Aside from the desulfurisation, the denitrogenation of fuels is of great importance to minimze the environmental impact of transport emissions. The oxidative reaction pathway of organic nitrogen in the catalytic oxidative denitrogenation could be successfully elucidated. This is the first time such a pathway could be traced in detail in non-microbial systems.
View Article and Find Full Text PDFThe critical micelle concentrations (CMCs) of several imidazolium-based ionic liquids (ILs) in aqueous HO (50 wt % in HO) were determined by tensiometry, conductometry, and the rate of catalytic epoxidation of -cyclooctene. CMC values in aqueous HO were significantly lower compared to values in pure water. In both HO solution and water, the CMC of all ILs decreases with an increasing alkyl chain length and increases with a rising temperature.
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