Ionic Strength-Dependent Assembly of Polyelectrolyte-Nanoparticle Membranes via Interfacial Complexation at a Water-Water Interface.

Complexation between oppositely charged nanoparticles (NPs) and polyelectrolytes (PEs) is a scalable approach to assemble functional, stimuli-responsive membranes. Complexation at interfaces of aqueous two-phase systems (ATPSs) has emerged as a powerful method to assemble these functional structures. Membranes formed at these interfaces can grow continuously to thicknesses approaching several millimeters and display a high degree of tunability via modification of solution properties such as ionic strength.

Micromotors Powered by Enzyme Catalysis.

Active biocompatible systems are of great current interest for their possible applications in drug or antidote delivery at specific locations. Herein, we report the synthesis and study of self-propelled microparticles powered by enzymatic reactions and their directed movement in substrate concentration gradient. Polystyrene microparticles were functionalized with the enzymes urease and catalase using a biotin-streptavidin linkage procedure.