Publications by authors named "William A Carole"
Article Synopsis
- The review covers the synthesis, characterization, and structural behavior of palladium acetate in both liquid and solid forms.
- It compares the catalytic activities of pure palladium acetate with two common byproducts: Pd3(OAc)5(NO2) and polymeric [Pd(OAc)2]n.
- The minireview aims to provide a quick reference for researchers and industry professionals working with palladium acetate.
Commercially available palladium acetate often contains two major impurities, whose presence can impact the overall catalytic efficacy. This systematic study provides a comparison of the differences in catalytic activity of pure palladium acetate, Pd3(OAc)6, with the two impurities: Pd3(OAc)5(NO2) and polymeric [Pd(OAc)2]n in a variety of cross-coupling reactions. The solid state (13)C NMR spectra of all three compounds in conjunction with DFT calculations confirm their reported geometries.
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