Hydrogenated amorphous silicon (a-Si:H)-based infrared photodiodes were fabricated by coating a-Si:H thin-film p-i-n layers over hydrothermally-synthesized disordered zinc oxide (ZnO) nanowire (NW) networks. Due to enhanced light scattering, the reversed biased three dimensional (3-D) radial-junction NW diodes showed an ∼10× increase in photocurrent under a broad spectrum (800-2000 nm) infrared (IR) illumination compared to planar devices. The diodes were optimized by using InGaZnO (IGZO) transparent top contacts that had 20% higher optical transmission in the IR compared to Al-doped ZnO electrodes.
View Article and Find Full Text PDFIn this paper, the size-dependent optical and electrical properties of 365 nm InGaN/AlGaN ultraviolet micron-size light-emitting diodes (μLEDs) on c-plane sapphire substrates is investigated. The series resistance of the μLED increased from 20 Ω to 15 kΩ when the diameter of the device decreased from 150 to 3 μm. The ideality factor increased from 4 to 4.
View Article and Find Full Text PDFIn this work, the successful integration of a-Si:H thin-film transistors (TFTs) and high-efficiency μ-iLEDs on large-area flexible substrates has been demonstrated. A conventional low-temperature a-Si:H TFT fabrication process combined with a laser lift-off transfer procedure was used to integrate μ-iLEDs with flexible TFT pixel circuits. Electrical and optical characterization showed the current-voltage and electroluminescence characteristics of the TFTs and LEDs did not change after integration onto the flexible platforms.
View Article and Find Full Text PDFSilver nanowires in conjunction with sputter-coated Al-doped ZnO (AZO) thin films were used as a composite transparent top electrode for hybrid radial-junction ZnO nanowire/a-Si:H p-i-n thin-film solar cells. Solar cells with the composite nanowire top contacts attained a short-circuit current density (J) of 13.9 mA/cm and a fill factor (FF) of 62% on glass substrates while a J of 13.
View Article and Find Full Text PDFManipulation of nanoliter droplets is a key step for many emerging technologies including ultracompact microfluidics devices, 3D and flexible electronic printing. Despite progress, contamination-free generation and release of nanoliter droplets by compact low-cost devices remains elusive. In the present study, inspired by butterflies' minute manipulation of fluids, the authors have engineered a superamphiphobic bionic proboscis (SAP) layout that surpasses synthetic and natural designs.
View Article and Find Full Text PDFEngineering surface textures that are highly transparent and repel water, oil, and other low surface energy fluids can transform our interaction with wet environments. Despite extensive progress, current top-down methods are based on directional line-of-sight fabrication mechanisms that are limited by scale and cannot be applied to highly uneven, curved, and enclosed surfaces, while bottom-up techniques often suffer from poor optical transparency. Here, we present an approach that enables the rapid, omnidirectional synthesis of flexible and up to 99.
View Article and Find Full Text PDFIn nature, durable self-cleaning surfaces such as the Lotus leaf rely on the multiscale architecture and cohesive regenerative properties of organic tissue. Real-world impact of synthetic replicas has been limited by the poor mechanical and chemical stability of the ultrafine hierarchical textures required for attaining a highly dewetting superhydrophobic state. Here, we present the low-cost synthesis of large-scale ultradurable superhydrophobic coatings by rapid template-free micronano texturing of interpenetrated polymer networks (IPNs).
View Article and Find Full Text PDFDisordered 3-D hybrid ZnO nanowire/a-Si:H thin-film radial-junction solar cells are directly fabricated onto flexible substrates. A 41% reduction in optical reflectivity resulted in a 15% increase in the current density when the substrate is mechanically bent concave-up toward the incoming light. The light scattering of the nanowire devices was enhanced by decreasing the spacing between the nanowire solar cell by bending the substrate.
View Article and Find Full Text PDFSuperhydrophobic materials with excellent humidity tolerance, high porosity and light transmittance are being investigated for numerous applications including moisture-sensitive catalysts and perovskite solar cells. Here, we report the one-step solvent-free synthesis of ultraporous superhydrophobic nano-layers by the on-the-fly functionalization of nanoparticle aerosols. Short exposure of surfaces to hot Mn3O4, ZnO and TiO2 aerosols results in ultraporous nanoparticle networks with repulsive dewetting state approaching ideal Cassie-Baxter superhydrophobicity.
View Article and Find Full Text PDFWe experimentally demonstrate a new optical platform by integrating hydrogenated amorphous silicon nanowire arrays with thin films deposited on transparent substrates like glass. A 535 nm thick thin film is anisotropically etched to fabricate vertical nanowire arrays of 100 nm diameter arranged in a square lattice. Adjusting the nanowire length, and consequently the thin film thickness permits the optical properties of this configuration to be tuned for either transmission filter response or enhanced broadband absorption.
View Article and Find Full Text PDFThe optics of core / shell nanowire solar cells was investigated. The optical wave propagation was studied by finite difference time domain simulations using realistic interface morphologies. The interface morphologies were determined by a 3D surface coverage algorithm, which provides a realistic film formation of amorphous silicon films on zinc oxide nanowire arrays.
View Article and Find Full Text PDFSilicon nanowire (SiNW) field-effect transistors (FETs) were fabricated from nanowire mats mechanically transferred from a donor growth wafer. Top- and bottom-gate FET structures were fabricated using a doped a-Si:H thin film as the source/drain (s/d) contact. With a graded doping profile for the a-Si:H s/d contacts, the off-current for the hybrid nanowire/thin-film devices was found to decrease by 3 orders of magnitude.
View Article and Find Full Text PDFDisordered silicon nanowires are diffuse optical reflectors, with reflectivity modified by the nanowire absorption. We present an analytical model which describes the reflectivity, absorption, and transmission of a nanowire mat, across a wide spectral range, and including substrate effects. The model provides the ability to predict the optical properties of other nanowire mat structures, including core/shell heterostructures.
View Article and Find Full Text PDFWe propose and demonstrate a novel approach in optical fiber design in which the optical waveguide is formed by a ring of large air holes surrounding a solid silica core. With an appropriate choice of the geometrical configuration, robust single-transverse-mode propagation with a record effective area of 1417 microm2, verified by various methods, was demonstrated. A breakthrough was made toward the development of practical ultra-high-power fiber lasers as we observed negligible loss of the fiber at bending diameters as small as 15 cm.
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