The low carbon mass loading along with serious imbalance between the carbon mass loading and the electrode performance greatly hinders practical applications of capacitive deionization (CDI). Traditional thick bulk-type (BT) carbon electrodes often suffer from extremely limited active sites, thereby being vital to explore a basic strategy to unlock the performance. Herein, 3D-printed thick carbon electrodes were utilized for CDI desalination for the first time.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2024
Lanthanide metal-organic frameworks (LnMOFs) have substantial potential in luminescence due to their unique antenna effect. Nevertheless, the single emission is susceptible to pseudo-signals caused by external environmental conditions, which significantly threaten the accurate measurement of the concentration. In this case, we prepared a dual-emission fluorescent probe {EuTb(NH-BDC)(DMF)·2DMF} (NH-BDC = Diaminoterephthalic acid, DMF = N,N-dimethylformamide).
View Article and Find Full Text PDFInterlayer functionalization modulation is essential for modifying LDHs and improving their selectivity and adsorption capacity for target pollutants. In this work, Glu@NiFe-LDH was synthesized using a simple one-step hydrothermal method and tested for its ability to remove CrO from wastewater. The modification significantly increased the composite material's removal ability by 2-3 times, up to 98.
View Article and Find Full Text PDFIn the adsorption process of functionalized layered double hydroxide (LDH) to target pollutants it, is essential to investigate the role of functional groups. In this work, 2‑mercaptoethane sulfonic acid (MS) was used as an intercalation modifier to prepare functionalized NiFe-LDH by solvothermal method. The interfacial interaction between the functional groups and the NiFe-LDH surface was studied via molecular dynamics simulation.
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