Black arsenic-phosphorus (b-AsP), an alloy containing black phosphorus and arsenic in the form of b-AsP, has a broadly tunable band gap changing with the chemical ratios of As and P. Although mid-infrared photodetectors and mode-locked or Q-switched pulse lasers based on b-AsP (mostly b-AsP) are investigated, the potential of this family of materials for near-infrared photonic and optoelectronic applications at telecommunication bands is not fully explored. Here, we have verified a multifunctional fiber device based on b-AsP nanosheets for highly responsive photodetection and dual-wavelength ultrafast pulse generation at around 1550 nm.
View Article and Find Full Text PDFPhys Chem Chem Phys
October 2021
Photodetectors based on intrinsic graphene can operate over a broad wavelength range with ultrafast response, but their responsivity is much lower than commercial silicon photodiodes. The combination of graphene with two-dimensional (2D) semiconductors may enhance the light absorption, but there is still a cutoff wavelength originating from the bandgap of semiconductors. Here, we report a highly responsive broadband photodetector based on the heterostructure of graphene and transition metal carbides (TMCs, more specifically MoC).
View Article and Find Full Text PDFIn recent years, polaritons in two-dimensional (2D) materials have gained intensive research interests and significant progress due to their extraordinary properties of light-confinement, tunable carrier concentrations by gating and low loss absorption that leads to long polariton lifetimes. With additional advantages of biocompatibility, label-free, chemical identification of biomolecules through their vibrational fingerprints, graphene and related 2D materials can be adapted as excellent platforms for future polaritonic biosensor applications. Extreme spatial light confinement in 2D materials based polaritons supports atto-molar concentration or single molecule detection.
View Article and Find Full Text PDFBulk germanium as a group-IV photonic material has been widely studied due to its relatively large refractive index and broadband and low propagation loss from near-infrared to mid-infrared. Inspired by the research of graphene, the 2D counterpart of bulk germanium, germanene, has been discovered and the characteristics of Dirac electrons have been observed. However, the optical properties of germanene still remain elusive.
View Article and Find Full Text PDFTwo-dimensional (2D) BiSrCaCuO (BSCCO) is a emerming class of 2D materials with high-temperature superconductivity for which their electronic transport properties have been intensively studied. However, the optical properties, especially nonlinear optical response and the photonic and optoelectronic applications of normal state 2D BiSrCaCuO (Bi-2212), have been largely unexplored. Here, the linear and nonlinear optical properties of mechanically exfoliated Bi-2212 thin flakes are systematically investigated.
View Article and Find Full Text PDFHeavily doped colloidal plasmonic nanocrystals have attracted great attention because of their lower and adjustable free carrier densities and tunable localized surface plasmonic resonance bands in the spectral range from near-infra to mid-infra wavelengths. With its plasmon-enhanced optical nonlinearity, this new family of plasmonic materials shows a huge potential for nonlinear optical applications, such as ultrafast switching, nonlinear sensing, and pulse laser generation. CuP nanocrystals were previously shown to have a strong saturable absorption at the plasmonic resonance, which enabled high-energy Q-switched fiber lasers with 6.
View Article and Find Full Text PDFPhonon polaritons (PhPs) have attracted significant interest in the nano-optics communities because of their nanoscale confinement and long lifetimes. Although PhP modification by changing the local dielectric environment has been reported, controlled manipulation of PhPs by direct modification of the polaritonic material itself has remained elusive. Here, chemical switching of PhPs in α-MoO is achieved by engineering the α-MoO crystal through hydrogen intercalation.
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