Green chemical method for the synthesis of chromogenic fiber and its application for the detection and extraction of Hg and Cu in environmental medium.

To advocate environment friendly detection idea, we adopted the green chemical method to synthesis the 1-(2 amino ethyl) piperidine functionalized polyacrylonitrile fiber (APF) and the chromogenic fiber 4-(2-pyridylazo) resorcinol (APF-PAR). The APF has high adsorption selectivity of Hg and Cu, and the change of structure, surface morphology and thermo-stability before and after adsorption have been characterized by the infrared spectra, scanning electron microscope and thermogravimetric analysis. The APF achieved the adsorption equilibrium of Hg just in 25 min and the adsorption capacity is 435.