Fabrication of heterocellular spheroids with controllable core-shell structure using inertial focusing effect for scaffold-free 3D cell culture models.

Three-dimensional (3D) cell culture models capable of emulating the biological functions of natural tissues are pivotal in tissue engineering and regenerative medicine. Despite progress, the fabrication ofheterocellular models that mimic the intricate structures of natural tissues remains a significant challenge. In this study, we introduce a novel, scaffold-free approach leveraging the inertial focusing effect in rotating hanging droplets for the reliable production of heterocellular spheroids with controllable core-shell structures.

Zebra-Patterned Stretchable Helical Yarn for Triboelectric Self-Powered Multifunctional Sensing.

Smart textiles capable of both energy harvesting and multifunctional sensing are highly desirable for next-generation portable electronics. However, there are still challenges that need to be conquered, such as the innovation of an energy-harvesting model and the optimization of interface bonding between fibers and active materials. Herein, inspired by the spiral structure of natural vines, a highly stretchable triboelectric helical yarn (TEHY) was manufactured by twisting the carbon nanotube/polyurethane nanofiber (CNT/PU NF) Janus membrane.

A Unified Model for Non-Fickian Diffusion and Anomalous Swelling of Glassy Polymer Gels.

A sheet of glassy polymers placed in a solvent shows swelling behaviors quite different from that of soft polymers (rubbers and gels). (1) Non-Fickian diffusion (called case II diffusion): As solvent permeates into the sample, a sharp front is created between the swollen part and the glassy part, and it moves toward the center at constant speed. (2) Nonmonotonous swelling: The thickness of the sample first increases and then decreases toward the equilibrium value.

Joint Experimental and Theoretical Study on Deposition Morphologies in Polymer Sessile Droplets.

Although past experimental and theoretical research has made substantial progress in understanding evaporation behaviors in various suspensions, the fundamental mechanism for polymer sessile droplets is still lacking. One critical effect is the molecular weight on the evaporation behaviors. Here, systematic experiments are carried out to investigate the evaporation behavior of polymer droplets under the effects of polymer concentration, evaporation rate, and especially molecular weight.

Bioinspired Superhydrophobic Fibrous Materials.

Natural fibers with robust water repellency play an important role in adapting organisms to various environments, which has inspired the development of artificial superhydrophobic fibrous materials with applications in self-cleaning, antifogging, water harvesting, heat exchanging, catalytic reactions, and microrobots. However, these highly textured surfaces (micro/nanotextured) suffer from frequent liquid penetration in high humidity and abrasion-induced destruction of the local environment. Herein, bioinspired superhydrophobic fibrous materials are reviewed from the perspective of the dimension scale of fibers.

Accelerating the stimuli-responsive bending of a gel using mechanical constraints.

Gel bends in response to external stimuli, which has important technical applications ranging from artificial muscle to drug delivery. Here, we predict a simple and effective method to accelerate the bending of gel using mechanical constraints. We propose an exact theory of the bending dynamics of gel, which gives analytical solutions for the time evolution of the gel curvature and the relaxation time with which the system approaches to its final equilibrium state.

The Process-Directed Self-Assembly of Block Copolymer Particles.

The kinetic paths of structural evolution and formation of block copolymer (BCP) particles are explored using dynamic self-consistent field theory (DSCFT). It is shown that the process-directed self-assembly of BCP immersed in a poor solvent leads to the formation of striped ellipsoids, onion-like particles and double-spiral lamellar particles. The theory predicts a reversible path of shape transition between onion-like particles and striped ellipsoidal ones by regulating the temperature (related to the Flory-Huggins parameter between the two components of BCP, χ ) and the selectivity of solvent toward one of the two BCP components.

Enhanced Electro-actuation in Dielectric Elastomers: The Nonlinear Effect of Free Ions.

Plasticized poly(vinyl chloride) (PVC) is a jelly-like soft dielectric material that attracted substantial interest recently as a new type of electro-active polymers. Under electric fields of several hundred volt/mm, PVC gels undergo large deformations. These gels can be used as artificial muscles and other soft robotic devices, with striking deformation behavior that is quite different from conventional dielectric elastomers.

Evaporation Dynamics of Sessile Droplets: The Intricate Coupling of Capillary, Evaporation, and Marangoni Flow.

A single-component droplet placed on a completely wetting substrate shows a pseudostable apparent contact angle (θ) during evaporation. We propose a simple theory to explain the phenomenon accounting for the liquid evaporation and the internal flow induced by the capillary and Marangoni effects. The theory predicts that when evaporation starts, the contact angle approaches to θ in a short time τ, remains constant for most of the time of evaporation, and finally increases rapidly when the droplet size becomes very small.

Epitaxial growth of bilayer Bi(110) on two-dimensional ferromagnetic FeGeTe.

Heterostructures of two-dimensional (2D) layered materials with selective compositions play an important role in creating novel functionalities. Effective interface coupling between 2D ferromagnet and electronic materials would enable the generation of exotic physical phenomena caused by intrinsic symmetry breaking and proximity effect at interfaces. Here, epitaxial growth of bilayer Bi(110) on 2D ferromagnetic FeGeTe(FGT) with large magnetic anisotropy has been reported.

The contact angle of an evaporating droplet of a binary solution on a super wetting surface.

We study the dynamics of the contact angle of a droplet of a binary solution evaporating on a super wetting surface. Recent experiments have shown that although the equilibrium contact angle of such a droplet is zero, the contact angle can show complex time dependence before reaching the equilibrium value. We analyse such phenomena by extending our previous theory for the dynamics of an evaporating single component droplet to a double component droplet.

General Programmable Growth of Hybrid Core-Shell Nanostructures with Liquid Metal Nanodroplets.

Core-shell and hollow nanostructures have been receiving significant interest due to their potential in wide scientific and technological fields. Given such large scope, however, they still lag far behind in terms of the ambition toward controllably, or even programmatically, synthesizing libraries of core-shell structures on a large scale. Here, a general route for the programmable preparation of complex core-shell nanostructures by using liquid metal (LM) droplets as reformable templates is presented, and the triggering of a localized galvanic replacement reaction in one ultrasonication system is demonstrated.

Formation of Deposition Patterns Induced by the Evaporation of the Restricted Liquid.

Evaporation-induced self-assembly of colloids or suspensions has received increasing attention. Given its critical applications in many fields of science and industry, we report deposition patterns constructed by the evaporation of the restricted aqueous suspension with polystyrene particles at different substrate temperatures and geometric container dimensions. With the temperature increases, the deposition patterns transition from honeycomb to multiring to island, which is attributed to the competition between the particle deposition rate and the contact line velocity , and the dimension of the geometric container has an effect on the characteristics of patterns.

Drying Droplets with Soluble Surfactants.

We propose a theory for the drying of liquid droplets of surfactant solutions. We show that the added surfactant hinders droplet receding and facilitates droplet spreading, causing a complex behavior of the contact line of an evaporating droplet: the contact line first recedes, then advances, and finally recedes again. We also show that the surfactant can change the deposition pattern from mountain-like to volcano-like and then to coffee-ring-like.

Interpenetrating Janus Membrane for High Rectification Ratio Liquid Unidirectional Penetration.

Anisotropic interfaces with opposite properties provide numerous unusual physical chemical properties that have played irreplaceable roles in broad domains. Here, we rationally designed an anisotropic Janus membrane with opposite wettability and special interpenetrating interface microstructure, which shows a unidirectional liquid penetration "diode" performance. Liquid is allowed to penetrate from lyophobic to lyophilic direction but is blocked in the reverse direction.

Vapor-induced motion of two pure liquid droplets.

The movement of evaporating liquid droplets on a surface can be triggered by the Marangoni effect arising from heterogeneities in the surface tension or a gradient in the surface energy of the substrate. Here, we show that, on a high energy surface that remains uniform, the motion of two pure liquid droplets can be induced by a gradient in the liquid vapor resulting from evaporation. The droplets always attract each other, moving from the high evaporation side to the low evaporation side, to reduce energy dissipation.

Multi-ring Deposition Pattern of Drying Droplets.

We propose a theory for the multi-ring pattern of the deposits that are formed when droplets of the suspension are dried on a substrate. Assuming a standard model for the stick-slip motion of the contact line, we show that as droplets evaporate many concentric rings of deposits are formed but are taken over by a solid-circle pattern in the final stage of drying. An analytical expression is given to indicate when the ring pattern changes to a solid-circle pattern during the evaporation process.

Translocation of a vesicle through a narrow hole across a membrane.

We study the translocation process of a vesicle through a hole in a solid membrane separating two chambers by using the Onsager principle. By considering the stretching energy of the vesicle and the driving force due to pressure difference, we derive a free energy that shows clearly a decrease in the energy barrier as the pressure difference between two sides of the membrane increases. The difference between the reaction path obtained from the string method and the actual kinetic paths obtained from the Onsager principle is discussed when the friction parameter changes.

Vapor-Induced Motion of Liquid Droplets on an Inert Substrate.

Evaporating droplets are known to show complex motion that has conventionally been explained by the Marangoni effect (flow induced by the gradient of surface tension). Here, we show that the droplet motion can be induced even in the absence of the Marangoni effect due to the gradient of the evaporation rate. We derive an equation for the velocity of a droplet subject to the nonuniform evaporation rate and nonuniform surface tension placed on an inert substrate, where the wettability is uniform and unchanged.

Structure Formation in Soft-Matter Solutions Induced by Solvent Evaporation.

Solvent evaporation in soft-matter solutions (solutions of colloidal particles, polymers, and their mixtures) is an important process in material making and in the printing and coating industries. The solvent-evaporation process determines the structure of materials and strongly affects their performance. Solvent evaporation involves many physicochemical processes: flow, diffusion, crystallization, gelation, glass transition, etc.

Deposition Patterns of Two Neighboring Droplets: Onsager Variational Principle Studies.

When two droplets containing nonvolatile components are sitting close to each other, asymmetrical ring-like deposition patterns are formed on the substrate. We propose a simple theory based on the Onsager variational principle to predict the deposition patterns of two neighboring droplets. The contact line motion and the interference effect of two droplets are considered simultaneously.

Ring to Mountain Transition in Deposition Pattern of Drying Droplets.

When a droplet containing a nonvolatile component is dried on a substrate, it leaves a ringlike deposit on the substrate. We propose a theory that predicts the deposit distribution based on a model of fluid flow and the contact line motion of the droplet. It is shown that the deposition pattern changes continuously from a coffee ring to volcanolike and to mountainlike depending on the mobility of the contact line and the evaporation rate.

Coherent states formulation of polymer field theory.

We introduce a stable and efficient complex Langevin (CL) scheme to enable the first direct numerical simulations of the coherent-states (CS) formulation of polymer field theory. In contrast with Edwards' well-known auxiliary-field (AF) framework, the CS formulation does not contain an embedded nonlinear, non-local, implicit functional of the auxiliary fields, and the action of the field theory has a fully explicit, semi-local, and finite-order polynomial character. In the context of a polymer solution model, we demonstrate that the new CS-CL dynamical scheme for sampling fluctuations in the space of coherent states yields results in good agreement with now-standard AF-CL simulations.

Block copolymer films with free interfaces: ordering by nanopatterned substrates.

We study block copolymers (BCPs) on patterned substrates, where the top polymer film surface is not constrained but is free and can adapt its shape self-consistently. In particular, we investigate the combined effect of free interface undulations with wetting of the BCP film as induced by nanopatterned substrates. Under wetting conditions and for a finite volume of BCP material, we find equilibrium droplets composed of coexisting perpendicular and parallel lamellar domains.