A trinary support of Ni/NiO/C to immobilize Ir nanoclusters for alkaline hydrogen oxidation.

The hydrogen oxidation reaction is an important process in anion exchange membrane fuel cells with alkaline solutions. The pursuit of efficient catalysts for alkaline hydrogen oxidation has attracted considerable attention. In this study, we present a precursor route for the synthesis of a new Ir-based catalyst (Ir-Ni/NiO/C), in which Ir nanoclusters were immobilized on the generated Ni/NiO/C support derived from a metal-organic framework.

An efficient approach for the treatment of radioactive waste perfluoropolyether lubricants via a synergistic effect of thermal catalysis and immobilization.

Perfluoropolyether (PFPE) lubricants are a kind of high-molecular polymer with many excellent properties. However, the use of PFPEs in the nuclear industry can lead to partial decomposition and carrying radionuclides, resulting in a large amount of radioactive waste PFPE lubricants annually. Moreover, radioactive waste PFPE lubricants are difficult to be effectively treated due to their high stability, the risk of possible leakage of radionuclides, and hypertoxic fluorine-containing by-products.

Degradation and phosphorus immobilization treatment of organophosphate esters hazardous waste by Fe-Mn bimetallic oxide.

Organophosphate esters (OPEs) waste is difficult to dispose effectively because of its stability and the potential risk of P element. In this study, taking one typical organic extractant of tributyl phosphate (TBP) as an example, we proposed a strategy to treat OPEs inspired by chemical looping combustion (CLC) technology-oxygen carrier immobilization process (OCIP), aiming at efficient TBP degradation and simultaneous P immobilization. Adopting Fe-Mn bimetallic oxide (FMBO) as oxygen carrier, an almost 100% P immobilization efficiency was achieved under recommended conditions which were obtained by response surface methodology.

Microstructural tailoring of porous few-layer graphene-like biochar from kitchen waste hydrolysis residue in molten carbonate medium: Structural evolution and conductive additive-free supercapacitor application.

Biomass-derived graphene-like material is a promising candidate for supercapacitor electrodes, while it is critical to controllably convert biomass into structure-tunable graphene. Herein, few-layer graphene-like biochar (FLGBS) was successfully fabricated from waste biomass in molten carbonate medium. Molten carbonate acted as the effective catalyst for graphitizing and the liquid medium for microcrystal relinking to achieve the rearrangement of carbon structure.

Tributyl phosphate degradation and phosphorus immobilization by MnO: Reaction condition optimization and mechanism exploration.

The treatment of tributyl phosphate (TBP) extractant waste from specific industry, eg., nuclear industry, is a great challenge due to its stability and high environmental risk of phosphorus-containing species releasing. Inspired by chemical looping combustion (CLC) technology, a MnO-assisted thermal oxidation strategy is proposed for TBP degradation and simultaneously P immobilization.

Effect of NbO doping on improving the thermo-mechanical stability of sealing interfaces for solid oxide fuel cells.

NbO is added to a borosilicate sealing system to improve the thermo-mechanical stability of the sealing interface between the glass and Fe-Cr metallic interconnect (Crofer 22APU) in solid oxide fuel cells (SOFCs). The thermo-mechanical stability of the glass/metal interface is evaluated experimentally as well as by using a finite element analysis (FEA) method. The sealing glass doped with 4 mol.