In this work, the amorphous CoS@SiO nanocages were hydrothermally synthesized by sulfurizing ZIF-67@SiO in the presence of thioacetamide (TAA). The catalytic performances of CoS@SiO nanocages as heterogeneous catalysts to activate peroxymonosulfate (PMS) for the sulfamethoxazole (SMX) degradation were systematically investigated. 100% SMX was degraded within 6 min in CoS@SiO/PMS system, indicating that the amorphous CoS@SiO nanocages exhibited outstanding sulfate radical-advanced oxidation process (SR-AOP) activity toward SMX degradation due to the regeneration of Co by surficial sulfur species like S/S.
View Article and Find Full Text PDFThe composite agents containing potassium chloride (KCl) and Hydroxyapatite (HA) were used to remediate the lead and cadmium contaminated soil in Fenghuang lead-zinc mining-smelting areas, Hunan province. The objective of this study was to identify and evaluate the influence of Cl- to the fixing efficiency of Pb and Cd by HA. Two types of contaminated soil (HF-1, HF-2) were chosen and forty treatments were set by five different Hydroxyapatite (HA) dosages and four different Cl- dosages.
View Article and Find Full Text PDFCadmium (Cd)-contaminated rice is one of the most important sources of cadmium exposure in the general population from some Asian countries. This study was conducted to assess cadmium exposure from uncooked rice in rural mining areas based on the bioaccessible fraction of cadmium using an in vitro digestion model. The biotoxic effects of cadmium in uncooked rice from mining areas were much higher than those in the control area, based not only on their higher total concentration (52.
View Article and Find Full Text PDFA method for the determination of five trace elements, including Pb, Cd, Se, As and Hg concentrations in human whole blood by HNO3-H2O2 digestion under temperature-controllable condition and ICP-MS was described. Under the optimum experimental conditions and instrumental operation parameters, the limit of detection for the five elements were 2-40 ng x L(-1). The system had a good stability with RSDs of the determination of value repeated 3 times less than 3%.
View Article and Find Full Text PDFThe concentrations of methylmercury (MeHg) in water were investigated in both level period and flood period in the Second Songhua River. The results show that the MeHg concentrations in water of Hongshi, Shihaoxian and Ganshuigang sites are relatively higher than other sampling sites. The MeHg concentrations in the level period are higher than the flood season in most sampling sites beside Laozhou and Sifangtai sites.
View Article and Find Full Text PDFWe researched mercury contents in plants and arthropods collected from the river banks in mercury polluted areas. The results show that total mercury (T-Hg) and methyl mercury (Me-Hg) in Locusta migratoria manilensis and Acrida chinensis are 0.032 - 0.
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