Volatile organic compounds (VOCs) are important precursors of ozone (O) and fine particulate matter (PM). An accurate depiction of the emission characteristics of VOCs is the key to formulating VOC control strategies. In this study, the VOC emission factors and source profiles in five industrial sectors were developed using large-scale field measurements conducted in Guangzhou, China (100 samples for the emission factors and 434 samples for the source profile measurements).
View Article and Find Full Text PDFThe real-time detection of the mixing states of polycyclic aromatic hydrocarbons (PAHs) and nitro-PAHs in ambient particles is of great significance for analyzing the source, aging process, and health effects of PAHs and nitro-PAHs; yet there is still few effective technology to achieve this type of detection. In this study, 11 types of PAH and nitro-PAH standard samples were analyzed using a high performance-single particle aerosol mass spectrometer (HP-SPAMS) in lab studies. The identification principles 'parent ions' and 'mass-to-charge (m/z) = 77' of each compound were obtained in this study.
View Article and Find Full Text PDFAlthough recent laboratory simulations have demonstrated that organic matter prevents the degradation of polycyclic aromatic hydrocarbons (PAHs), their role in the long-range transport of PAHs in the real atmosphere remains poorly understood. In this study, we measured the chemical composition and mixing state of PAHs-containing individual particles in aerosols from three sources, one urban area and one remote area. PAHs-containing particles were classified into five types: organic carbon (OC), potassium mixed with organic carbon (KOC), potassium mixed with sodium (KNa), Krich and PAH-rich.
View Article and Find Full Text PDFImidazoles (IMs) are potential contributors to brown carbon; they may notably contribute to climate radiative forcing. However, only a few studies have assessed the mixing state, seasonal and spatial distributions of IMs, and influencing factors for IM formation in urban aerosols. In this study, two single-particle aerosol mass spectrometers were employed to investigate the IM-containing particles in the urban areas of Beijing and Guangzhou, China.
View Article and Find Full Text PDFNine amine species in atmospheric particles during haze and low-pollution days with low and high relative humidity (RH) were analyzed in urban Guangzhou, China. The mean concentrations of total measured amines (Ʃamines) in fine particles were 208 ± 127, 63.7 ± 21.
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