Luminescent Perovskite-Cross-Linked Polymer with Low Shrinkage and Excellent Stability.

When organic cross-linked polymers are combined with metal halide perovskite nanocrystals (PNCs) for realizing luminescent perovskite-polymer display materials, the stability of PNCs is enhanced and their shrinkage is suppressed. This work presents a feasible strategy for preparing CsPbBr nanocrystals (NCs) within a polydicyclopentadiene (PDCPD) thermosetting cross-linked resin matrix simultaneously via a one-step reaction. The obtained PDCPD@PNCs composite exhibits narrow peak half-widths (15-20 nm), high light transmittance (80%), low curing volume shrinkage (1.

An Intrinsic Photothermal Supramolecular Hydrogel with Robust Mechanical Strength and NIR-Responsive Shape Memory.

Near-infrared (NIR)-triggered shape memory hydrogels with promising mechanical strength hold immense potential in the field of biomedical applications and soft actuators. However, the optical and mechanical properties of currently reported hydrogels usually suffer from limited solubility and dispersion of commonly used photothermal additives in hydrogels, thus restricting their practical implementations. Here,, a set of NIR-responsive shape memory hydrogels synthesized by polyaddition of diisocyanate-terminated poly(ethylene glycol), imidazolidinyl urea (IU), and p-benzoquinone dioxime (BQDO) is reported.

Hydrogen Bonds Reinforced Ionogels with High Sensitivity and Stable Autonomous Adhesion as Versatile Ionic Skins.

Flexible wearable sensors have demonstrated enormous potential in various fields such as human health monitoring, soft robotics, and motion detection. Among them, sensors based on ionogels have garnered significant attention due to their wide range of applications. However, the fabrication of ionogels with high sensitivity and stable autonomous adhesion remains a challenge, thereby limiting their potential applications.

Ionic Switches with Positive Temperature Coefficient Enabled by Phase Separation within Hydrogel Electrolytes.

Ionic switches with a positive temperature coefficient (PTC) effect are highly desirable in the fabrication of smart electrolytes for the safety protection of electrochemical energy devices. However, most of them encounter liquid leaking or volume shrinking problems, limiting their long-term and stable operations. Herein, a PTC-type ionic switch is introduced based on a poly(acrylic acid) (PAA) hydrogel soaked by calcium acetate (CaAc), with a resistance change of six times in maximum between the homogeneous and phase separated state.

Bioinspired Semicrystalline Dynamic Ionogels with Adaptive Mechanics and Tactile Sensing.

A biological system shows dynamical shapes and tunable mechanical states while working as an actuator and/or sensor. To simulate this, we prepared semicrystalline dynamic ionogels (SDIGs) via a facile process by introducing crystallized polymer domains for phase change and amorphous domains for ionic liquid loading into ionogels. The obtained SDIGs offered tunable mechanical properties upon temperature switching with a change in modulus up to 2 orders of magnitude.

Adhering Low Surface Energy Materials without Surface Pretreatment via Ion-Dipole Interactions.

Low surface energy materials resist adhesion due to their chemical inertness and non-wetting properties. Herein, we report the creation of a transparent ionogel adhesive that uses ion-dipole interactions to achieve a higher bonding performance to polytetrafluoroethylene (PTFE) relative to most commercial glues. The ionogel adhesive is composed of a poly(hexafluorobutyl acrylate--methyl methacrylate) random copolymer and a hydrophobic ionic liquid.

All-Solid-State Self-Healing Ionic Conductors Enabled by Ion-Dipole Interactions within Fluorinated Poly(Ionic Liquid) Copolymers.

Self-healing ionic conductors in all solid state without evaporation or leakage offers great potential for the next-generation soft ionotronics. However, it remains challenging to endow ionic conductors with all solid state while keeping their essential features. In this study, an intrinsically conducting polymer is developed as all-solid-state self-healing ionic conductors based on ion-dipole interactions within a fluorinated poly(ionic liquid) copolymer.

Highly Transparent, Stretchable, and Conducting Ionoelastomers Based on Poly(ionic liquid)s.

The rapid development of soft electronics has revitalized the research of conducting elastomers. However, the design of conducting elastomers having high stretchability and good transparency still remains a considerable challenge. In this study, we develop a highly transparent, stretchable, and conducting ionoelastomer based on a poly(ionic liquid) in which cations are fixed to a stretchable elastomeric network and counter anions are mobile.