Controllable amorphization and morphology engineering on mixed-valence MOFs for ultra-fast and high-stability near-pseudocapacitance Li storage.

Coulombic efficiency (CE) and rate capability are crucial parameters for advanced secondary batteries. Herein, for the first time, we report controllable amorphization and morphology engineering on mixed-valence Fe(II,III)-MOFs from the crystalline to amorphous state and micro-clustered to hollow nano-spherical geometry through valence manipulation by a dissolved oxygen-mediated pathway. The disordered structure and the hollow nanostructure can endow the MOFs with the highest initial CE (>80%) to date for MOF electrodes, and ultrafast and super-stable near-pseudocapacitance lithium storage.

Defluorinative Haloalkylation of Unactivated Alkenes Enabled by Dual Photoredox and Copper Catalysis.

A three-component defluorinative haloalkylation of alkenes with trifluoromethyl compounds and TBAX (X = Cl, Br) via dual photoredox/copper catalysis is reported. The mild conditions are compatible with a wide array of activated trifluoromethyl aromatics bearing diverse substituents, and various nonactivated terminal and internal alkenes, enabling straightforward access to synthetically valuable γ-gem-difluoroalkyl halides with high efficiency. Mechanistic studies indicate that the [Cu] complexes not only serve as XAT catalysts but also facilitate the SET reduction of trifluoromethyl groups by photocatalysts.

A multi-objective optimization model of urban passenger transportation structure under low-carbon orientation considering participating subjects.

The optimization of urban passenger transport structure can effectively save energy and reduce the carbon emission of transport. However, the carbon emission and energy consumption generated by the construction of transport projects are worthy of attention. In this paper, a multi-objective optimization model of urban passenger transport structure oriented to low carbon is proposed considering passenger, operator, and construction.

Multi-objective cold chain logistic distribution center location based on carbon emission.

The issues of food safety and environmental protection are attracting more and more attention. Everyday, a large number of cold chain products are delivered from suppliers to customers. The cold chain products require refrigeration equipment in delivery and should be delivered to customers as soon as possible.

A Collaborative Data Collection Scheme Based on Optimal Clustering for Wireless Sensor Networks.

In recent years, energy-efficient data collection has evolved into the core problem in the resource-constrained Wireless Sensor Networks (WSNs). Different from existing data collection models in WSNs, we propose a collaborative data collection scheme based on optimal clustering to collect the sensed data in an energy-efficient and load-balanced manner. After dividing the data collection process into the intra-cluster data collection step and the inter-cluster data collection step, we model the optimal clustering problem as a separable convex optimization problem and solve it to obtain the analytical solutions of the optimal clustering size and the optimal data transmission radius.

The presence of genogroup II norovirus in retail shellfish from seven coastal cities in China.

Noroviruses (NoVs) are commonly occurring pathogens that cause gastroenteritis. Outbreaks of viral diseases have often been ascribed to the consumption of contaminated shellfish. Our objective was to evaluate the presence and contamination levels of NoV in shellfish sold at seafood markets in China.