Catalytic ozonation of bio-treated coking wastewater in continuous pilot- and full-scale system: Efficiency, catalyst deactivation and in-situ regeneration.

In this study, the performance of catalytic ozonation in the treatment of bio-treated coking wastewater (BCW) using pilot- and full-scale systems was investigated. Additionally, the removal efficiency of organic pollutants from BCW, the deactivation mechanism of MnCeO/γ-AlO, and backflushing optimization for in-situ catalyst regeneration, which have not been previously investigated, were analysed. Results of the 12-month pilot scale experiments showed that catalytic ozonation resulted in the effective removal of organic pollutants when backflushing was applied as an in-situ catalyst regeneration strategy.

Catalytic Ozonation of Organics in Reverse Osmosis Concentrate with Catalysts Based on Activated Carbon.

Acid-washed activated carbon (AC-A), nitric acid modified activated carbon (AC-NO), aminated activated carbon (AC-NH) and cerium-loaded activated carbon (Ce/AC) were prepared and characterized by BET procedure, Boehm titration and SEM. Their performances were investigated for the ozonation of p-chlorobenzoic acid (p-CBA) in its solution and organic compounds in reverse osmosis concentrate (ROC). Nitration and amination had little effect on the surface area of catalyst, but increased the concentration of surface acid and basic functional group respectively.