Thermodynamics of Mg-Al Order-Disorder Reaction in MgAlO-Spinel: Constrained by Prolonged Annealing Experiments at 773-1123 K.

MgAlO-spinel has wide industrial and geological applications due to its special structural and physical-chemical features. It is presumably the most important endmember of complex natural spinel solid solutions, and therefore provides a structural model for a large group of minerals with the spinel structure. There exists a well known but still inadequately understood phenomenon in the structure of MgAlO-spinel, the Mg-Al cations readily exchanging their positions in response to variations of temperature, pressure, and composition.

Novel open-framework europium silicates prepared under high-temperature and high-pressure conditions.

Two new europium silicates, Na15Eu3Si12O36 (denoted as 1) and K2EuSi4O10F (denoted as 2), were successfully synthesized under high-temperature and high-pressure conditions, and structurally characterized by single-crystal and powder X-ray diffraction (XRD). The single-crystal XRD analysis of 1 reveals that its structure is based on [Si6O18]n(12n-) cyclosilicate anions that are built from six SiO4 tetrahedra sharing two of their four O corners with each other. Such [Si6O18]n(12n-) cyclosilicate anions are linked via EuO6 octahedra to form a three-dimensional (3D) framework containing 6-membered ring channels delimited by the SiO4 tetrahedra and EuO6 octahedra along the [010] direction.

Developmental changes of Col3a1 mRNA expression in muscle and their association with intramuscular collagen in pigs.

Eighty-four castrated boars including Laiwu Black (LW) (weight 30-90 kg, n=6) and Lulai Black (LL) (weight 40-100 kg, n=6) were used to study the developmental changes of collagen type III alpha 1 (Col3a1) mRNA expression in the muscle and their association with intramuscular collagen (IMC). The muscle total RNA was extracted to determine the abundance of Col3a1 mRNA using relative quantitative RT-PCR with beta-actin mRNA as the internal standard. The results indicated that the developmental patterns of muscle Col3a1 mRNA in LW and LL pigs were similar.