A hybridization of managed aquifer recharge (MAR) with pre-oxidation processes was conducted in this study to investigate changes in dissolved organic matter characteristics and the attenuation of selected trace organic contaminants (TrOCs). Potassium permanganate, chlorine, and ozone treatments were used for pre-oxidation, which effectively attenuated some TrOCs, particularly the combination of MAR with ozone achieved 84-99% attenuation. The pre-oxidation step using potassium permanganate showed high removal of carbamazepine (96%).
View Article and Find Full Text PDFThis study is the first to demonstrate the capability of Cl to markedly accelerate organic oxidation using thermally activated peroxymonosulfate (PMS) under acidic conditions. The treatment efficiency gain allowed heat-activated PMS to surpass heat-activated peroxydisulfate (PDS). During thermal PMS activation at excess Cl, accelerated oxidation of 4-chlorophenol (susceptible to oxidation by hypochlorous acid (HOCl)) was observed along with significant degradation of benzoic acid and ClO occurrence, which involved oxidants with low substrate specificity.
View Article and Find Full Text PDFThis study evaluated the performance of a pilot-scale hybrid constructed wetland system for secondary effluent and investigated bulk organic matter characteristics. The hybrid constructed wetland consisted of a vertical-flow (VF) bed followed by a horizontal-flow (HF) bed. We also investigated the effects of hydraulic loading rates and influent organic load on the performance of the pilot-scale VF-HF hybrid constructed wetland.
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