In this work, flexible CuS films on nylon membranes are prepared by combining a simple hydrothermal synthesis and vacuum filtration followed by hot pressing. The films consist of CuS and CuS two phases with grain sizes from nano to submicron. Doping Se on the S site not only increases the CuS content in the CuS to increase carrier concentration but also modifies electronic structure, thereby greatly improves the electrical properties of the CuS.
View Article and Find Full Text PDFRecent studies have shown that silver selenide is a promising thermoelectric material at room temperature. Herein, flexible films with a nominal composition of (AgCu)Se are prepared by a simple and efficient one-pot method combined with vacuum-assisted filtration and hot pressing. The thermoelectric properties of the films are regulated by both cationic doping and a dual-phase strategy via a wet chemical method.
View Article and Find Full Text PDFMaterials (Basel)
November 2023
Copper-sulfide-based materials have attracted noteworthy attention as thermoelectric materials due to rich elemental reserves, non-toxicity, low thermal conductivity, and adjustable electrical properties. However, research on the flexible thermoelectrics of copper sulfide has not yet been reported. In this work, we developed a facile method to prepare flexible Mn-doped CuS films on nylon membranes.
View Article and Find Full Text PDFThis paper presents the study on the variation, influencing factors and diffusion regularity of hydrogen sulfide (HS) concentration and surface flux on the working face and intermediate geomembrane cover of a landfill. Field investigations were conducted using static chambers at a large-scale municipal solid waste landfill in Hangzhou, China, from January 2019 to June 2021. The analytical models of HS transport in the working face and intermediate cover were developed to investigate the surface flux under various conditions.
View Article and Find Full Text PDFLandfill gas (LFG) emission is gaining more attention from the scientific fraternity and policymakers recently due to its threat to the atmosphere and human health of the populace living in surrounding premises. Though landfill cover (LFC) (viz., daily, intermittent and final cover) is widely used by landfill operators to mitigate or reduce these emissions, their overall performance is still under question.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
October 2022
The quantitative assessment of landfill gas emissions is essential to assess the performance of the landfill cover and gas collection system. The relative error of the measured surface emission of landfill gas may be induced by the static flux chamber technique. This study aims to quantify effects of the size of the chamber, the insertion depth, pressure differential on the relative errors by using an integrated approach of in situ tests, and numerical modeling.
View Article and Find Full Text PDFSnTe is considered as a promising alternative to the conventional high-performance thermoelectric material PbTe, which inspired the thermoelectric community for a while. Here, we design a green, facile and low-energy-intensity hydrothermal route without involving any toxic or unstable chemicals to fabricate SnTe-based thermoelectric materials. Ultralow lattice thermal conductivity and enhanced thermoelectric performance are achieved via the combination of band engineering and nanostructuring.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
June 2019
Variation of volatile organic compound (VOC) concentration and composition in an active landfill were monitored by a developed static chamber for 2 years. The landfill gas from 82 sampling points including 70 points on working face, 8 points on geomembrane (GMB), and 4 points on final cover were analyzed for VOCs by GC-MS. Twenty-eight types of VOCs were detected, including terpenes, sulfur compounds, aromatics, hydrocarbon, oxygenated compounds, aldehyde compounds, and halogenated compounds.
View Article and Find Full Text PDFThe variation characteristics and influence factors of methane emission at Jiangchungou landfill, one of the largest landfill in China, has been investigated by a one-year field monitoring campaign during 2015-2016. The methane concentration above the landfill surface varied widely from negligible to 33,975 ppm. At least 75% of the methane concentration values of the sampling points are lower than the allowed limit (500 ppm).
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