensors do not require an external power source or complex devices for the sensitive detection of targets. As a result, these sensors have enormous application potential for the development of novel portable sensors.
View Article and Find Full Text PDFExogenous addition of IAA has the potential to improve the metal tolerance and phytostabilization of plants, but these effects have not been systematically investigated in naturally tolerant plants. Ryegrass ( L.) is a typical indigenous plant in the Lanping Pb/Zn mining area with high adaptability.
View Article and Find Full Text PDFPursuing a more efficient signal amplification strategy is highly demanded for improving the performance of the promising cathodic photoelectrochemical (PEC) sensors. In this work, we present an extremely effective dual signal amplification strategy by the integration of a -scheme nanohybrids-based photocathode with the effective signal modulation of an organic photoelectrochemical transistor (OPECT) device. Specifically, photocathodic gate material of CdTe-BiOBr nanohybrids with a -scheme electron-transfer route was designed and synthesized for preliminary improvement of the activity of the photogate; afterward, signal modulation of the OPECT system by the photocathodic gate of CdTe-BiOBr was then accomplished for further signal amplification by 2 orders of magnitude.
View Article and Find Full Text PDFExploiting ingenious photoelectrodes and innovative signal amplification strategies has the potential to achieve high sensitivity in self-powered cathodic photoelectrochemical (PEC) analysis. In this work, a novel self-powered PEC sensing platform was constructed by integrating a synergistic signal amplification of an ingenious photocathode with a high light-harvesting photoanode. In the dual photoelectrode-based PEC system, the amplified photocurrent signals were induced by a synergistic enhancement: (1) the photocurrent of the BiOBr photocathode was improved by the incorporation of nitrogen-doped graphene; (2) the photocurrent of the self-powered sensor was activated by the high-light-harvesting BiS-CN photoanode.
View Article and Find Full Text PDFA novel actinobacterium, designated KC 17012, was isolated from lead zinc tailings collected from Lanping, Yunnan, PR China. Comparative 16S rRNA gene sequencing showed that KC 17012 belonged to the genus and was most closely related to the type strains of (98.34%), (98.
View Article and Find Full Text PDFAntonie Van Leeuwenhoek
October 2022
An isolate of Gram-stain-negative and strictly aerobic bacterium, designated KC 17139, was isolated from Jiaozi Mountain sample in Yunnan, China. Cells were non-motile cocci to oval, catalase-positive and oxidase-positive. Growth occurred at 0-7% NaCl (w/v; optimum, 0%), pH 6.
View Article and Find Full Text PDFThe search for efficient and low-cost electrocatalysts for the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER) is of utmost importance for the production of hydrogen and oxygen water splitting. In this work, the catalytic performance of the OER and HER on transition metal doped boron nanotubes (BNTs) was investigated using density functional theory. It was found that the doped transition metal atoms determine the catalytic activity of the BNTs.
View Article and Find Full Text PDFPlant CLE peptides, which regulate stem cell maintenance in shoot and root meristems and in vascular bundles through LRR family receptor kinases, are novel, complex, and to some extent conserved. Over the past two decades, peptide ligands of the CLAVATA3 (CLV3) /Embryo Surrounding Region (CLE) family have been recognized as critical short- and long-distance communication signals in plants, especially for stem cell homeostasis, cell fate determination and physiological responses. Stem cells located at the shoot apical meristem (SAM), the root apical meristem (RAM) and the procambium divide and differentiate into specialized cells that form a variety of tissues such as epidermis, ground tissues, xylem and phloem.
View Article and Find Full Text PDFAfter double fertilization, zygotic embryogenesis initiates a new life cycle, and stem cell homeostasis in the shoot apical meristem (SAM) and root apical meristem (RAM) allows plants to produce new tissues and organs continuously. Here, we report that mutations in DEAD-BOX RNA HELICASE 27 (RH27) affect zygote division and stem cell homeostasis in Arabidopsis (Arabidopsis thaliana). The strong mutant allele rh27-1 caused a zygote-lethal phenotype, while the weak mutant allele rh27-2 led to minor defects in embryogenesis and severely compromised stem cell homeostasis in the SAM and RAM.
View Article and Find Full Text PDFVitiligo (VIT) is caused by loss and degradation of functional epidermal melanocytes. Studies have indicated that melanocyte destruction may be associated with an imbalance between regulatory T cells (Treg cells) and effector T cells (Teff cells). The current study aimed to investigate the molecular mechanism through which Treg/Teff balance affects VIT pathogenesis.
View Article and Find Full Text PDFPolypyridyl transition metal complexes are well-established homogeneous electrocatalysts for the reduction of CO2. In this work, the relationship between the transition metal (including V, Cr, Mn, Nb, Mo, Ta, W, and Re) and the catalytic activity has been theoretically investigated using density functional theory. It is found that the transition metal center determines the catalytic activity of M(bpy)(CO)4.
View Article and Find Full Text PDFBackground: Polyadenylation plays a key role in producing mature mRNAs in eukaryotes. It is widely believed that the poly(A)-binding proteins (PABs) uniformly bind to poly(A)-tailed mRNAs, regulating their stability and translational efficiency.
Results: We observe that the homozygous triple mutant of broadly expressed Arabidopsis thaliana PABs, AtPAB2, AtPAB4, and AtPAB8, is embryonic lethal.
J Integr Plant Biol
September 2017
In sexual organisms, division of the zygote initiates a new life cycle. Although several genes involved in zygote division are known in plants, how the zygote is activated to start embryogenesis has remained elusive. Here, we showed that a mutation in ZYGOTE-ARREST 3 (ZYG3) in Arabidopsis led to a tight zygote-lethal phenotype.
View Article and Find Full Text PDFDeveloping inexpensive and non-precious metal electrocatalysts for the oxygen reduction reaction (ORR) is among the major goals in fuel cells. Herein, by using density-functional theory calculations, we show that N-doped olympicene/graphene hybrids exhibit unexpectedly high ORR catalytic activity-even comparable to that of the Pt(111) surface. Both graphitic-type and pyridine-type N-doped olympicene/graphene hybrids are highly active for the ORR and have good CO tolerance.
View Article and Find Full Text PDFFor the goal of practical industrial development of fuel cells, inexpensive, sustainable, and highly efficient electrocatalysts for oxygen reduction reactions (ORR) are highly desirable alternatives to platinum (Pt) and other rare metals. In this work, based on density functional theory, silicon (Si)-doped carbon nanotubes (CNTs) and graphene as metal-free, low cost, and high-performance electrocatalysts for ORR are studied systematically. It is found that the curvature effect plays an important role in the adsorption and reduction of oxygen.
View Article and Find Full Text PDFZ Naturforsch C J Biosci
June 2013
Treatment with solutions containing high concentrations of NaCl (200 or 300 mM) induced cell death in rice (Oryza sativa L.) roots, as well as the application of exogenous hydrogen peroxide (H2O2). Moreover, the pretreatment with dimethylthiourea (DMTU), a scavenger of H2O2, partially alleviated the root cell death induced by 200 mM NaCl.
View Article and Find Full Text PDFPADI4 post-translationally converts peptidylarginine to citrulline. PADI4 can disrupt the apoptotic process via the citrullination of histone H3 in the promoter of p53-target genes. The current study focused on PADI4 expression in various subtypes of oesophageal carcinoma (EC) by immunohistochemistry, western blotting and real time PCR.
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