Nitrogen-doped porous carbon-encapsulated copper composite for efficient reduction of 4-nitrophenol.

Developing low-cost non-precious metals as efficient catalysts for the reduction of toxic 4-nitrophenol (4-NP) to useful 4-aminophenol (4-AP) have received increasing attention in recent years. Herein, a novel and efficient Cu-based catalyst Cu/CuO@CN (carbon doped with nitrogen) was prepared via a facile method from pyrolysis of bi-ligand MOFs material Cu(BDC)(BPY) (BDC = p-Phthalic acid, BPY = 4,4'-bipyridyl) in Ar atmosphere. Characterization results revealed that N doping in carbon matrix favors the development of mesoporous structure, the formation of more defect sites in carbon matrix, better dispersion of Cu/CuO nano particles, and maintenance of Cu species in metallic Cu state (the active site), all of which contribute to a superior catalytic activity for 4-NP reduction with a pseudo-first-order rate constant as high as 0.