Structural, vibrational, photoelectrochemical, and optical properties of two-dimensional Ruddlesden-Popper perovskite BAPbI crystals.

Two-dimensional organic-inorganic hybrid Ruddlesden-Popper perovskites have attracted a lot of attention due to their unique photochemical properties and enhanced stability towards photoluminescence devices. Compared with three-dimensional materials, two-dimensional perovskites show great potential for photoelectric applications due to their tunable band gap, great excitation binding energy, and large crystal anisotropy. Although the synthesis and optical properties of BAPbI crystals have been extensively studied, the role of their microstructure in photoelectric applications, their electronic structure, and their electron-phonon interaction are still poorly understood.

Cs(Pb,Mn)Br Quantum Dots Glasses with Superior Thermal Stability for Contactless Electroluminescence Green-Emitting LEDs.

CsPbX (X = Cl, Br or I) perovskite quantum dots (PQDs) have gained increasing interest due to their superior performance in photoelectric applications. In our work, a series of Mn doped CsPbBr PQDs were successfully prepared in glasses by melt quenching and in situ crystallization technique. Due to the T (G)→A (S) transition of Mn, a slight red shift from 510 nm to 516 nm was found, with the FWHM expansion from 18 nm to 26 nm.