On the Performance of a Ready-to-Use Electrospun Sulfonated Poly(Ether Ether Ketone) Membrane Adsorber.

Motivated by the need for efficient purification methods for the recovery of valuable resources, we developed a wire-electrospun membrane adsorber without the need for post-modification. The relationship between the fiber structure, functional-group density, and performance of electrospun sulfonated poly(ether ether ketone) (sPEEK) membrane adsorbers was explored. The sulfonate groups enable selective binding of lysozyme at neutral pH through electrostatic interactions.

Theoretical Study of the Reaction of Hydrogen Atoms with Three Pentene Isomers: 2-Methyl-1-butene, 2-Methyl-2-butene, and 3-Methyl-1-butene.

This paper presents a comprehensive potential energy surface (PES) for hydrogen atom addition to and abstraction from 2-methyl-1-butene, 2-methyl-2-butene, and 3-methyl-1-butene and the subsequent ß-scission and H atom transfer reactions. Thermochemical parameters for species on the ĊH potential energy surface (PES) were calculated as a function of temperature (298-2000 K), using a series of isodesmic reactions to determine the formation enthalpies. High-pressure limiting and pressure-dependent rate constants were calculated using Rice-Ramsperger-Kassel-Marcus theory with a one-dimensional master equation.