Preparation of Pt Nanocatalyst on Carbon Materials via a Reduction Reaction of a Pt Precursor in a Drying Process.

Platinum (Pt) nanocatalyst for a proton-exchange membrane fuel cell (PEMFC) was prepared on a carbon black particle or a graphite particle coated with a nafion polymer via a reduction of platinum(II) bis(acetylacetonate) denoted as Pt(acac)2 as a Pt precursor in a drying process. Sublimed Pt(acac)2 adsorbed on the nafion-coated carbon materials was reduced to Pt nanoparticles in a glass reactor at 180 degrees C of N2 atmosphere. The morphology of Pt nanoparticles on carbon materials was observed by scanning electron microscopy (SEM) and the distribution of Pt nanoparticles was done by transmission electron microscopy (TEM).

A new incorporation method of metallic precursors into a nafion film via a drying process for the preparation of metallic nanocatalysts/nafion.

A new simple drying process was developed in order to prepare a metallic nanocatalysts/Nafion for self-humidifying membrane in a proton-exchange membrane fuel cell (PEMFC). Metallic precursors such as platinum(ll) bis(acetylacetonate) or palladium(ll) bis(acetylacetonate) was sublimed and simultaneously penetrated into the surface of a Nafion film. And then it was reduced to Pt or Pd nanoparticles beneath the film surface without a special reducing agent in a glass reactor of N2 atmosphere at 180 degrees C for 5, 10, 30 and 60 min, respectively.

A new deposition method for the preparation of Pt-Pd nanocatalysts on a nafion coated carbon black via the reduction of metallic precursors in a drying process.

A simple method for the synthesis of Pt-Pd nanocatalysts was developed for a proton-exchange membrane fuel cell (PEMFC), which was loaded on a nafion coated carbon black via the sequential reduction of palladium(II) bis(acetylacetonato) and platinum(II) bis(acetylacetonato) in a drying process. Metallic precursors were sublimed and reduced on a nafion coated carbon black which was spray coated on a gas diffusion layer (GDL) in a glass reactor of N2 atmosphere at 180 degrees C for various times. The morphology and distribution of the Pt and Pd nanoparticles were observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), and we found that the loading weight, number density and particle size of Pt-Pd nanoparticles increased with increasing exposure time at 180 degrees C.