Intensifying Interfacial Reverse Hydrogen Spillover for Boosted Electrocatalytic Nitrate Reduction to Ammonia.

Rational regulation of active hydrogen (*H) behavior is crucial for advancing electrocatalytic nitrate reduction reaction (NO3RR) to ammonia (NH3), yet in-depth understanding of the *H generation, transfer, and utilization remains ambiguous, and explorations for *H dynamic optimization are urgently needed. Herein we engineer a Ni3N nanosheet array intimately decorated with Cu nanoclusters (NF/Ni3N-Cu) for remarkably boosted NO3RR. From comprehensive experimental and theoretical investigations, the Ni3N moieties favors water dissociation to generate *H, and then *H can rapidly transfer to the Cu via unique reverse hydrogen spillover mediating interfacial Ni-N-Cu bridge bond, thus increasing *H coverage on the Cu site for subsequent deoxygenation/hydrogenation.

Virtual Frisch grid perovskite CsPbBr semiconductor with 2.2-centimeter thickness for high energy resolution gamma-ray spectrometer.

High intrinsic detection efficiency is as decisive as high energy resolution. Scaling up detector volume has presented great challenges, preventing perovskite semiconductors from reaching sufficient detection efficiency. We report a hole-only virtual-Frisch-grid CsPbBr detector up to 2.

Development of machine learning-based personalized predictive models for risk evaluation of hepatocellular carcinoma in hepatitis B virus-related cirrhosis patients with low levels of serum alpha-fetoprotein.

Introduction And Objectives: The increasing incidence of hepatocellular carcinoma (HCC) in China is an urgent issue, necessitating early diagnosis and treatment. This study aimed to develop personalized predictive models by combining machine learning (ML) technology with a demographic, medical history, and noninvasive biomarker data. These models can enhance the decision-making capabilities of physicians for HCC in hepatitis B virus (HBV)-related cirrhosis patients with low serum alpha-fetoprotein (AFP) levels.

Landscape fragmentation and regularity lead to decreased carbon stocks in basins: Evidence from century-scale research.

Landscapes evolution have significantly altered the Earth's energy balance and biogeochemical cycles, thereby exacerbating climate change. This, in turn, affects surface characteristics and the provision of ecosystem services, especially carbon storage. While recent centuries have witnessed unprecedented landscape changes, limited long-term studies have offered insights into the comparison between present-day features and historical conditions.

Acetate anions intercalated Fe/Mg-layered double hydroxides modified biochar for efficient adsorption of anionic and cationic heavy metal ions from polluted water.

The simultaneous removal of anionic and cationic heavy metals presents a challenge for adsorbents. In this study, acetate (Ac-) was utilized as the intercalating anion for layered double hydroxide (LDH) to prepare a novel biochar composite adsorbent (Ac-LB) designed for the adsorption of Pb(II), Cu(II), and As(V). By utilizing Ac- as the intercalating anion, the interlayer space of the LDH was enlarged from 0.

Improving Osteoarthritis by Regulating the Pyroptosis of Cartilage Cells.

Background: The regulation of in the pyroptosis of cartilage cells still needs to be further clarified. We aimed to explore the regulation of on the pyroptosis of cartilage cells and to reveal the improvement of osteoarthritis.

Methods: Chondrocytes were collected and isolated from patients with osteoarthritis (average age 58.

Highly Sensitive and Stable Flexible Smart Sensors Based on Commercial Carbon Fiber Powder Inks.

With the fast development of the smart lifestyle in recent years, simple and flexible body condition monitoring has become more and more important. However, currently, commercially available motion-sensing devices always lack flexibility or at a high cost. This article has fully explored the merits of a commercial and easily available material of carbon fiber powder (CFP) and prepared CFP-based screen printing inks.

Threshold effect of ecosystem services in response to human activity in China's urban agglomeration: a perspective on quantifying ecological resilience.

Ecological resilience reflects the role of human activity intensity (HMI) on regional ecosystem services (ESs), and resilience improvement is crucial for the high-quality development of urban agglomeration areas. However, a theoretical framework for ecological resilience needs to be developed based on ES thresholds under human activities. Based on the threshold index, we used threshold regression model to determine of the nonlinear dominant factors affecting ESs and to identify the priority areas for ecological restoration.

Mechanism of miRNA-31 Regulating Wnt/β-catenin Signaling Pathway by Targeting Satb2 in the Osteogenic Differentiation of Human Bone Marrow-Derived Mesenchymal Stem Cells.

Objective: To explore the expression of miR-31 and Satb2 gene in the serum of postmenopausal women with osteoporosis (OP).

Methods: 97 postmenopausal women with OP and 100 healthy women were selected as research subjects. MSCs were purchased from Shanghai Zhong Qiao Xin Zhou Biotechnology Co.

Effect of Thermal Shock on Properties of a Strongly Amorphous AlCrTiZrMo High-Entropy Alloy Film.

AlCrTiZrMo high-entropy alloy (HEA) films with strong amorphization were obtained by co-filter cathode vacuum arc deposition, and the effect of thermal shock on the films was investigated in order to explore the protection mechanism of HEA films against mechanical components in extreme service environments. The results show that after annealing at 800 °C for 1 h, the formation of a dense ZrTiO composite oxide layer on the surface actively prevents the oxidation from continuing, so that the AlCrTiZrMo HEA film exhibits excellent oxidation resistance at 800 °C in air. In the friction-corrosion coupling environment, the AlCrTiZrMo HEA film annealed at 800 °C for 1 h shows the best tribocorrosion resistance due to the stable dense microstructure and excellent mechanical properties, and its ΔOCP, COF and wear rate possess the smallest values of 0.

Plant-based Biomass/Polyvinyl Alcohol Gels for Flexible Sensors.

Flexible sensors show great application potential in wearable electronics, human-computer interaction, medical health, bionic electronic skin and other fields. Compared with rigid sensors, hydrogel-based devices are more flexible and biocompatible and can easily fit the skin or be implanted into the body, making them more advantageous in the field of flexible electronics. In all designs, polyvinyl alcohol (PVA) series hydrogels exhibit high mechanical strength, excellent sensitivity and fatigue resistance, which make them promising candidates for flexible electronic sensing devices.

Incomplete Multi-View Learning Under Label Shift.

In image processing, images are usually composed of partial views due to the uncertainty of collection and how to efficiently process these images, which is called incomplete multi-view learning, has attracted widespread attention. The incompleteness and diversity of multi-view data enlarges the difficulty of annotation, resulting in the divergence of label distribution between the training and testing data, named as label shift. However, existing incomplete multi-view methods generally assume that the label distribution is consistent and rarely consider the label shift scenario.

Circular RNA CircDHRS3 Aggravates IL-1β-induced ECM Degradation, Apoptosis, and Inflammatory Response via Mediating MECP2 Expression.

Previous studies have reported that circular RNA hsa_circ_0010024 (circDHRS3), microRNA (miR)-193a-3p, and Methyl CpG binding protein 2 (MECP2) are unconventionally expressed in osteoarthritis (OA) cartilage samples. However, the regulatory mechanisms among circDHRS3, miR-193a-3p, and MECP2 in OA pathogenesis are unclear. Changes of circDHRS3, miR-193a-3p, and MECP2 mRNA were detected by qRT-PCR.

IBIL Measurement and Optical Simulation of the D Center in 4H-SiC.

In this paper, D defects are studied via experiments and calculations. The 2 MeV H is used to carry on an ion-beam-induced luminescence (IBIL) experiment to measure the in-situ luminescence of untreated and annealed 4H-SiC at 100 K. The results show that the luminescence intensity decreases rapidly with increasing H fluence, which means the losses of optical defect centers.

A Study of AlO/MgO Composite Films Deposited by FCVA for Thin-Film Encapsulation.

AlO and MgO composite (AlO/MgO) films were rapidly deposited at low temperatures using filtered cathode vacuum arc (FCVA) technology, aiming to achieve good barrier properties for flexible organic light emitting diodes (OLED) thin-film encapsulation (TFE). As the thickness of the MgO layer decreases, the degree of crystallinity decreases gradually. The 3:2 AlO:MgO layer alternation type has the best water vapor shielding performance, and the water vapor transmittance (WVTR) is 3.

Spatio-temporal characteristics and mechanism of ecological degradation in a hilly southern area-a case study of Dongting Lake Basin.

Understanding the spatio-temporal characteristics of ecological degradation and its mechanism is the key to implementing national land space ecological restoration. Currently, there is a lack of knowledge about identifying ecologically degraded areas from a structure-function angle. This paper used the Dongting Lake Basin (DLB) as the research area, with the landscape pattern index and InVest model utilized to analyze the landscape distribution characteristics and ecosystem service functions in 2000 and 2018.

LncRNA TUG regulates osteogenic differentiation of bone marrow mesenchymal stem cells via miRNA-204/SIRT 1.

Objective: To explore the regulation of LncRNA TUG /miRNA-204/SIRT1 pathway on osteogenic differentiation of bone marrow mesenchymal stem cells (BMSCs), so as to provide a new theoretical basis for the clinical treatment of osteoporosis.

Methods: Detect changes of LncRNA and miRNA expression predicted in post-differentiation BMSCs with Western blot and qPCR tests. Verify the regulatory relationship between LncRNA and miRNA, miRNA and SIRT1 through the luciferase reporter assay.

Foxf1 gene increases the risk of osteoporosis in rats by inhibiting osteoblast formation and promoting osteoclast differentiation through the upregulation of NF-κB pathway.

Objectives: a) To explore the expression of Foxf1 and NF-κB in bone tissue of ovariectomized rats with osteoporosis and b) to investigate the role and mechanism of NF-κB pathway regulated by Foxf1 gene in the differentiation and formation of rat osteoclasts and osteoblasts with cell experiments.

Methods: Ovariectomized rat model of osteoporosis was established with 3-month-old female SD rats. The rats were divided into sham group (n=10) and osteoporosis group (n=10).

Identifying the Impacts of Climate Change and Human Activities on Vegetation Cover Changes: A Case Study of the Yangtze River Basin, China.

The normalized difference vegetation index (NDVI) is a useful indicator to characterize vegetation development and land use which can effectively monitor changes in ecological environments. As an important area for ecological balance and safety in China, understanding the dynamic changes in land cover and vegetation of the Yangtze River Basin would be crucial in developing effective policies and strategies to protect its natural environment while promoting sustainable growth. Based on MODIS-NDVI data and meteorological data from 2000 to 2019, the temporal and spatial distribution of vegetation coverage in the Yangtze River Basin during the past 20 years were characterized, and the impacts of human activities and climate change were quantitatively evaluated.

Mechanically Robust Irradiation, Atomic Oxygen, and Static-Durable CrO/CuNi Coatings on Kapton Serving as Space Station Solar Cell Arrays.

The polymers that served for solar cell arrays are constantly subject to various hazards, such as atomic oxygen (AO), ion irradiation, or electrostatic discharge (ESD) events. To address these issues, we fabricated and sifted CrO/CuNi-coated Kapton with a gradient structure with the goal of reaching an equilibrium between AO durability and resistance. The resulting material exhibits an impressively low of 6.

The rapid and controllable fabrication of large-scale and highly ordered micro-honeycomb arrays induced by nonsolvent phase separation.

Structures that are highly ordered in nature show unique light propagation abilities. Among them, micro-honeycomb arrays are attractive owing to their advantages relating to the collection of light or enlarging the viewing angle and, also, owing to their potential applications in precision optics. Inspired by the natural phenomenon of droplet condensation on a cold surface, breath figure self-assembly has been a common approach used to fabricate such ordered micro-honeycomb arrays.

How Do Ecosystem Services Affect Poverty Reduction Efficiency? A Panel Data Analysis of State Poverty Counties in China.

Scientific evaluation of the interaction between poverty reduction efficiency (PRE) and ecosystem services (ES) in state poverty counties is essential in promoting the rural revitalization strategy and the construction of an ecological civilization. Using the DEA model, the InVEST model, and fixed-effect panel data, this study was analyzed using the panel data of 832 poverty counties in China for 2010-2019 to evaluate the relationship between poverty reduction efficiency and ecosystem services. The main results are as follows: (1) The overall poverty reduction efficiency showed an upward trend, while ES exhibited a declining trend with spatial heterogeneity.

Circ_SPG11 plays contributing effects on IL-1β-induced chondrocyte apoptosis and ECM degradation via miR-665 inhibition-mediated GREM1 upregulation.

The dysregulation of circular RNA (circRNA) has been monitored in osteoarthritis (OA) cartilage, hinting that circRNA deregulation modulates OA progression. We thus aimed to unveil the role of circRNA spastic paraplegia 11 (circ_SPG11) in OA conditions. The upregulation of circ_SPG11 was observed in OA cartilage and IL-1β-treated chondrocytes.

Soil chemistry determines whether defensive plant secondary metabolites promote or suppress herbivore growth.

Plant secondary (or specialized) metabolites mediate important interactions in both the rhizosphere and the phyllosphere. If and how such compartmentalized functions interact to determine plant-environment interactions is not well understood. Here, we investigated how the dual role of maize benzoxazinoids as leaf defenses and root siderophores shapes the interaction between maize and a major global insect pest, the fall armyworm.

The Driving Influence of Multi-Dimensional Urbanization on PM Concentrations in Africa: New Evidence from Multi-Source Remote Sensing Data, 2000-2018.

Africa's PM pollution has become a security hazard, but the understanding of the varying effects of urbanization on driven mechanisms of PM concentrations under the rapid urbanization remains largely insufficient. Compared with the direct impact, the spillover effect of urbanization on PM concentrations in adjacent regions was underestimated. Urbanization is highly multi-dimensional phenomenon and previous studies have rarely distinguished the different driving influence and interactions of multi-dimensional urbanization on PM concentrations in Africa.