Effect of nitrogen oxides and sulfur oxides to triphenyl phosphate degradation and cytotoxicity on surface of different transition metal salts.

Nitrogen oxides and sulfur oxides, as the dominant toxic gases in the atmosphere, can induce severe human health problems under the composite pollutant conditions. Currently the effect of nitrogen or sulfur oxides in atmospheric environment to the degradation and cytotoxicity of triphenyl phosphate (TPhP) on atmospheric particle surfaces still remain poorly understood. Hence, laboratory simulation methods were used in this study to investigate the effect and related mechanism.

Degradation, transformation and cytotoxicity of triphenyl phosphate on surface of different transition metal salts in atmospheric environment.

Triphenyl phosphate (TPhP) and transition metal elements have been ubiquitously detected in the atmosphere, which can participate in atmospheric chemical reactions and induce damage to human health. Currently the understanding of TPhP degradation, transformation and cytotoxicity on atmospheric particles surface are still limited. Therefore, this study used laboratory simulation methods to investigate the influence of irradiation time, transition metal salts, relative humidity (RH) to TPhP degradation, transformation and relative cytotoxicity.

A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates.

Secondary organic aerosols (SOA) are crucial constitution of fine particulate matter (PM), which are mainly derived from photochemical oxidation products of primary organic matter and volatile organic compounds (VOCs), and can induce terrible impacts to human health, air quality and climate change. As we know, organosulfates (OSs) and organic nitrates (ON) are important contributors for SOA formation, which could be possibly produced through various pathways, resulting in extremely complex formation mechanism of SOA. Although plenty of research has been focused on the origins, spatial distribution and formation mechanisms of SOA, a comprehensive and systematic understanding of SOA formation in the atmosphere remains to be detailed explored, especially the most important OSs and ON dedications.