Synthesis of ZIF-67 composite lignin hydrogel and its catalytic degradation of naphthalene by PMS in wastewater.

The incorporation of ZIF-67 into hydrogels for wastewater pollutant remediation has been widely studied, but the synthesis often requires organic solvents such as methanol or ethanol, which can result in the generation of toxic liquid waste. In this study, a novel hydrogel (ZIF-67@SL) was synthesized by integrating ZIF-67 into a dual-network system of sodium lignosulfonate (SL) and acrylamide (AM) using an in situ precipitation method in water. The material was characterized by XRD, FTIR, XPS, SEM, TEM, BET, and TGA analyses.

Synthesis of magnetic sodium lignosulfonate hydrogel(FeO@LS) and its adsorption behavior for Cd in wastewater.

Heavy metal pollution is becoming increasingly serious. Heavy metal pollutants are nonbiodegradable and can be bioenriched through the food chain, and thus, they greatly threaten the environment and human health. Hydrogels, as an ideal adsorbent, have been widely used to treat heavy metal industrial wastewater.

Tracing sources of oilfield wastewater based on excitation-emission matrix fluorescence spectroscopy coupled with chemical pattern recognition techniques.

In order to prevent the illegal discharge of oilfield wastewater, this work proposed excitation-emission matrix fluorescence (EEMF) spectroscopy coupled with two kinds of chemical pattern recognition methods for tracing the sources of oilfield wastewater. The first pattern recognition method was built from the relative concentrations extracted by alternating trilinear decomposition (ATLD) based on partial least squares-discriminant analysis (PLS-DA) algorithm, and the other one was modeled based on strictly multi-way partial least squares-discriminant analysis (N-PLS-DA). Both methods showed good discrimination abilities for oilfield wastewater samples from three different sources.

Adsorption of Rhodamine B from an aqueous solution by acrylic-acid-modified walnut shells: characterization, kinetics, and thermodynamics.

A batch experiment was used in studying the effect of acrylic-acid-modified walnut shell (MWNS) as a low-cost adsorbent for removing Rhodamine B (RB) cationic dye in aqueous solutions. The adsorbent dosage, initial dye concentration, contact time, temperature, pH, and supporting electrolyte concentration on the adsorption behaviour of the adsorbent were explored. The adsorbent was characterized using the point of zero charge (pH), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), automatic specific surface analysis (BET), and X-ray photoelectron spectroscopy (XPS).