Ultra-high nickel layered oxides are recognized as promising cathode candidates for high-energy-density lithium-ion batteries due to their enhanced overall capacity and elevated operating voltage. However, the interlayer sliding of transition metal-oxygen octahedra (TMO6) and the instability of lattice oxygen at high voltages for ultra-high nickel oxide cathodes pose significant challenges to their development. Herein, the origin of oxygen framework stability is investigated by incorporating high-covalent element Mo in both bulk and surface using a one-step integrated method for ultra-high nickel cathode material LiNiCoO.
View Article and Find Full Text PDFThe relationship between matter properties and their atomic-scale structures is a challenging investigation. For relaxor ferroelectrics, correlating the relaxor mechanisms on the atomic scale to properties is still ambiguous. Here, the correlation between the atomic-scale structure and strain performance of 0.
View Article and Find Full Text PDFA modular approach to obtain benzimidazolium-urea-based, fluorophore-appended macrocyclic receptors was developed. This class of receptors could be used as selective ratiometric fluorescent sensors for H2PO4(-) due to the synergistic binding effect of benzimidazolium and urea moieties.
View Article and Find Full Text PDFIn this paper, a series of novel acridine derived bisbenzimidazolium macrocyclic fluorescent sensors were designed and synthesized. X-ray crystal structures demonstrated the self-assembly behavior of these cyclophanes in the solid state driven by hydrogen bond and π-π interactions. Anion binding studies of these sensors revealed a significant effect of the macrocyclic size and rigidity for H2PO4(-) sensing via the obvious turn-on as well as bathochromic-shift in fluorescence emission.
View Article and Find Full Text PDFZhonghua Gan Zang Bing Za Zhi
April 2010