All-solid-state lithium batteries, including sulfide electrolytes and nickel-rich layered oxide cathode materials, promise safer electrochemical energy storage with high gravimetric and volumetric densities. However, the poor electrical conductivity of the active material results in the requirement for additional conducive additives, which tend to react negatively with the sulfide electrolyte. The fundamental scientific principle uncovered through this work is simple and suggests that the electrical network benefits associated with the introduction of short-length carbons will eventually be overpowered by the increase in bulk resistance associated with their instability in the sulfide electrolyte.
View Article and Find Full Text PDFThe mobile robot market is experiencing rapid growth, playing a pivotal role in various human-centric environments like restaurants, offices, hotels, hospitals, apartments, and factories. However, current differential-driven mobile robots, employing conventional casters and wheel motors, encounter limitations in surmounting uneven surfaces and high steps due to constraints caused by wheel and caster dimensions. While some robots address these challenges by incorporating optimized wheel shapes and additional motors, this invariably leads to an increase in both size and cost.
View Article and Find Full Text PDFIn general, sanding robots that move as if drawing a line along a surface are mainly used when sanding objects with a large area; however, they require a long working time, and it is difficult to secure a uniform sanded area. This study focuses on large-area sanding robots, such as those for ships, storage tanks, and tank lorries, and proposes an adaptive belt tension robot equipped with a 4-point supported belt mechanism capable of sanding variable curved surfaces. In addition, a sanding normal force prediction formula is proposed to describe the sanding performance of the contact surface.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2023
Accomplishments of enhanced activity and durability are a major concern in the design of catalysts for acidic water oxidation. To date, most studied supported metal catalysts undergo fast degradation in strongly acidic and oxidative environments due to improper controlling of the interface stability caused by their lattice mismatches. Here, we evaluate the activity-stability trends of in situ crystallized antimony-doped tin oxide (Sb-SnO)@RuO (Sb-SnO@RuO) heterostructure nanosheets (NSs) for acidic water oxidation.
View Article and Find Full Text PDFTo fabricate high efficiency photoanodes for water oxidation, it is highly required to engineer their nanoporous architecture and interface to improve the charge separation and transport efficiency. By focusing on this aspect, we developed hierarchical nanoporous BiVO (BV) from solution processed two-dimensional BiOI (BI) crystals. The orientation of the BI crystals was controlled by changing the solvent volume ratios of ethylene glycol (EG) to ethanol (ET), which resulted in different hierarchical and planar BV morphologies through a chemical treatment followed by thermal heating.
View Article and Find Full Text PDFPlasma-enhanced atomic layer deposition (PEALD) of TiN thin films were investigated as an effective Se diffusion barrier layer for Cu (In, Ga) Se (CIGS) solar cells. Before the deposition of TiN thin film on CIGS solar cells, a saturated growth rate of 0.67 Å/cycle was confirmed using tetrakis(dimethylamido)titanium (TDMAT) and N plasma at 200 °C.
View Article and Find Full Text PDFNanostructuring is considered one of the key approaches to achieve highly efficient thermoelectric alloys by reducing thermal conductivity. In this study, we investigated the effect of oxide (ZnO and SnO) nanolayers at the grain boundaries of polycrystalline InYbCoSb skutterudites on their electrical and thermal transport properties. Skutterudite powders with oxide nanolayers were prepared by atomic layer deposition method, and the number of deposition cycles was varied to control the coating thickness.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2020
Extended and oriented rutile nanowires (NWs) hold great promise for numerous applications because of their various tunable physicochemical properties in air and/or solution media, but their direct synthesis on a wide range of conducting substrates remains a significant challenge. Their device performance is governed by relevant NW geometries that cannot be fully controlled to date by varying bulk synthetic conditions. Herein, orientation engineering of rutile SnO NWs on a variety of conducting substrates by atomic layer deposition (ALD) seeding has been investigated.
View Article and Find Full Text PDFA dataset in this report is regarding an article "Ultrathin Effective TiN Protective Films Prepared by Plasma-Enhanced Atomic Layer Deposition for High Performance Metallic Bipolar Plates of Polymer Electrolyte Membrane Fuel Cells" [1]. TiN (Titanium Nitride) thin films were deposited by Plasma-Enhanced Atomic Layer Deposition (PEALD) method using well known two types of precursor: using tetrakis(dimethylamino)titanium (TDMAT) and titanium tetrachloride (TiCl), and plasma. Summarized reports, growth characteristics (growth rate as a function of each precursor pulse time, plasma power, precursor and plasma purge time, thickness depending on the number of PEALD cycles), each precursor structural information and the atomic force micrographs (AFM) data are herein demonstrated.
View Article and Find Full Text PDFan edible plant, has been traditionally used for reducing swelling and treating wounds, muscle catches, sprains, bone fractures, blisters, and diarrhea. ethanol extract (PSE) was evaluated for its anti-inflammatory potential in lipopolysaccharide-stimulated murine RAW 264.7 cells.
View Article and Find Full Text PDFA signal conditioning block of a 1 × 200 Complementary Metal-Oxide-Semiconductor (CMOS) detector array is proposed to be employed with a real-time 0.2 THz imaging system for inspecting large areas. The plasmonic CMOS detector array whose pixel size including an integrated antenna is comparable to the wavelength of the THz wave for the imaging system, inevitably carries wide pixel-to-pixel variation.
View Article and Find Full Text PDFJ Environ Sci (China)
June 2014
Anoxic gas recirculation system was applied to control the membrane fouling in pilot-scale 4-stage anoxic membrane bioreactor (MBR). In the anaerobic-anoxic-anoxic-aerobic flow scheme, hydrophilic polytetrafluoroethylene (PTFE) membrane (0.2 μm, 7.
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