CsPbI perovskite nanocrystals (NCs) are gaining popularity as promising photoactive materials for optoelectronic devices. However, their poor phase stability has caused substantial limitations in their practical application. Herein, the small-sized rare earth La cation is strategically introduced to fundamentally improve the NC phase stability against the environment, heat, and UV radiation by the partial substitution of Pb ions to suppress structural distortion and increase the formation energy.
View Article and Find Full Text PDFQuasi-two-dimensional (quasi-2D) perovskite has exhibited great potential to be an ideal luminescent material for perovskite light-emitting diodes (PeLEDs). However, the low-order phases (especially = 1 phase) and the inevitable defects result in massive nonradiative recombination and poor emission efficiency. Herein, a multifunctional molecule of tetrabutylammonium dihydrogen phosphate (TDP) is introduced to simultaneously suppress the low- phase, passivate the defects, and increase the exciton binding energy of the quasi-2D perovskite for massive radiative recombination and thus high emission efficiency.
View Article and Find Full Text PDFAlthough all-inorganic perovskite materials present multiple fascinating optical properties, their poor stability undermines their potential application in the field of multi-color display. Herein, spatially confined CsPbBr nanocrystals are in situ crystallized within uniform mesoporous SiO nanospheres (MSNs) to regulate their size distribution, passivate their surface defects, shield them from water/oxygen, and more importantly, enhance their thermotolerance. As a result, the remnant PL intensity of the prepared spatially confined perovskite (CsPbBr ) nanocrystals by in situ crystallization within uniform mesoporous SiO nanospheres (SCP@MSNs) powders can be maintained over 98% of its initial value even after being immersed in harsh conditions (0.
View Article and Find Full Text PDFAll-inorganic perovskite quantum dots (PQDs), potentially applicable to high-performance display technologies, are facing challenges when the superior luminescence properties with high stability and uncompromised electrical conductivity are combined. Here, by introducing hexylamine sulfate and reducing the reaction rate, we managed to optimize the surface sacrificial coating of CsPbBr QDs. As a result, the colloidal PQDs show a photoluminescence quantum efficiency (PLQE) of 95.
View Article and Find Full Text PDFAm J Hosp Palliat Care
February 2021
Objective: The aim of this study was to understand the attitudes of front-line clinical nurses toward hospice care in the fight against the COVID-19 pandemic, to provide a source of reference for hospice care education and training in hospitals treating patients with COVID-19.
Method: Front-line nurses from a designated COVID-19 hospital in Wuhan, China, participated. Participants completed the Chinese versions of the General Information Questionnaire, the Frommelt Attitudes Toward Care of the Dying Scale, the Jefferson Scale of Empathy, and the General Self-Efficacy Scale.
Backgrounds: The aim of the research was to investigate the factors contributing to cognitive dysfunction in type 2 diabetic patients, to distinguish the complex relationship between diabetic retinopathy (DR) and different cognitive status.
Methods: Two hundred and ninety-seven type 2 diabetes mellitus (T2DM) patients were enrolled in our study. We adopted the Clinical Dementia Rating (CDR), Mini-mental State Examination (MMSE) and Montreal Cognitive Assessment (MOCA) to evaluate the cognitive function.