Three types of carbon dots were synthesized using the same precursor (folic acid and europium nitrate) via different preparation methods (doping and direct coordination). A comprehensive comparison and analysis of the morphology, surface groups, and optical properties of the prepared carbon dots (CD), europium-doped carbon dots (CD-Eu), and europium-functionalized carbon dots (CD@Eu) were conducted. Moreover, due to the higher quantum yield, excellent stability, and outstanding selectivity for UO exhibited by CD-Eu, we selected CD-Eu as the probe for subsequent applications.
View Article and Find Full Text PDFComposite materials can take advantages of the functional benefits of multiple pure nanomaterials to a greater degree than single nanomaterials alone. The UCNPs-MoS composite is a nano-application platform that combines upconversion luminescence and photothermal properties. Upconversion nanoparticles (UCNPs) are inorganic nanomaterials with long-wavelength excitation and short-wavelength tunable emission capabilities, and are able to effectively convert near-infrared (NIR) light into visible light for increased photostability.
View Article and Find Full Text PDFIn this study, we developed a simple and sensitive colorimetric sensing method for the detection of UO, which was built to release MB from the molybdenum disulfide with a phosphate group (MoS-PO) gated mesoporous silica nanoparticles functionalized phosphate group (MSN-PO) with UO chelating. In the presence of UO, MoS-PO can be effectively adsorbed onto the surface of MSN-PO based on the coordination chemistry for strong affinity between the P-O bond and UO. The adsorbed MoS-PO was then utilized as an ideal gate material to control the release of signal molecules (MB) entrapped within the pores of MSN-PO, resulting in a detectable decrease in the absorption peak at 663 nm.
View Article and Find Full Text PDFUranium (U) is an important strategic resource as well as a heavy metal element with both chemical and radiotoxicity. At present, the rapid and efficient removal of uranium from wastewater remains a huge challenge for environmental protection and ecological security. In this paper, phosphate-modified biochar supporting nano zero-valent iron (PBC/nZVI) was triumphantly prepared and fully characterized.
View Article and Find Full Text PDF