Tuning the Chirality Evolution in Achiral Subnanometer Systems by Judicious Control of Molecule Interactions.

Chirality evolution from molecule levels to the nanoscale in an achiral system is a fundamental issue that remains undiscovered. Here, we report the assembly of polyoxometalate (POM) clusters into chiral subnanostructures in achiral systems by programmable single-molecule interactions. Driven by the competing binding of Ca and surface ligands, POM assemblies would twist into helical nanobelts, nanorings, and nanotubes with tunable helicity.

Microwave-assisted synthesis of polyoxometalate-DyO monolayer nanosheets and nanotubes.

Two-dimensional (2D) materials have shown unique chemical and physical properties; however, their synthesis is highly dependent on the layered structure of building blocks. Herein, we developed monolayer DyO-phosphomolybdic acid (PMA) nanosheets and nanotubes based on microwave synthesis. Microwave-assisted synthesis with high-energy input gives a faster and dynamically driven growth of nanomaterials, resulting in high-purity nanostructures with a narrow size distribution.

Visible Light Induced Ag-Polyoxometalate Coassembly into Single-Cluster Nanowires.

1D superlattices with long-ranged periodicity present extraordinary application properties due to their unique electronic structures. Here, the visible light driven synthesis of 1D single-cluster chains constructed by polyoxometalate (POM) and Ag clusters is reported, where two types of clusters align alternatively along the nanowire. Low symmetrical POM clusters of [P W O ] , [P W O ] , and [EuW O ] can be used as building blocks.

Cluster-Nuclei Coassembled One-Dimensional Subnanometer Heteronanostructures.

The cluster-nuclei coassembled strategy provides an impressive way to obtain 1D subnanometer heteronanostructures, including subnanometer nanowires and subnanometer nanobelts. These nanomaterials have diameters and thicknesses close to the size of a unit cell and exhibit excellent performance originating from multicomponent synergy. This Mini Review summarizes the recent progress of these novel functional nanomaterials, including their properties and applications in catalysis, energy conversion, and other fields.