Sulfur Bridge Geometry Boosts Selective Fe═O Generation for Efficient Fenton-Like Reactions.

High-valent iron-oxo species (Fe═O) is a fascinating enzymatic agent with excellent anti-interference abilities in various oxidation processes. However, selective and high-yield production of Fe═O remains challenging. Herein, Fe diatomic pairs are rationally fabricated with an assisted S bridge to tune their neighbor distances and increase their loading to 11.

MiLNet: Multiplex Interactive Learning Network for RGB-T Semantic Segmentation.

Semantic segmentation methods enhance robust and reliable understanding under adverse illumination conditions by integrating complementary information from visible and thermal infrared (RGB-T) images. Existing methods primarily focus on designing various feature fusion modules between different modalities, overlooking that feature learning is the critical aspect of scene understanding. In this paper, we propose a novel module-free Multiplex Interactive Learning Network (MiLNet) for RGB-T semantic segmentation, which adeptly integrates multi-model, multi-modal, and multi-level feature learning, fully exploiting the potential of multiplex feature interaction.

CO Fixation into Useful Aromatic Carboxylic Acids via C (sp)-X Bonds Functionalization.

Carbon dioxide (CO) is an abundant and readily available carbon source. Its transformation into high-added-value chemicals is a beneficial strategy, which mitigates greenhouse gas emissions and provides new raw material sources for the chemical industry. Among these chemicals, the aromatic carboxylic acids and derivatives have broad applications in medicine, pesticides, and materials science.

Rerouting charge transfer for pharmaceutical wastewater electrochemical treatment via interfacial cocatalyst modification.

Electrochemical oxidation stands as a pivotal technology for refractory wastewater treatment. However, the high cost and low elemental abundance of commercial electrodes limit its widespread application. This work tries to address this by introducing a charge-transfer rerouting strategy via cocatalyst modification using earth-abundant elements.

RSAD2, a pyroptosis-related gene, predicts the prognosis and immunotherapy response for colorectal cancer.

Colorectal cancer (CRC) is among the most prevalent malignant tumors, known for its high heterogeneity. Although many treatments and medications are available, the long-term survival rate of CRC patients is far from satisfactory. Pyroptosis is closely related to tumor progression.

Impacts of Perfluoroalkyl Substances on Aqueous and Nonaqueous Phase Liquid Dechlorination by Sulfidized Nanoscale Zerovalent Iron.

Per- and poly fluoroalkyl substances (PFASs) are often encountered with nonaqueous phase liquid (NAPL) in the groundwater at fire-fighting and military training sites. However, it is unclear how PFASs affect the dechlorination performance of sulfidized nanoscale zerovalent iron (S-nFe), which is an emerging promising NAPL remediation agent. Here, S-nFe synthesized with controllable S speciation (FeS or FeS) were characterized to assess their interactions with PFASs and their dechlorination performance for trichloroethylene NAPL (TCE-NAPL).

Black soldier fly larvae mitigate greenhouse gas emissions from domestic biodegradable waste by recycling carbon and nitrogen and reconstructing microbial communities.

Black soldier fly larvae have been proven to reduce greenhouse gas emissions in the treatment of organic waste. However, the microbial mechanisms involved have not been fully understood. The current study mainly examined the dynamic changes of carbon and nitrogen, greenhouse gas emissions, the succession of microbial community structure, and changes in functional gene abundance in organic waste under larvae treatment and non-aeration composting.

Efficacy and mechanism of enhanced Sb(V) removal from textile wastewater using ferric flocs in aerobic biological treatment.

Antimony contamination from textile industries has been a global environmental concern and the existing treatment technologies could not reduce Sb(V) to meet the discharge standards. To overcome this shortcoming, ferric flocs were introduced to expedite the biological process for enhanced Sb(V) removal in wastewater treatment plant (WWTP). For this purpose, a series of laboratorial-scale sequential batch reactor activated sludge processes (SBRs) were applied for Sb(V) removal with varied reactor conditions and the transformation of Fe and Sb in SBR system was investigated.

Ni-Catalyzed Csp and Csp Coupling for Divergent Bisboronic Ester Synthesis.

Bisboronic esters are critical compounds in various research fields, including drug discovery, chemical biology, and material sciences. Currently, the bisboronic esters with reactive functional groups are difficult to synthesize; this is partially due to the lack of a robust method to produce these products with diverse structures and various functional groups at specific locations. To overcome this issue, this study introduced a Ni-catalysis approach to produce bisboronic esters efficiently via cross-coupling and homocoupling using readily available halogenated boronic esters as the starting material under mild reaction conditions.

Nickel-Catalyzed Reductive Cross-Coupling of Propargylic Acetates with Chloro(vinyl)silanes: Access to Silylallenes.

Because of their various reactivities, propargyl acetates are refined chemical intermediates that are extensively applied in pharmaceutical synthesis. Currently, reactions between propargyl acetates and chlorosilanes may be the most effective method for synthesizing silylallenes. Nevertheless, owing to the adaptability and selectivity of substrates, transition metal catalysis is difficult to achieve.

Precise coordination of high-loading Fe single atoms with sulfur boosts selective generation of nonradicals.

Nonradicals are effective in selectively degrading electron-rich organic contaminants, which unfortunately suffer from unsatisfactory yield and uncontrollable composition due to the competitive generation of radicals. Herein, we precisely construct a local microenvironment of the carbon nitride-supported high-loading (~9 wt.%) Fe single-atom catalyst (Fe SAC) with sulfur via a facile supermolecular self-assembly strategy.

Meta-analysis of the efficacy of postoperative adjuvant chemotherapy for stage IB non-small cell lung cancer.

Background: Many clinical trials have shown that postoperative adjuvant chemotherapy can provide a survival benefit for patients with stage IB non-small cell lung cancer. However, whether adjuvant chemotherapy should be routinely given after surgery remains controversial. Therefore, we performed a meta-analysis to investigate the efficacy of adjuvant chemotherapy versus surgery alone for stage IB non-small cell lung cancer (NSCLC).

Facial Prior Guided Micro-Expression Generation.

This paper focuses on the facial micro-expression (FME) generation task, which has potential application in enlarging digital FME datasets, thereby alleviating the lack of training data with labels in existing micro-expression datasets. Despite obvious progress in the image animation task, FME generation remains challenging because existing image animation methods can hardly encode subtle and short-term facial motion information. To this end, we present a facial-prior-guided FME generation framework that takes advantage of facial priors for facial motion generation.

Hydroxysteroid Dehydrogenase-Catalyzed Highly Regio-, Chemo-, and Enantioselective Hydrogenation of 3-Keto in Steroids.

A highly selective hydrogenation of 3-keto in steroids to 3-hydroxyl steroids catalyzed by hydroxysteroid dehydrogenases (HSDHs) was demonstrated. The Ct3α-HSDH-catalyzed hydrogenation generated 3α-hydroxyl steroids as the main enantiopure isomers in high yields, while the Ss3β-HSDH catalytic system afforded 3β-hydroxyl steroids in excellent yields. In both catalytic systems, the hydrogenation proceeded regioselectively at 3-keto with 7-, 11-, 17-, and 20-keto almost unreacted, and chemoselectively with the C═C bond and ester group unattacked.

Visible-Light-Induced Photoredox 1,2-Dialkylation of Styrenes with α-Carbonyl Alkyl Bromides and Pyridin-1-ium Salts.

A visible-light-driven photoredox dialkylation of styrenes with α-carbonyl alkyl bromides and pyridin-1-ium salts for the synthesis of polysubstituted 1,4-dihydropyridines is reported. This reaction enables the formation of two new C(sp)-C(sp) bonds in a single reaction step and provides a strategy that employs pyridin-1-ium salts as the functionalized alkylating reagents dearomatization to directly trap the resulting alkyl radicals from radical addition of alkenes and then terminate the alkene dialkylation.

Comparative Sb(V) removal efficacy of different iron oxides from textile wastewater: effects of co-existing anions and dye compounds.

Elevated Sb(V) concentration in textile wastewater is a growing environmental concern worldwide and has received wider attention in recent years. Iron oxides possess appealing characteristics as efficient and cost-effective adsorbents in large-scale applications. In the present study, Sb(V) adsorption capacity of α-FeO, γ-FeO, and FeO was compared under experimental conditions close to the practical textile wastewater treatment.

Synergistic effect of novel pyrite/N-doped reduced graphene oxide composite with heterojunction structure for enhanced photo-assisted reduction of Cr(VI) in oxic water: Specific role of molecular oxygen.

To avoid severe aggregation and synergistically utilize the intrinsic and photocatalytic reducibility, pyrite (FeS) was loaded onto N-doped reduced graphene oxides (N-rGO) to fabricate a novel FeS/N-rGO heterojunction catalyst for enhanced chromium (Cr(VI)) reduction in oxic condition to simultaneously investigate the specific effect and role of dissolved oxygen (DO). Characterization results showed that strong interaction and combination of FeS and N-rGO not only achieved the uniform distribution of FeS, but also increased the defects, and exposed more functional groups. Meanwhile, the Type II heterojunction was formed in FeS/N-rGO, which facilitated the separation efficiency of photo-generated carriers and electrons, endowing FeS/N-rGO a superior photocatalytic activity.

Palladium-Catalyzed β-C(sp)-H Arylation of Silyl Prop-1-en-1-ol Ethers with Aryl Halides: Entry to -Unsaturated Ketones.

A palladium(0)-catalyzed β-C(sp)-H arylation of silyl prop-1-en-1-ol ethers with aryl halides for the synthesis of -unsaturated ketones is presented. In contrast to the reported β-C(sp)-H arylation of ketones, the chemoselectivity of this current method relies on the Pd(0) catalytic systems and reaction temperatures: While using the Pd(dba)/DavePhos/KF system at 80 °C resulted in β-C(sp)-H monoarylation to produce β-monoarylated -unsaturated ketones, harnessing the Pd(OAc)/-Bu XPhos/KHPO system at 110 °C induced β-C(sp)-H diarylation to afford -diarylated -unsaturated ketones. The method provides a versatile route that uses readily available ketone-derivatized α-nonsubstituted silyl prop-1-en-1-ol ethers as the alkene sources and is characterized by a good functional group compatibility, a broad substrate scope, and an excellent selectivity.

Black soldier fly larvae recruit functional microbiota into the intestines and residues to promote lignocellulosic degradation in domestic biodegradable waste.

Lignocellulose is an important component of domestic biodegradable waste (DBW), and its complex structure makes it an obstacle in the biological treatment of DBW. Here, we identify black soldier fly larvae (Hermetia illucens L., BSFL) as a bioreactor for lignocellulose degradation in DBW based on their ability to effectively recruit lignocellulose-degrading bacteria.

Polydopamine-Modified MXene-Integrated Poly(-isopropylacrylamide) to Construct Ultrafast Photoresponsive Bilayer Hydrogel Actuators with Smart Adhesion.

In nature, living organisms, such as octopuses, cabrito, and frogs, have already evolved admirable adhesive abilities for better movement and predation in response to the surroundings. Inspired by biological structures, researchers have made enormous efforts in developing actuators that can respond to external stimuli, while such adhesive property is very desired, yet there is still limited research in responsive hydrogel actuators. Here, a bilayer actuator with high stretchability and robust interface bonding is presented, which has a smart adhesion and thermoreception function.

Cobalt-Promoted Electroreductive Cross-Coupling of Prop-2-yn-1-yl Acetates with Chloro(vinyl)silanes.

An electroreductive cross-coupling of prop-2-yn-1-yl acetates with chloro(vinyl)silanes for producing tetrasubstituted silylallenes is developed. The method enables the formation of a new C─Si bond through the cathodic reduction formation of the silyl radical, radical addition across the C≡C bond, the alkenyl anion intermediate formation, and deacetoxylation and represents a mild, practical route to the synthesis of silylallenes. Mechanistic studies reveal that CoCl acts as the mediator to promote the formation of the alkenyl anion intermediate via electron transfer.

Iron/nitrogen co-doped biochar derived from salvaged cyanobacterial for efficient peroxymonosulfate activation and ofloxacin degradation: Synergistic effect of Fe/N in non-radical path.

A green, low-cost, high-performance Fe/N co-doped biochar material (Fe-N@C) was synthesized using salvaged cyanobacteria without other extra precursors for peroxymonosulfate (PMS) activation and ofloxacin (OFX) degradation. With the increased pyrolysis temperature, the graphitization degree, the specific surface area and the corresponding groups like OH, COO etc. for Fe-N@C tended to increase, resulting in a greater OFX adsorption.

Thioalkynes in Ring Forming Reactions.

Organic cycles play an important role in chemistry, pharmacology and material science for their unique properties. Construction of organic cycles from thioalkynes attracted increasing attention due to the facile access of thioalkynes. 2H-Azirines were synthesized successfully from thioalkynyl oxime ethers.