Several analytical methods have been developed for analyzing alcohol ethoxylates (AE) in aqueous environmental samples. These methods differ widely in their selectivity and sensitivity for measuring the AE components; that is, they vary in their resolution of alkyl chain length homologs and ethoxymer distributions (degree of ethoxylation for each homolog). Given these differences, AE monitoring results from different studies often are inconsistent and, sometimes, are deemed to be incomparable.
View Article and Find Full Text PDFThe concentrations and removal rate of Triclosan, an antibacterial ingredient in consumer products, were measured at advanced trickling filter (TF) and activated sludge (AS) wastewater treatment plants (WWTPs) in the River Aire basin in the UK in September 2000. Additionally, the in-stream removal of Triclosan was measured directly in Mag Brook, the stream receiving the treated effluent from the TF plant, using a fluorescent dye tracer to determine the water plug travel times. The in-stream removal of the dissolved and un-ionized (i.
View Article and Find Full Text PDFThe concentrations and removals of 16 fragrance materials (EMs) were measured in 17 U.S. and European wastewater treatment plants between 1997 and 2000 and were compared to predicted values.
View Article and Find Full Text PDFThe objective of this study was to investigate the fate and removal of triclosan (TCS; 5-chloro-2-[2,4-dichloro-phenoxy]-phenol), an antimicrobial agent used in a variety of household and personal-care products, in wastewater treatment systems. This objective was accomplished by monitoring the environmental concentrations of TCS, higher chlorinated derivatives of TCS (4,5-dichloro-2-[2,4-dichloro-phenoxy]-phenol [tetra II]; 5,6-dichloro-2-[2,4-dichloro-phenoxy]-phenol [tetra III]; and 4,5,6-trichloro-2-(2,4-dichloro-phenoxy)-phenol [penta]), and a potential biotransformation by-product of TCS (5-chloro-2-[2,4-dicholoro-phenoxy]-anisole [TCS-OMe]) during wastewater treatment. These analytes were isolated from wastewater by using a C18 solid-phase extraction column and from sludge with supercritical fluid CO2.
View Article and Find Full Text PDF