Proc Natl Acad Sci U S A
October 2024
Field-driven transport systems offer great promise for use as biofunctionalized carriers in microrobotics, biomedicine, and cell delivery applications. Despite the construction of artificial microtubules using several micromagnets, which provide a promising transport pathway for the synchronous delivery of microrobotic carriers to the targeted location inside microvascular networks, the selective transport of different microrobotic carriers remains an unexplored challenge. This study demonstrated the selective manipulation and transport of microrobotics along a patterned micromagnet using applied magnetic fields.
View Article and Find Full Text PDFPrevious electrochemically powered yarn muscles cannot be usefully operated between extreme negative and extreme positive potentials, since generated stresses during anion injection and cation injection partially cancel because they are in the same direction. We here report an ionomer-infiltrated hybrid carbon nanotube (CNT) yarn muscle that shows unipolar stress behavior in the sense that stress generation between extreme potentials is additive, resulting in an enhanced stress generation. Moreover, the stress generated by this muscle unexpectedly increases with the potential scan rate, which contradicts the fact that scan-rate-induced stress decreases for neat CNT muscles.
View Article and Find Full Text PDFThe manipulation of fast, unidirectional motion for large droplets shows important applications in the fields of fog collection and biochemical reactions. However, driving large droplets (>5 μL) to move directionally and quickly remains challenging due to the nonnegligible volume force. Herein, we fabricated a scalable, bionic peristome substrate with a microcavity width of 180 μm using a 3D printing method, which could unidirectionally drive a large water droplet (~8 μL) at a speed reaching 12.
View Article and Find Full Text PDFThere has been enormous interest in technologies that generate electricity from ambient energy such as solar, thermal, and mechanical energy, due to their potential for providing sustainable solutions to the energy crisis. One driving force behind the search for new energy-harvesting technologies is the desire to power sensor networks and portable devices without batteries, such as self-powered wearable electronics, human health monitoring systems, and implantable wireless sensors. Various energy harvesting technologies have been demonstrated in recent years.
View Article and Find Full Text PDFBiological cilia play essential roles in self-propulsion, food capture, and cell transportation by performing coordinated metachronal motions. Experimental studies to emulate the biological cilia metachronal coordination are challenging at the micrometer length scale because of current limitations in fabrication methods and materials. We report on the creation of wirelessly actuated magnetic artificial cilia with biocompatibility and metachronal programmability at the micrometer length scale.
View Article and Find Full Text PDFCorrection for 'Enhanced energy harvester performance by a tension annealed carbon nanotube yarn at extreme temperatures' by Xinghao Hu , , 2022, , 16185-16192, https://doi.org/10.1039/D2NR05303A.
View Article and Find Full Text PDFCarbon nanotube (CNT) yarns generate electrical energy when they were stretched in an electrolyte, and they have been exploited for diverse applications such as self-powered sensors and human health monitoring systems. Here we improved the capacitance change and harvester performance of a coiled CNT yarn by using an incandescent tension annealing process (ITAP). When undergoing stretching cycles at 1 Hz, a coiled ITAP yarn can produce 2.
View Article and Find Full Text PDFRecently, the realization of minimally invasive medical interventions on targeted tissues using wireless small-scale medical robots has received an increasing attention. For effective implementation, such robots should have a strong adhesion capability to biological tissues and at the same time easy controlled detachment should be possible, which has been challenging. To address such issue, a small-scale soft robot with octopus-inspired hydrogel adhesive (OHA) is proposed.
View Article and Find Full Text PDFSoft untethered micromachines with overall sizes less than 100 μm enable diverse programmed shape transformations and functions for future biomedical and organ-on-a-chip applications. However, fabrication of such machines has been hampered by the lack of control of microactuator's programmability. To address such challenge, we use two-photon polymerization to selectively link Janus microparticle-based magnetic microactuators by three-dimensional (3D) printing of soft or rigid polymer microstructures or links.
View Article and Find Full Text PDFManipulating and separating single label-free cells without biomarker conjugation have attracted significant interest in the field of single-cell research, but digital circuitry control and multiplexed individual storage of single label-free cells remain a challenge. Herein, by analogy with the electrical circuitry elements and electronical holes, we develop a pseudo-diamagnetophoresis (PsD) mattertronic approach in the presence of biocompatible ferrofluids for programmable manipulation and local storage of single PsD holes and label-free cells. The PsD holes conduct along linear negative micro-magnetic patterns.
View Article and Find Full Text PDFMechanical energy harvesters are widely studied because of their diverse applications, such as harvesting ocean wave energy, self-powered wireless sensors, portable power supplies and so on. To be feasible, an energy harvester needs to provide a high output current and voltage, in addition to being environmentally friendly. Hence, in this study, a new energy harvester is developed via reversible deformation of a three-dimensional graphene aerogel which was immersed in a salt solution.
View Article and Find Full Text PDFSuccess in making artificial muscles that are faster and more powerful and that provide larger strokes would expand their applications. Electrochemical carbon nanotube yarn muscles are of special interest because of their relatively high energy conversion efficiencies. However, they are bipolar, meaning that they do not monotonically expand or contract over the available potential range.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
October 2019
Piezocatalysis, converting mechanical vibration into chemical energy, has emerged as a promising candidate for water-splitting technology. However, the efficiency of the hydrogen production is quite limited. We herein report well-defined 10 nm BaTiO nanoparticles (NPs) characterized by a large electro-mechanical coefficient which induces a high piezoelectric effect.
View Article and Find Full Text PDFProgrammable delivery of biological matter is indispensable for the massive arrays of individual objects in biochemical and biomedical applications. Although a digital manipulation of single cells has been implemented by the integrated circuits of micromagnetophoretic patterns with current wires, the complex fabrication process and multiple current operation steps restrict its practical application for biomolecule arrays. Here, a convenient approach using multifarious transit gates is proposed, for digital manipulation of biofunctionalized microrobotic particles that can pass through the local energy barriers by a time-dependent pulsed magnetic field instead of multiple current wires.
View Article and Find Full Text PDFThe precise delivery of biofunctionalized matters is of great interest from the fundamental and applied viewpoints. In spite of significant progress achieved during the last decade, a parallel and automated isolation and manipulation of rare analyte, and their simultaneous on-chip separation and trapping, still remain challenging. Here, a universal micromagnet junction for self-navigating gates of microrobotic particles to deliver the biomolecules to specific sites using a remote magnetic field is described.
View Article and Find Full Text PDFACS Appl Mater Interfaces
May 2018
We demonstrate an efficient approach for quantifying frictional forces (sub-piconewton) at nano-bio interfaces by controlled magnetic forces, which is based on simultaneous measurements of critical frequencies for streptavidin-coupled magnetic particles. The maximum phase angle, being corresponded with the critical frequency, is formulated in terms of magnetic, frictional, and viscous forces of the particles on DNA- and SiO-functionalized micromagnet arrays. The streptavidin/DNA interface shows lower friction as an enhanced lubrication than the streptavidin/SiO interface, which is indicated by the lower transition field of quasi-static motion, the larger ratio of dynamic particles, and also the higher velocity of the particles.
View Article and Find Full Text PDFMechanoreceptors in a fingertip convert external tactile stimulations into electrical signals, which are transmitted by the nervous system through synaptic transmitters and then perceived by the brain with high accuracy and reliability. Inspired by the human synapse system, this paper reports a robust tactile sensing system consisting of a remote touch tip and a magnetic synapse. External pressure on the remote touch tip is transferred in the form of air pressure to the magnetic synapse, where its variation is converted into electrical signals.
View Article and Find Full Text PDFAlthough dielectric energy-storing devices are frequently used in high voltage level, the fast growing on the portable and wearable electronics have been increasing the demand on the energy-storing devices at finite electric field strength. This paper proposes an approach on enhancing energy density under low electric field through compositionally inducing tricriticality in Ba(Ti,Sn)O ferroelectric material system with enlarged dielectric response. The optimal dielectric permittivity at tricritical point can reach to ε = 5.
View Article and Find Full Text PDFA novel method based on remotely controlled magnetic forces of bio-functionalized superparamagnetic colloids using micromagnet arrays was devised to measure frictional force at the sub-picoNewton (pN) scale for bio-nano-/micro-electromechanical system (bio-NEMS/MEMS) interfaces in liquid. The circumferential motion of the colloids with phase-locked angles around the periphery of the micromagnets under an in-plane rotating magnetic field was governed by a balance between tangential magnetic force and drag force, which consists of viscous and frictional forces. A model correlating the phase-locked angles of the steady colloid rotation was formulated and validated by measuring the angles under controlled magnetic forces.
View Article and Find Full Text PDFWe investigate the non-linear dynamics of superparamagnetic beads moving around the periphery of patterned magnetic disks in the presence of an in-plane rotating magnetic field. Three different dynamical regimes are observed in experiments, including (1) phase-locked motion at low driving frequencies, (2) phase-slipping motion above the first critical frequency f, and (3) phase-insulated motion above the second critical frequency f. Experiments with Janus particles were used to confirm that the beads move by sliding rather than rolling.
View Article and Find Full Text PDFThe ability to manipulate small fluid droplets, colloidal particles and single cells with the precision and parallelization of modern-day computer hardware has profound applications for biochemical detection, gene sequencing, chemical synthesis and highly parallel analysis of single cells. Drawing inspiration from general circuit theory and magnetic bubble technology, here we demonstrate a class of integrated circuits for executing sequential and parallel, timed operations on an ensemble of single particles and cells. The integrated circuits are constructed from lithographically defined, overlaid patterns of magnetic film and current lines.
View Article and Find Full Text PDFA controlled magnetic field creates patterns of superparamagnetic nanoparticles with a minimum line width of 10 μm on a flexible substrate. This magnetic printing method is also successfully used to print conductive patterns consisting of copper or carbon nanomaterials.
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