- The root mean square (r.m.s.) deviation from the average position for the non-hydrogen atoms in the compound C(7)H(5)BrN(2)S is 0.011 Å, indicating a very small displacement.
- In the crystal structure, molecules are connected through N-H⋯N and N-H⋯Br hydrogen bonds, forming sheets in the (010) direction.
- The study also notes weak aromatic π-π stacking and potential C-H⋯Br interactions, with the crystal exhibiting characteristics of an inversion twin.