Mechanical and Antimicrobial Properties of the Graphene-Polyamide 6 Composite.

This paper presents the synthesis and characterization of graphene-polymer composites, focusing on their mechanical and antibacterial properties. Graphene flakes were obtained via an electrochemical method and integrated into polyamide 6 (PA6) matrices using melt intercalation. Various characterization techniques confirmed the quality of the graphene flakes, including X-ray diffraction (XRD), Raman spectroscopy, and infrared (IR) spectroscopy, as well as scanning and transmission electron microscopy (SEM and TEM) imaging.

High luminous efficiency and high saturation threshold in highly transparent LuAG:Ce phosphor ceramics for laser diodes lighting.

LuAlO:Ce (LuAG:Ce) phosphor ceramics (PCs) with the excellent thermal stability and high saturation threshold are considered as the best green-fluorescent converters for high-power laser diodes (LDs) lighting. In this study, the effects of sintering additives and sintering processes on the transmittance and microstructure of LuAG:Ce PCs were systematically studied, and the luminescence performance of ceramics with different transmittance was compared. LuAG:Ce PCs with the transmittance of 80% (@800 nm, 1.

High luminous efficiency and excellent thermal performance in rod-shaped YAG:Ce phosphor ceramics for laser lighting.

High power and high brightness laser lighting puts forward new requirements for phosphor converters such as high luminous efficiency, high thermal conductivity and high saturation threshold due to the severe thermal effect. The structure design of phosphor converters is proposed as what we believe to be a novel strategy for less heat production and more heat conduction. In this work, the rod-shaped YAG:Ce phosphor ceramics (PCs) and disc-shaped YAG:Ce PCs as control group were fabricated by the gel casting and vacuum sintering, to comparatively study the luminescence performance for LD lighting, on the premise that the total number of transverse Ce ions and the volume of samples from two comparison groups were same.

Laminated structural AlO/YAG:Ce composite ceramic phosphor with high front light emission for transmissive laser lighting.

The realization of high front light emission in laser lighting under transmissive modes is heavily constrained by low thermal stability and light extraction efficiency of color converter materials. Therefore, it is necessary to improve the heat dissipation capacity and light utilization efficiency of the color converter through appropriate microstructural adjustments. In this study, what we believe to be a novel laminated structure consisting of AlO and YAG:Ce was designed and fabricated for transmissive laser lighting.

Effect of the Addition of Graphene Flakes on the Physical and Biological Properties of Composite Paints.

In this study, graphene flakes were obtained using an electrolytic method and characterized using X-ray diffraction (XRD), Raman and FTIR spectroscopy, scanning and transmission electron microscopy (SEM/TEM). Graphene-based composites with varying concentrations of 0.5%, 1% and 3% by weight were prepared with acrylic paint, enamel and varnish matrices.

Broad Luminescence Generated by IR Laser Excitation from CsPbBr:Yb Perovskite Ceramics.

This paper demonstrates the generation of broadband emission in the visible and infrared ranges induced by a concentrated beam of infrared radiation from CsPbBr ceramics doped with Yb ions. The sample was obtained by the conventional solid-state reaction method, and XRD measurements confirmed the phase purity of the material crystallizing in the orthorhombic system. Spectroscopic measurements required further sample preparation in the form of ceramics using a high-pressure press.

Optimization of the Electrochemical Method of Obtaining Graphene Nanoplatelets (GNPs).

Graphene nanoplatelets (GNPs) were prepared using the electrolytic exfoliation method on graphite foil in an ammonium sulfate solution. A series of experiments were conducted in order to optimize the production of the flakes by varying the pH of the solution, applied voltage and current, duration of electrolysis, temperature in the electrolytic system, and type and duration of the ultrasound interaction. The quality of the produced graphene nanoplatelets was analyzed using X-ray diffraction, Raman and IR spectroscopy, and TEM.

Laser induced white emission generation from LaNdAlO nanocrystals.

The synthesis and structural characteristics of nanocrystalline LaAlO perovskites doped with different concentrations of Nd ions are reported. Their excitation and Stokes emission spectra, in which significant concentration quenching was observed, were recorded and characterized. The measurements of anti-Stokes laser induced white emission (LIWE) spectra were also performed.

Size-Dependent Persistent Luminescence of YAGG:Cr Nanophosphors.

In the current work, YAGG:Cr nanophosphors were synthesized by the Pechini method and then annealed at different temperatures in the range 800-1300 °C. The structure and morphology of the samples were characterized by X-ray Powder Diffraction (XRPD). The lattice parameters and average crystalline sizes as site occupation by Al and Ga ions were calculated from the Rietveld refinement data.

High-resolution deposition of conductive and insulating materials at micrometer scale on complex substrates.

Additive manufacturing transforms the landscape of modern microelectronics. Recent years have witnessed significant progress in the fabrication of 2D planar structures and free-standing 3D architectures. In this work, we present a much-needed intermediary approach: we introduce the Ultra-Precise Deposition (UPD) technology, a versatile platform for material deposition at micrometer scale on complex substrates.

Laser-Induced Generation of Hydrogen in Water by Using Graphene Target.

A new method of hydrogen generation from water, by irradiation with CW infrared laser diode of graphene scaffold immersed in solution, is reported. Hydrogen production was extremely efficient upon admixing NaCl into water. The efficiency of hydrogen production increased exponentially with laser power.

A Study of the Impact of Graphene Oxide on Viral Infection Related to A549 and TC28a2 Human Cell Lines.

Graphene has been one of the most tested materials since its discovery in 2004. It is known for its special properties, such as electrical conductivity, elasticity and flexibility, antimicrobial effect, and high biocompatibility with many mammal cells. In medicine, the antibacterial, antiviral, and antitumor properties of graphene have been tested as intensively as its drug carrying ability.

Boosting Continuous-Wave Laser-Driven Nonlinear Photothermal White Light Generation by Nanoscale Porosity.

The irradiation of an optically absorptive medium by a continuous-wave (CW) near-infrared (NIR) laser can result in a spectral continuum emission covering both the visible and NIR regions, which is attractive for applications as continuum light sources in diverse fields. It is shown here that this NIR-laser-driven light emission can be effectively modulated with nanoscale architecture in the medium. By using porous silica as the model matrix and Yb ions as the photothermally active centers, up to 100 folds increment in NIR-laser-induced emission intensity and dramatic decrease in threshold excitation density are demonstrated.

Laser induced visible and infrared emission of a tungsten filament.

The measurements of laser induced emission (LIE) of a tungsten filament upon irradiation with the focused beam of a CW IR laser diode are reported. It was found that the emission occurred in visible and infrared range. The influence of the applied DC electric field significantly affected the intensity of LIE of the tungsten filament.

Laser-Induced Hydrogen Generation from Methanol with Graphene Aerogel as the Target.

The present work demonstrates a new concept of the efficient generation of hydrogen from methanol by the continuous wave laser diode irradiation of an immersed graphene aerogel (GA) scaffold as the target. It was observed that the process occurred very intensively when it was assisted by bright white light emission in the spot of a laser-irradiated GA scaffold. The yield of hydrogen emission increased exponentially with the applied laser power.

Gallato Zirconium (IV) Phtalocyanine Complex Conjugated with SiO2 Nanocarrier as a Photoactive Drug for Photodynamic Therapy of Atheromatic Plaque.

A new conjugate of gallato zirconium (IV) phthalocyanine complexes (PcZrGallate) has been obtained from alkilamino-modified SiO nanocarriers (SiO-(CH)-NHNPs), which may potentially be used in photodynamic therapy of atherosclerosis. Its structure and morphology have been investigated. The photochemical properties of the composite material has been characterized.

Studies of graphene influence on the laser induced white emission spectra of SrCeO/graphene flake composites.

The Stokes and anti-Stokes emission spectra generated from Sr2CeO4/graphene flake composites were investigated. The excitation and emission spectra, decay profiles and quantum efficiency of the studied materials were collected. It was found that the addition of graphene flakes (GFs) significantly affects spectroscopic properties.

Magnetic Properties of LaAMnO (A: Li, Na, K) Nanopowders and Nanoceramics.

Nanocrystalline LaAMnO (where A is Li, Na, K) powders were synthesized by a combustion method. The powders used to prepare nanoceramics were fabricated via a high-temperature sintering method. The structure and morphology of all compounds were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM).

Ferromagnetic-like behavior of BiLaFeO-KBr nanocomposites.

We studied magnetostatic response of the BiLaFeO- KBr composites (BLFO-KBr) consisting of nanosized (≈100 nm) ferrite BiLaFeO (BLFO) conjugated with fine grinded ionic conducting KBr. When the fraction of KBr is rather small (less than 15 wt%) the magnetic response of the composite is very weak and similar to that observed for the BLFO (pure KBr matrix without BiLaFeO has no magnetic response as anticipated). However, when the fraction of KBr increases above 15%, the magnetic response of the composite changes substantially and the field dependence of magnetization reveals ferromagnetic-like hysteresis loop with a remanent magnetization about 0.

Biocompatible Carbon-Based Coating as Potential Endovascular Material for Stent Surface.

Stainless steel 316L is a material commonly used in cardiovascular medicine. Despite the various methods applied in stent production, the rates of in-stent restenosis and thrombosis remain high. In this study graphene was used to coat the surface of 316L substrate for enhanced bio- and hemocompatibility of the substrate.

Shaping Luminescent Properties of Yb and Ho Co-Doped Upconverting Core-Shell β-NaYF Nanoparticles by Dopant Distribution and Spacing.

At the core of luminescence color and lifetime tuning of rare earth doped upconverting nanoparticles (UCNPs), is the understanding of the impact of the particle architecture for commonly used sensitizer (S) and activator (A) ions. In this respect, a series of core@shell NaYF UCNPs doped with Yb and Ho ions are presented here, where the same dopant concentrations are distributed in different particle architectures following the scheme: YbHo core and YbHo@…, …@YbHo, Yb@Ho, Ho@Yb, YbHo@Yb, and Yb@YbHo core-shell NPs. As revealed by quantitative steady-state and time-resolved luminescence studies, the relative spatial distribution of the A and S ions in the UCNPs and their protection from surface quenching has a critical impact on their luminescence characteristics.

Laser induced white lighting of graphene foam.

Laser induced white light emission was observed from porous graphene foam irradiated with a focused continuous wave beam of the infrared laser diode. It was found that the intensity of the emission increases exponentially with increasing laser power density, having a saturation level at ca. 1.

Antimicrobial graphene family materials: Progress, advances, hopes and fears.

Graphene-based materials have become very popular bionanotechnological instruments in the last few years. Since 2010, the graphene family materials have been recognized as worthy of attention due to its antimicrobial properties. Functionalization of graphene (or rather graphene oxide) surface creates the possibilities to obtain efficient antimicrobial agents.

Optically stimulated persistent luminescence of europium-doped LaAlO3 nanocrystals.

Optically stimulated persistent luminescence was investigated for europium-doped LaAlO3 nanocrystals. This system shows conventional luminescence of both the Eu(3+) line emission and the weak broad-band emission of Eu(2+) upon UV excitation. The persistent luminescence is predominantly associated with the Eu(3+) emission, and can be amplified significantly through irradiation with IR at 975 nm.