Kill two birds with one stone: simultaneous removal of volatile organic compounds and ozone secondary pollution by a novel photocatalytic process.

Volatile organic compounds (VOCs) originating from diverse sources with complex compositions pose threats to both environmental safety and human health. Photocatalytic treatment of VOCs has garnered attention due to its high efficacy at room temperature. However, the intricate photochemical reaction generates ozone (O), causing secondary pollution.

Rapid Sample Enrichment, Novel Derivatization, and High Sensitivity for Determination of 3-Chloropropane-1,2-diol in Soy Sauce via High-Performance Liquid Chromatography-Tandem Mass Spectrometry.

A novel, simplified derivatization method and a rapid sample preparation process using carbon yarn as a sorbent for the determination of 3-chloropropane-1,2-diol (3-MCPD) in soy sauce via high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) was developed. 3-MCPD was first enriched and purified with carbon yarn and then eluted with a methanol-water solution. Subsequently, the analyte underwent derivatization with -(dimethylamino)-phenol for sensitive detection via HPLC-MS/MS.

Occurrence and human health risk assessment of antibiotics in cultured fish from 19 provinces in China.

The occurrence of antibiotics and potential health risk of 300 cultured fish samples from 19 provinces in China were investigated. The levels of 28 antibiotics (15 fluoroquinolones, 4 tetracyclines, 8 macrolides and rifampin) in 8 fish species were measured through liquid chromatography electrospray tandem mass spectrometry. As a result, 10 antibiotics were detected with an overall detection frequency of 24.

Spent LiFePO: An old but vigorous peroxymonosulfate activator for degradation of organic pollutants in water.

Iron-based catalysts have been demonstrated to activate peroxymonosulfate (PMS) to generate reactive radicals, which is however limited by their complex preparation process, high costs and inefficiency for practical applications. Herein we obtain spent LiFePO (SLFP), with powerful catalytic capacity by a simple one-step treatment of the retired LiFePO cathode material, for PMS activation to decontaminate organic pollutants. Lithium defects and oxygen vacancies in SLFP play critical roles for PMS utilization, further confirmed by density functional theory (DFT) calculations.

Spermidine Ameliorates Nonalcoholic Steatohepatitis through Thyroid Hormone-Responsive Protein Signaling and the Gut Microbiota-Mediated Metabolism of Bile Acids.

Spermidine, a natural polyamine and physiological autophagy inducer, is involved in various physiological processes. However, the impact and mechanism of spermidine on nonalcoholic steatohepatitis (NASH) remains unclarified. We found that daily spermidine intake was significantly lower in volunteers with liver dysfunction than the healthy controls, and the serum and fecal spermidine levels were negatively correlated with the NASH phenotypes.

Insights into antimicrobial agent sulfacetamide transformation during chlorination disinfection process in aquaculture water.

Antibiotic addition and chlorination are two common processes in fishery culture. Antibiotic residues not only pollute aquaculture water, but are also one of the potential precursors of disinfection by-products (DBPs) during chlorination. The degradation kinetics, products identification and reaction mechanism of sulfacetamide (SFA), a new sulfonamides antibiotics, and potential formation of haloacetic acids (HAAs) in chlorination were explored.

Fate of sulfamethoxazole and potential formation of haloacetic acids during chlorine disinfection process in aquaculture water.

There exist two common processes in fishery culture, i.e. antibiotic addition to reduce disease in fishery, and chlorination disinfection to inhibit infectious pathogenic microorganisms.

Determination of Methylene Blue and Its Metabolite Residues in Aquatic Products by High-Performance Liquid Chromatography-Tandem Mass Spectrometry.

A sensitive and reliable method was developed to determine methylene blue (MB) and its metabolite residues, including azure A (AZA), azure B (AZB), and azure C (AZC) in aquatic products by HPLC-MS/MS. The samples were extracted by acetonitrile and cleaned up by alumina-neutral (ALN) cartridges. The analytes were separated on a Sunfire C18 column (150 mm × 2.

Efficient degradation of industrial pollutants with sulfur (IV) mediated by LiCoO cathode powders of spent lithium ion batteries: A "treating waste with waste" strategy.

Strategies to maximize the reuse of electronic and industrial wastes have scientific, economic, social and environmental implications. We herein propose a strategy of "treating waste with waste" using LiCoO cathode powders from spent lithium ion batteries to eliminate industrial pollutants led by sulfur (S) (IV) in waste water. By radical scavenging experiments and electron spin resonance (ESR) analysis, we identified singlet O as the dominant species while SO and OH as the secondary species for decontamination during the oxidization process mediated by LiCoO powders.

Development of an immobilized liposome chromatography method for screening and characterizing α-glucosidase-binding compounds.

Immobilized liposome chromatography (ILC) is a powerful tool in screening and analyzing membrane-permeable components in natural medicinal herbs. In this study, the stationary phase of a new receptor liposome biomembrane chromatography (RLBC) was employed to screen the active ingredients in seven natural medicinal herbs. As a model system, α-glucosidase was immobilized in porous silica gel by incorporating α-glucosidase into liposome vesicles.

Is addition of reductive metals (Mo, W) a panacea for accelerating transition metals-mediated peroxymonosulfate activation?

The interaction of reductive metal ions and peroxymonosulfate (PMS) is necessary for the generation of sulfate radials (SO), however, this process is greatly restrained by the sluggish reduction of high-valent metal ions. Here we report that commercially available reductive metal (Mo or W) powders are capable of unlocking this kinetic constraint. The reduction of Fe(III) to Fe(II), decomposition of PMS, and degradation/mineralization of 4-chlorophenol (4-CP) are all accelerated in the Mo/Fe/PMS process at a very low Fe/PMS ratio (Fe/PMS = 1/10).

Simultaneous determination of ten aminoglycoside antibiotics in aquatic feeds by high-performance liquid chromatography quadrupole-orbitrap mass spectrometry with pass-through cleanup.

A simple and sensitive method has been established based on pass-through cleanup and high-performance liquid chromatography quadrupole-orbitrap mass spectrometry (HPLC-Q/Orbitrap MS) for the simultaneous determination of ten aminoglycosides (AGs) in aquatic feeds. The extraction solution and cleanup procedure had been optimized, and good sensitivity, accuracy, and precision were obtained. The calibration curves of AGs were linearity (R > 0.

Chemical instability of graphene oxide following exposure to highly reactive radicals in advanced oxidation processes.

The rapidly increasing and widespread use of graphene oxide (GO) as catalyst supports, requires further understanding of its chemical stability in advanced oxidation processes (AOPs). In this study, UV/HO and UV/persulfate (UV/PS) processes were selected to test the chemical instability of GO in terms of their performance in producing highly reactive hydroxyl radicals (OH) and sulfate radicals (SO), respectively. The degradation intermediates were characterized using UV-visible absorption spectra (UV-vis), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), Raman spectroscopy, and matrix-assisted laser desorption and ionization time-of-flight mass spectrometry (MALDI-TOF-MS).

Significantly enhanced base activation of peroxymonosulfate by polyphosphates: Kinetics and mechanism.

Base activation of peroxydisulfate (PDS) is a common process aiming for water treatment, but requires high doses of PDS and strongly basic solutions. Peroxymonosulfate (PMS), another peroxygen of sulfurate derived from PDS, may also be activated by a less basic solution. However, enhancing the base-PMS reactivity is still challenging.

Enhanced AOX accumulation and aquatic toxicity during 2,4,6-trichlorophenol degradation in a Co(II)/peroxymonosulfate/Cl⁻ system.

Chloride ion is known to affect on degradation kinetics in different ways during HO· and SO4(·-)-based advanced oxidation processes (AOPs). However, its effect on absorbable organic halogen (AOX) evolution and acute toxicity of treated water remains unknown, despite the importance of the two parameters in evaluating the applicability of AOPs. In the present study, Co/peroxymonosulfate (Co/PMS) and UV/hydrogen peroxide (UV/H2O2) treatment of 2,4,6-trichlorophenol was compared in terms of AOX formation, chlorinated byproducts and acute toxicity.

Transformations of chloro and nitro groups during the peroxymonosulfate-based oxidation of 4-chloro-2-nitrophenol.

Dechlorination and denitration are known to occur during the oxidative degradation of chloronitroaromatic compounds, but the possibility of re-chlorination and re-nitration of chloro and nitro groups is not assessed despite of its importance in evaluating the applicability of advanced oxidation processes (AOPs). In this study, transformation of chloro and nitro groups in degradation of 4-chloro-2-nitrophenol (4C2NP) by sulfate radical generated via Co-mediated peroxymonosulfate activation was investigated. Both chloride and nitrate ions were found as the main inorganic products of chloro and nitro groups in 4C2NP, but their levels were much lower than that of degraded parent 4C2NP.

Peroxymonosulfate activation by phosphate anion for organics degradation in water.

Activation of peroxygens is a critical method to generate oxidative species, but often consumes additional chemical reagents and/or energy. Here we report a novel and efficient activation reaction for peroxymonosulfate (PMS) by phosphate anions (PBS). The PBS/PMS coupled system, at neutral pH, is able to decompose efficiently even mineralize a variety of organic pollutants, such as Acid Orange 7, Rhodamine B and 2,4,6-trichlorophenol.

Distinct effects of oxalate versus malonate on the iron redox chemistry: Implications for the photo-Fenton reaction.

The dicarboxylic acids oxalate (Oxal) and malonate (Mal) are frequently detected as the final low-molecular-weight organic acids during oxidative degradation of aromatic compounds. Here a distinct effect of Oxal versus Mal on iron-based photocatalytic technologies was reported by testing the degradation efficiency of the dye rhodamine B. The rates of dye degradation in irradiated Fe(III) solutions depended on Fe(III/II) speciation, photoreactivities of Fe complexes and reactivities of Fe(II) complexes with H2O2.

Novel photo-sulfite system: toward simultaneous transformations of inorganic and organic pollutants.

An efficient and green advanced oxidation process (i.e., photo-sulfite reaction) for the simultaneous oxidation of sulfite and organic pollutants in water is reported.

Rapid dye degradation with reactive oxidants generated by chloride-induced peroxymonosulfate activation.

Transition-metal is known to catalyze peroxymonosulfate (PMS) decomposition to produce sulfate radicals. Here we report reactions between PMS and chloride, without a need of transition metals, also can be used to degrade organic dye pollutant (Rhodamine B, (RhB)). Some important operating parameters, such as dosages of PMS and Cl(-), pH of solution, temperature, ionic strength, and several common cations, were systematically investigated.

Sequential reduction-oxidation for photocatalytic degradation of tetrabromobisphenol A: kinetics and intermediates.

C-Br bond cleavage is considered as a key step to reduce their toxicities and increase degradation rates for most brominated organic pollutants. Here a sequential reduction/oxidation strategy (i.e.