To address the problems of unstable efficiency, long treatment period, and high energy consumption during microplastics (MPs) removal by traditional coagulation-flotation technology, a gel coagulation-spontaneous flotation (GCSF) process is proposed that employs laminarin (LA) as the crosslinker and polyaluminum chloride (PAC)/polyaluminum ferric chloride (PAFC) as the coagulant to remove MPs. Herein, the effects of GCSF chemical conditions on microplastic-humic acid composite pollutants (MP-HAs) removal were investigated, and the removal mechanisms were analyzed through theoretical calculations and floc structure characterization. Results showed that an LA to PAC/PAFC ratio of 2.
View Article and Find Full Text PDFThe long-term effects of oxytetracycline (OTC) with a high concentration on the anaerobic ammonium oxidation (Anammox) process were evaluated, and the role of static magnetic field (SMF) was further explored. The stress of OTC at 50 mg/L had little effect on the nitrogen removal of anammox process at the first 16 days. With the continuous addition of OTC and the increase of nitrogen loading, the OTC inhibited the nitrogen removal and anammox activity severely.
View Article and Find Full Text PDFThe gel coagulation-spontaneous flotation (GCSF) process designed in this paper mainly rely on dissolved gas in water rather than auxiliary gas equipment to achieve spontaneous flotation. Compared with the traditional coagulation-dissolved air flotation method, GCSF has more stable flotation efficiency and shorter operation cycle under conventional hydraulic conditions. In this study, the GCSF scheme was applied for surface water treatment, and its operating efficiency, mechanism of action, and environmental implications were explored systematically.
View Article and Find Full Text PDFPolyacrylamide (PAM) is the most commonly used coagulant aid in coagulation-ultrafiltration (C-UF) systems; however, its hydrolyzed monomer is harmful to the human nervous system. In this study, laminarin (LA), was extracted from Laminaria japonica and used as a novel coagulant aid to improve coagulation efficiency and reduce membrane fouling during the C-UF process. Optimal LA usage conditions were systematically examined and compared with those of PAM to evaluate their potential for industrial applications.
View Article and Find Full Text PDFProliferation of bla in water and wastewater is particularly concerning because of multidrug-resistance and horizontal transfer of the gene. In the present study, a pathogenic NDM-1-positive Escherichia coli strain (named E. coli NDM-1) and the bla gene were treated with titanium dioxide (TiO)/ultraviolet A (UVA) photocatalysis.
View Article and Find Full Text PDFChlorpyrifos is one of the most widely used organophosphate insecticides in agricultural production. Nevertheless, the residues of chlorpyrifos in agricultural by-product seriously threaten human health. Thus, the ultrasensitive detection of chlorpyrifos residues in agri-food products is of great demand.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
February 2022
Denitrifying phosphorus removal was realized in sequencing batch reactors using different carbon sources (acetate, propionate, and a mixture of acetate/propionate). Nutrient removal and nitrous oxide (NO) production were investigated, and the factors affecting NO production were explored. Nitrogen removal was 40.
View Article and Find Full Text PDFSilver nanoparticles (AgNPs) in surface water cause a serious threat to the health of humans and aquatic organisms. However, it is difficult to remove AgNPs completely since they could adsorb onto the surface of humic acid (HA) and meanwhile release Ag into water. In this paper, polysaccharides (Ep) were applied as a coagulant aid with polyaluminum chloride (PAC) to solve this problem.
View Article and Find Full Text PDFThis study investigated the greenhouse gas emission characteristics and microbial community dynamics with the variation of temperature during partial nitrification. Low temperature weakened nitrite accumulation, and partial nitrification would shift to complete nitrification easily at 15 °C. Based on CO equivalents (CO-eq), partial nitrification process released 2.
View Article and Find Full Text PDFStatic magnetic field (SMF) with the intensity of 15 mT was applied during partial nitrification (PN) process to evaluate the impacts on nitrogen transformation and microbial characteristics. Results showed that the startup period of PN process at ambient temperature was markedly shortened by SMF, and the nitrite accumulation increased by 18% due to SMF exposure. The ammonia oxidizing bacteria (AOB) amoA gene copy numbers in the reactor with SMF exposure were 40% higher than that without SMF exposure, indicating the AOB abundance was enriched by SMF exposure.
View Article and Find Full Text PDFThe short- and long-term influences of ferric iron (Fe(III)) on nutrients removal and nitrous oxide (N2O) emission during SNDPR process were evaluated. According to the continuous cycle experiments, it was concluded that the addition of Fe(III) could lower the nitrogen removal of the following cycle during SNDPR process, which was mainly induced by the chemical removal of phosphorus. However, the impacts were transitory, and simultaneous nitrogen and phosphorus removal would recover from the inhibition of Fe(III) after running certain cycles.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
February 2016
To evaluate the impact of chemical oxygen demand (COD)/total phosphorus (TP) ratio on microbial community characteristics during low-oxygen simultaneous nitrification and denitrification process, three anaerobic-aeration (low-oxygen) sequencing batch reactors, namely R1, R2, and R3, were performed under three different COD/TP ratios of 91.6, 40.8, and 27.
View Article and Find Full Text PDFEffect of Fe(III) concentration on nitrogen immigration and transformation and nitrous oxide emission during the simultaneous nitrification denitrification (SND) process was investigated. Higher nitrogen removal efficiency was obtained when the Fe(III) concentration was 20 mg x L(-1), while lower nitrogen removal efficiency was observed when the Fe (III) concentration turned to 60 mg x L(-1). In addition, higher Fe(III) concentration significantly enhanced the N2O emission, as well as the N2O conversion ratio.
View Article and Find Full Text PDFThis study attempts to elucidate the emission sources and mechanisms of nitrous oxide (N2O) during simultaneous nitrification and denitrification (SND) process under oxygen-limiting condition. The results indicated that N2O emitted during low-oxygen SND process was 0.8±0.
View Article and Find Full Text PDFThree laboratory scale anaerobic-aerobic (low-oxygen) SBRs (R1, R2 and R3) were conducted at different influent phosphorus concentration to evaluate the impacts of phosphorus load on nutrients removal and nitrous oxide (N₂O) emission during low-oxygen simultaneous nitrification and denitrification (SND) process. The results showed that TP and TN removals were enhanced simultaneously with the increase in phosphorus load. It was mainly caused by the enrichment of polyphosphate accumulating organisms (PAOs) under high phosphorus load and low COD/P ratio (<50), which could use nitrate/nitrite as electron acceptors to take up the phosphorus.
View Article and Find Full Text PDFSimultaneous nitrification denitrification (SND) process was achieved in a SBR system to evaluate the impacts of intracellular carbon source PHB and oxygen uptake rate (OUR) on nitrous oxide (N(2)O) emission. Compared with the sequential nitrification and denitrification (SQND) process, SND process significantly improved the nitrogen removal. N(2)O emission during SND process was much higher than the SQND process.
View Article and Find Full Text PDFHuan Jing Ke Xue
November 2009
The nitrous oxide fluxes and ammonia-oxidizing bacterium in two typical constructed wetlands, i.e. subsurface flow (SF) and free water surface (FWS) were studied by the method of static chamber-gas chromatography.
View Article and Find Full Text PDFConstructed wetlands (CWs) are considered to be important sources of nitrous oxide (N(2)O). In order to investigate the effect of influent COD/N ratio on N(2)O emission and control excess emission from nitrogen removal, free water surface microcosm wetlands were used and fed with different influent. In addition, the transformation of nitrogen was examined for better understanding of the mechanism of N(2)O production under different operating COD/N ratios.
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