A comprehensive exploration of hydrogel applications in multi-stage skin wound healing.

Hydrogels, as an emerging biomaterial, have found extensive use in the healing of wounds due to their distinctive physicochemical structure and functional properties. Moreover, hydrogels can be made to match a range of therapeutic requirements for materials used in wound healing through specific functional modifications. This review provides a step-by-step explanation of the processes involved in cutaneous wound healing, including hemostasis, inflammation, proliferation, and reconstitution, along with an investigation of the factors that impact these processes.

Unravelling the removal mechanisms of trivalent arsenic by sulfidated nanoscale zero-valent iron: The crucial role of reactive oxygen species and the multiple effects of citric acid.

The remediation of arsenic-contaminated groundwater by sulfidated nanoscale zero-valent iron (S-nZVI) has raised considerable attention. However, the role of trivalent arsenic (As(III)) oxidation by S-nZVI in oxic conditions (S-nZVI/O) remains controversial, and the comprehensive effect of citric acid (CA) prevalent in groundwater on As(III) removal by S-nZVI remains unclear. Herein, the mechanisms of reactive oxygen species (ROS) generation and multiple effects of CA on As(III) removal by S-nZVI/O were systematically explored.

Activation of periodate by N-doped iron-based porous carbon for degradation of sulfisoxazole: Significance of catalyst-mediated electron transfer mechanism.

Periodate (PI) has recently been studied as an excellent oxidant in advanced oxidation processes, and its reported mechanism is mainly the formation of reactive oxygen species (ROS). This work presents an efficient approach using N-doped iron-based porous carbon (Fe@N-C) to activate periodate for the degradation of sulfisoxazole (SIZ). Characterization results indicated the catalyst has high catalytic activity, stable structure, and high electron transfer activity.

Activation of peroxymonosulfate for degrading ibuprofen via single atom Cu anchored by carbon skeleton and chlorine atom: The radical and non-radical pathways.

Single atomic Cu catalysts (SACs Cu@C) anchored by carbon skeleton and chlorine atom was synthesized by hydrolyzing Cu-MOFs and then pickled by aqua-regia to remove Cu nanoparticles (NPs Cu). Comparative characterizations revealed that SACs Cu@C was a hierarchically porous nanostructure and Cu dispersed uniformly throughout the carbon skeletons. With less active components, SACs Cu@C behaved better in activating PMS over NPs Cu@C on ibuprofen removal (91.

A comprehensive review on metal based active sites and their interaction with O during heterogeneous catalytic ozonation process: Types, regulation and authentication.

Heterogeneous catalytic ozonation (HCO) was a promising water purification technology. Designing novel metal-based catalysts and exploring their structural-activity relationship continued to be a hot topic in HCO. Herein, we reviewed the recent development of metal-based catalysts (including monometallic and polymetallic catalysts) in HCO.

Enhanced oxidation of organic contaminants by Mn(VII) in water.

Studies that promote chemical oxidation by permanganate (MnO; Mn(VII)) as a viable technology for water treatment and environmental purification have been quickly accumulating over the past decades. Various methods to activate Mn(VII) have been proposed and their efficacy in destructing a wide range of emerging organic contaminants has been demonstrated. This article aims to present a state-of-art review on the development of Mn(VII) activation methods, including photoactivation, electrical activation, the addition of redox mediators, carbonaceous materials, and other chemical agents, with a particular focus on the potential activation mechanism and critical influencing factors.

Functional bacterial consortium responses to biochar and implications for BDE-47 transformation: Performance, metabolism, community assembly and microbial interaction.

The influence of biochar on the biodegradation of persistent organic pollutants (POPs) has been extensively studied. However, the underlying mechanisms behind the response of functional microbial consortia to biochar remain poorly understood. Herein, we systematically explored the effect of biochar on 2,2',4,4'-tetrabrominated ether (BDE-47) biodegradation, and investigated the interaction and assembly mechanism of the functional bacterial consortium QY2.

Promotion of the biodegradation of phenanthrene adsorbed on microplastics by the functional bacterial consortium QY1 in the presence of humic acid: Bioavailability and toxicity evaluation.

The adsorption of hydrophobic organic compounds (HOCs) by microplastics (MPs) has attracted great attention in recent years. However, the ultimate environmental fate of the HOCs sorbed on MPs (HOCs-MPs) is poorly understood. In this work, we investigated the potential influence of the biotransformation process on the environmental fate of phenanthrene (PHE, a model HOC) sorbed on MPs (PHE-MPs) under the existence of humic acid (HA, the main ingredient of dissolved organic matter (DOM)) in the aquatic environment.

Bisulfite activated permanganate for oxidative water decontamination.

Recently, bisulfite-activated permanganate (MnO; Mn(VII)) process has attracted considerable attention as a novel class of advanced oxidation technology for destruction of organic contaminants in water. However, disputes over the underlying activation mechanism as well as reactive species generated in the Mn(VII)/bisulfite system remain for a long period due to the fairly complex chemistry involved in this system. This article aims to present a critical review on scientific development of the Mn(VII)/bisulfite system, with particular focus on the generation and contribution of various reactive intermediates.

Synergistic removal of Cr(VI) by S-nZVI and organic acids: The enhanced electron selectivity and pH-dependent promotion mechanisms.

The effects of organic acids on hexavalent chromium (Cr(VI)) removal by reduced iron-based materials have been extensively studied. Nevertheless, the promotion mechanism from the perspective of the electron transfer process is still unclear. Herein, sulfidated nanoscale zero-valent iron (S-nZVI) and the selected organic acids, citric acid (containing both -OH and -COOH groups) and oxalic acid (containing only -COOH groups), showed significant synergistic promotion effects in Cr(VI) removal.

Environmental contamination and human exposure of polychlorinated biphenyls (PCBs) in China: A review.

Polychlorinated biphenyls (PCBs), together with 11 other organic compounds, were initially listed as persistent organic pollutants (POPs) by the Stockholm Convention because of their potential threat to ecosystems and humans. In China, many monitoring studies have been undertaken to reveal the level of PCBs in environment since 2005 due to the introduced stricter environmental regulations. However, there are still significant gaps in understanding the overall spatial and temporal distributions of PCBs in China.

Effects of methanol on the performance of a novel BDE-47 degrading bacterial consortium QY2 in the co-metabolism process.

2,2',4,4'-tetrabrominated diphenyl ether (BDE-47), frequently detected in the environment, is arduous to be removed by conventional biological treatments due to its persistence and toxicity. Herein effects of methanol as a co-metabolic substrate on the biodegradation of BDE-47 was systematically studied by a functional bacterial consortium QY2, constructed through long-term and successive acclimation from indigenous microorganisms. The results revealed that BDE-47 (0.

Removal of heavy metal ions and polybrominated biphenyl ethers by sulfurized nanoscale zerovalent iron: Compound effects and removal mechanism.

Sulfurized nanoscale zerovalent iron (S-nZVI) has been widely reported to be able to quickly remove heavy metals/persistent organic pollutants, but the limited understanding of the complicated removal process of heavy metals-organic combined pollutants restricts the application of S-nZVI. Here, we demonstrate that there is significant difference in the effectiveness of S-nZVI for removing single pollutant and complex pollutants. The removal kinetic constant (k) of heavy metals by S-nZVI followed a sequence of Cr(VI)>Pb(II)>Ni(II)>Cd(II) with or without polybrominated diphenyl ethers (PBDEs).

Removal of triphenyl phosphate by nanoscale zerovalent iron (nZVI) activated bisulfite: Performance, surface reaction mechanism and sulfate radical-mediated degradation pathway.

Recently, sulfate radical-based advanced oxidation processes (SR-AOPs) have been studied extensively for the removal of pollutants, however, few researches focused on the activation of bisulfite by nanoscale zerovalent iron (nZVI), especially, surface reaction mechanism and sulfate radical-mediated degradation pathway have not been elucidated in detail. In this study, influencing factors, the kinetics, transformation pathway and mechanism of triphenyl phosphate (TPHP) degradation in the nZVI/bisulfite system were systematically discussed. Compared with Fe, nZVI was found to be a more efficient and long-lasting activator of bisulfite via gradual generation of iron ions.

Reductive debromination of decabromodiphenyl ether by iron sulfide-coated nanoscale zerovalent iron: mechanistic insights from Fe(II) dissolution and solvent kinetic isotope effects.

The mechanism that iron sulfide-coated nanoscale zero valent iron (S-nZVI) has better reduction activity towards organic pollutants than nanoscale zero-valent iron (nZVI) has long been debated. In this work, a systematic study was investigated to compare differences of main influences, BDE-209 degradation pathway, degradation kinetics and reduction mechanism of BDE-209 between nZVI and S-nZVI systems. The observed transformation rate of BDE-209 (k) by S-nZVI was 58.

Magnetite/Fe-Al-montmorillonite as a Fenton catalyst with efficient degradation of phenol.

A Fe-Al-MPM material assembled from nanosized magnetite and Fe-Al-pillared montmorillonite (Fe-Al-Mt) was characterized by XRD, XPS, BET, SEM and TEM. Fe-Al-Mt was proven to be capable of facilitating the dispersion of magnetite nanoparticles and inhibiting their aggregation. The coupling of Fe-Al-Mt with magnetite in Fe-Al-MPM improved its Fenton catalytic activity.

Efficient degradation of phenol using iron-montmorillonite as a Fenton catalyst: Importance of visible light irradiation and intermediates.

Iron-montmorillonite (Fe-Mt) with delaminated structures was synthesized via the introduction of iron oxides into Na-montmorillonite. Fe-Mt showed significant increases in the available iron content, surface area and pore volume, along with a slight increase in the basal spacing from d=1.26 (Na-Mt) to 1.