Publications by authors named "Xiaogang Yang"

This study aimed to extend the storage time of fresh-cut lotus roots. A quantitative evaluation was conducted using the grey-correlation analysis method based on the variation-coefficient weight to observe the treatment of acetic acid (0, 2%, and 5%) and ozone (0, 0.3 mg/L, and 0.

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Crafting semiconducting heterojunctions represents an effective route to enhance photocatalysis by improving interfacial charge separation and transport. However, lattice mismatch (δ) between different semiconductors can significantly hinder charge dynamics. Here, meticulous lattice tailoring is reported to create a covalent heterointerface with a built-in electric field (BIEF), imparting markedly improved hydrogen peroxide (HO) photosynthesis.

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As donors for effective energy transfer, metal-organic frameworks (MOFs) have attracted the attention of many experts in the field of artificial light-harvesting materials. This study introduces a novel two-dimensional Zn-MOF, synthesized using flexible 1,3-phenyldiacetic acid (Hmpda) and rigid 1,3,5-tris(1-imidazolyl)benzene (tib) as organic ligands. Through atomic force microscopy (AFM), we have determined the monolayer thickness of this novel material to be 5 nm.

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The incorporation of difluoroboron β-diketonate and tetraphenylethene under a facile Knoevenagel condensation reaction afforded one new D-π-A-π-D complex with high aggregation-induced emission (AIE) activity. The film can maintain a high photocurrent after long-term (500 min) photoelectronic measurements. The successful fabrication of a red LED device makes it a promising candidate for high-performance solid-state lighting.

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Article Synopsis
  • Photoenzyme-coupled catalytic systems show promise for converting carbon monoxide into valuable chemicals, but face challenges with costly coenzymes and slow reaction rates.
  • The study introduces a new 2D/2D MXene/CN platform that allows for effective regeneration of NADH and enhances the conversion of CO to formic acid (HCOOH).
  • The researchers achieved nearly 100% NADH regeneration efficiency in just 2.5 hours and a high HCOOH production rate with excellent selectivity, marking a significant step forward in CO conversion technology.
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Article Synopsis
  • Phosphor-converted white light-emitting diodes (PC-WLEDs) are gaining popularity in lighting and displays, but face challenges like thermal quenching and high costs.* -
  • A new metal-organic framework (MOF) phosphor, [CdCl(AD)], exhibits strong green emission, long lifetime, and excellent thermal stability, outperforming many commercial phosphors in tests.* -
  • The development of green and white LED devices using the [CdCl(AD)] phosphor demonstrates its potential as a competitive alternative to existing phosphors in the market.*
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Sonodynamic therapy (SDT) relies heavily on the presence of oxygen to induce cell death. Its effectiveness is thus diminished in the hypoxic regions of tumor tissue. To address this issue, the exploration of ultrasound-based synergistic treatment modalities has become a significant research focus.

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The alteration of intermediates on the (010) facet of BiVO leads to variations in charge accumulation numbers before overcoming the rate-determining step, which accounts for the enhanced charge transfer for oxygen evolution. This discovery provides insights into the photocharging effect and the photoelectrochemical reaction mechanism.

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Background: A proportion of Haematococcus pluvialis under the light stress can effectively conduct astaxanthin biosynthesis, leading to the increase in cell size. Although the size is a critical indicator for identifying the astaxanthin-rich H. pluvialis cells, the cut-off size to be separated varies from sample to sample.

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Since 2020, covalent organic frameworks (COFs) are emerging as robust catalysts for the photosynthesis of hydrogen peroxide (HO), benefiting from their distinct advantages. However, the current efficiency of HO production and solar-to-chemical energy conversion efficiency (SCC) remain suboptimal due to various constraints in the reaction mechanism. Therefore, there is an imperative to propose efficiency improvement strategies to accelerate the development of this reaction system.

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Background: In addition to the well-known Whipple's disease (WD), Tropheryma Whipplei (TW) can also lead to acute pneumonia. There is no unified consensus on the susceptible population, pathogenesis, clinical manifestations, diagnostic criteria, and treatment options for TW pneumonia.

Clinical Presentation And Intervention: This is an elderly patient with multiple injuries caused by falling from a building, and was transferred to intensive care unit (ICU) for mechanical ventilation and empirical anti-infection treatment due to severe pneumonia, and then the results of targeted next-generation sequencing (tNGS) in patient's bronchoalveolar lavage fluid (BALF) suggested TW and human metapneumovirus (HMPV) infection, and after switching to anti-infective therapy for TW, the patient was successfully extubated and transferred out of the ICU.

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Objective: Glioblastoma is the most common and aggressive type of the central nervous system cancers. Although radiotherapy and chemotherapy are used in the treatment of glioblastoma, survival rates remain unsatisfactory. This study aimed to explore differentially expressed genes (DEGs) based on the survival prognosis of patients with glioblastoma and to establish a model for classifying patients into different risk groups for overall survival.

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Marine heatwaves (MHWs) have a significant impact on intertidal bivalves and the ecosystems they sustain, causing the destruction of organisms' original habitats. Saccostrea mordax mainly inhabits the intertidal zone around the equator, exhibiting potential tolerance to high temperatures and maybe a species suitable for habitat restoration. However, an understanding about the tolerance mechanism of S.

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Artificial photosynthesis for hydrogen peroxide (HO) presents a sustainable and environmentally friendly approach to generate clean fuel and chemicals. However, the catalytic activity is hindered by challenges such as severe charge recombination, insufficient active sites, and poor selectivity. Here, a robust strategy is proposed to regulate the electronic structure of catalyst by the collaborative effect of defect engineering and dopant.

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Solar-driven carbon dioxide (CO) methanation holds significant research value in the context of carbon emission reduction and energy crisis. However, this eight-electron catalytic reaction presents substantial challenges in catalytic activity and selectivity. In this regard, researchers have conducted extensive exploration and achieved significant developments.

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The most challenging obstacle for photocatalysts to efficiently harvest solar energy is the sluggish surface redox reaction (e. g., oxygen evolution reaction, OER) kinetics, which is believed to originate from interface catalysis rather than the semiconductor photophysics.

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Nitrogen cycle is crucial for the Earth's ecosystem and human-nature coexistence. However, excessive fertilizer use and industrial contamination disrupt this balance. Semiconductor-based artificial nitrogen cycle strategies are being actively researched to address this issue.

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Luminescent coordination polymers (LCPs) have garnered significant attention from researchers as promising materials for detecting contaminants. In this paper, three new LCPs ([Zn(tib)(opda)]⋅HO (1), [Zn(tib)(mpda)]⋅5HO (2), [Zn (tib)(ppda)]⋅HO (3)) with different structures (LCP 1-3: 1D, 2D, 1D) using phenylenediacetic acid isomers and 1,3,5-tris (1-imidazolyl) benzene (tib) are synthesized. The specific surface areas (BET) of LCP 1-3 are 4 m/g, 19 m/g, and 13 m/g respectively.

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Background/aim: Ribosomal proteins have been shown to perform unique extraribosomal functions in cell apoptosis and other biological processes. Ribosomal protein L8 (RPL8) not only has important nonribosomal regulatory functions but also participates in the oncogenesis and development of tumors. However, the specific biological functions and pathways involved in this process are still unknown.

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Resorcinol-formaldehyde (RF) resin represents a promising visible-light responding photocatalyst for oxygen reduction reaction (ORR) toward HO production. However, its photocatalytic ORR activity toward HO generation is still unsatisfied for practical application. Herein, 3-hydroxythiophenol-formaldehyde (3-HTPF) resin microspheres synthesized through polycondensation reaction between 3-HTP and formaldehyde at room temperature and subsequent hydrothermal treatment exhibit enhanced photocatalytic ORR activity is reported.

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Single component white-light-emitting (SCWLE) materials are extremely desired in the field of solid-state lighting. However, pure-phosphorescent SCWLE has rarely been reported. Herein, one halogen-bonding-containing MOF [Cd(5-BIPA)(phen)] () has been synthesized, which shows efficient white-light emission originating from dual phosphorescence bands with different wavelengths and lifetimes.

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Free amino acids (FAAs) are believed to play important roles in osmoregulation and buffer capacity in some aquatic animals, such as fishes. However, the potential roles of FAAs have not been systematically summarized and characterized until now. In the present study, the meta-analysis was conducted to investigate the relationships between FAAs and environmental salinities.

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Article Synopsis
  • Lanthanide metal-organic frameworks (Ln-MOFs) are used in LEDs for better solid-state lighting and displays, but they often face challenges like low absorption rates of lanthanide ions.* -
  • This study introduces a new design for an energy transfer molecule that enhances energy transfer efficiency due to its rigid, conjugated structure, which helps in the construction of more effective Ln-MOFs.* -
  • The resulting Ln-MOFs (Eu-MOF and Tb-MOF) show impressive luminescence properties, with long-lived emissions and high quantum yields, and can be combined with blue phosphors to create a white LED with a strong color rendering index.*
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A broad light-harvesting range and efficient charge separation are two main ways to enhance the visible photocatalytic performance of semiconductors. Herein, an ionic porphyrin MOF [In(TPyP)]·(NO) (1) (TPyP = 5,10,15,20-tetrakis(4-pyridyl)-21,23-porphyrin) was synthesized metalation. The orderly arranged porphyrin photosensitizer and the internal electric field between the MOF host and NO guests enable effective visible light response and electron-hole separation.

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