A pair of enantiomeric ligands, (2R,3R)-dibenzyl-2,3-bis(isonicotinoyloxy)succinate ((R,R)-L) and (2S,3S)-dibenzyl-2,3-bis(isonicotinoyloxy)succinate ((S,S)-L), are designed and synthesized. Seven copper (II) coordination polymers {[Cu((R,R)-L)Br (THF)] ⋅ CH CN} (1 a) and {[Cu((S,S)-L)Br (THF)] ⋅ CH CN} (1 b), {[Cu((R,R)-L)Cl (THF)] ⋅ CH CN} (2 a) and {[Cu((S,S)-L)Cl (THF)] ⋅ CH CN} (2 b), {[Cu((R,R)-L)(NO ) (CH CN)]} (3 a) and {[Cu((S,S)-L)(NO ) (CH CN)]} (3 b), {[Cu((R,R)-L) (CH CN) ](ClO ) ⋅ 3CH CN} (4) were obtained through the assemblies with CuBr , CuCl ⋅ 2H O, Cu(NO ) ⋅ 3H O, Cu(ClO ) ⋅ 6H O, respectively. Single-crystal X-ray diffraction and circular dichroism analysis demonstrate that 1 a-3 a, 1 b-3 b have a mono chiral one-dimensional (1D) chain-like spiral structure, while 4 have 1D chain-like structure whose metal centers have chiral propeller coordination environment.
View Article and Find Full Text PDFA novel strategy for the growth of molecularly thin two-dimensional molecular crystals (2DMCs) of organic semiconductors with poor solubility was developed. Large-area bilayer 2DMCs were grown on a liquid surface at elevated temperatures, with record mobility and superior photoresponse.
View Article and Find Full Text PDFRapid, reliable and highly selective detection of mercury species, including Hg ions and organomercury, is of significant importance for environmental protection and human health. Herein, a new fluorescent dye 1,1,2,2-tetrakis[4-(3-methyl-1-benzimidazol-1-yl)phenyl ethylene tetraiodide () with aggregation-induced emission (AIE) potential was prepared and characterized. The presence of four positively charged methylated benzimidazole groups endows with excellent water solubility and almost undetectable background fluorescence.
View Article and Find Full Text PDFThe discovery of uncommon DNA structures and speculation about their potential functions in genes has brought attention to specific DNA structure recognition. G-quadruplexes are four-stranded nucleic acid structures formed by G-rich DNA (or RNA) sequences. G-rich sequences with a high potential to form G-quadruplexes have been found in many important genomic regions.
View Article and Find Full Text PDFNickel is considered a weak carcinogen. Some researches have shown that bound proteins or synthetic ligands may increase the toxic effect of nickel ions. A systematic study of ligand effects on the interaction between nickel complexes and DNA is necessary.
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