Realizing real-time optical molecular imaging in peripheral nerve tissue via Rhodamine B.

Background: Iatrogenic nerve injury is a consequential complication during surgery. Thus, real-time imaging of peripheral nerve (PN) possesses significant clinical implications. In recent years, the rapid advancements in optical molecular imaging (OMI) technology have provided essential technical foundations for the implementation of PN fluorescence imaging.

Ozone Doping and Negative Temperature Response in the Explosion Limits of Ethylene-Oxygen Mixtures.

In this work, effects of ozone (O) addition on ethylene-oxygen (CH-O) mixtures are computationally studied through the explosion limit profiles. The results show that the addition of minute quantities of ozone (with a mole fraction of 0.06% in the oxidizer) shifts the explosion limit of the CH-O-O mixtures to the low-temperature regime.

Plasmon-Promoted Interatomic Hot Carriers Regulation Enhanced Electrocatalytic Nitrogen Reduction Reaction.

Utilizing hot carriers for efficient plasmon-mediated chemical reactions (PMCRs) to convert solar energy into secondary energy is one of the most feasible solutions to the global environmental and energy crisis. Finding a plasmonic heterogeneous nanostructure with a more efficient and reasonable hot carrier transport path without affecting the intrinsic plasmonic properties is still a major challenge that urgently needs to be solved in this field. Herein, the mechanism by which plasmon-promoted interatomic hot electron redistribution on the surface of AuCu alloy nanoparticles promotes the electrocatalytic nitrogen reduction reaction (ENRR) is successfully clarified.

High-Power Impulse Magnetron Sputter Deposition of Ag on Self-Assembled Au Nanoparticle Arrays at Low-Temperature Dewetting Conditions.

Plasmons have facilitated diverse analytical applications due to the boosting signal detectability by hot spots. In practical applications, it is crucial to fabricate straightforward, large-scale, and reproducible plasmonic substrates. Dewetting treatment, applying direct thermal annealing of metal films, has been used as a straightforward method in the fabrication of such plasmonic nanostructures.

3D Anisotropic Au@Pt-Pd Hemispherical Nanostructures as Efficient Electrocatalysts for Methanol, Ethanol, and Formic Acid Oxidation Reaction.

Anisotropic 3D nanostructures exhibit excellent electrocatalytic activity and stability due to their heterogeneous elemental distribution and unsymmetrical configuration. However, it is still a huge challenge to combine anisotropically distributed elements and anisotropic morphologies within one 3D nanostructure. Herein, 3D Au@Pt-Pd hemispherical nanostructures (Au@Pt-Pd H-Ss) are fabricated as highly efficient electrocatalysts for oxidation reaction, which present heterogenous element distribution and anisotropic morphology.

Kinetic Study of Two-Stage Low-Temperature Heat Release in iso-Octane Autoignition.

Recognizing that low-temperature ignition of alkanes is usually associated with one heat release peak, we report herein that, for iso-octane under certain ranges of initial temperatures and pressures, two separate heat release peaks were observed through computational simulations using several kinetic mechanisms. The inherent chemical reason for this phenomenon is discussed using reaction channel analysis and is identified to result from the competition between R + O → RO and the β scission reactions. By further utilizing sensitivity and path flux analyses, an isomeric effect is identified in that the different isomeric structures produced through the H-abstraction reactions can lead to differences in the subsequent low-temperature reaction pathways.

Three-Phase Electrolysis by Gold Nanoparticle on Hydrophobic Interface for Enhanced Electrochemical Nitrogen Reduction Reaction.

Electrochemical nitrogen reduction reaction (NRR) provides a facile and sustainable strategy to produce ammonia (NH) at ambient conditions. However, the low NH yield and Faradaic efficiency (FE) are still the main challenges due to the competitive hydrogen evolution reaction (HER). Herein, a three-phase electrocatalyst through in situ fabrication of Au nanoparticles (NPs) located on hydrophobic carbon fiber paper (Au/o-CFP) is designed.

Plasmonic Nanoparticle Film for Low-Power NIR-Enhanced Photocatalytic Reaction.

Plasmonic metal nanostructures offer the unique ability to effectively enhance sunlight harvesting by localized surface plasmon resonance (LSPR), which can induce direct photocatalytic reactions. However, only metal nanoparticles with a relatively low magnitude of electromagnetic field enhancement usually require a high illumination intensity to ensure the catalytic performance, which greatly limits the solar photocatalytic efficiency. Herein, we designed plasmonic Au nanoparticle film with high electromagnetic field enhancement to achieve high-efficiency catalytic activity under low-power NIR light illumination.

Multiplexed Assembly of Plasmonic Nanostructures Through Charge Inversion on Substrate for Surface Encoding.

Plasmonic nanomaterials are excellent and promising building blocks for information encoding and decoding. However, the positioning of multiplexed nanomaterials into recognizable structures remains a major challenge in nanotechnology. Herein, we developed a novel method for fabricating diversified nanostructures through surface charge inversion from amino-modified substrates to carboxyl-modified ones, as well as the corresponding electrostatic-induced assembly of metal nanoparticles.

Plasmonic nanoparticle-film-assisted photoelectrochemical catalysis across the entire visible-NIR region.

Low solar light absorption and high electron-hole pair recombination are still the main challenges for solar energy conversion. Here, we design a plasmonic nanoparticle (NP)-film with a unique structure combining the advantages of a Au NP and film, which exhibits strong broadband absorption from the visible to near-infrared (NIR) wavelength range. In addition, the high density of sub-1 nm inter-particle gaps in the Au NP-film supports electromagnetic field enhancement of several orders of magnitude that greatly promotes the generation and separation of electron-hole pairs.

Clinical evaluation of IntelliPlex HCV genotyping kit for hepatitis C virus genotyping.

Genotyping of the hepatitis C virus (HCV) is crucial for determining the most efficient anti-viral therapy. The clinical sensitivity and specificity of the IntelliPlex HCV Genotyping Kit was determined by comparing the assay results of 307 specimens with the results obtained by Sanger sequencing. Out of 202 HCV-positive specimens tested, 8 samples yielded discrepant results between the IntelliPlex HCV Genotyping Kit and Sanger sequencing.

On Radical-Induced Ignition in Combustion Systems.

This article reviews recent theoretical developments on incipient ignition induced by radical runaway in systems described by detailed chemistry. Employing eigenvalue analysis, we first analyze the canonical explosion limits of mixtures of hydrogen and oxygen, yielding explicit criteria that well reproduce their characteristic Z-shaped response in the pressure-temperature plot. Subsequently, we evaluate the role of hydrogen addition to the explosion limits of mixtures of oxygen with either carbon monoxide or methane, demonstrating and quantifying its strong catalytic effect, especially for the carbon monoxide cases.

Distribution and phylogenetic analysis of Culex flavivirus in mosquitoes in China.

Culex flavivirus (CxFV) is an insect-specific virus of the genus Flavivirus. CxFV strains have been isolated from Cx. pipiens, Cx.

The association of PTPN22 rs2476601 polymorphism and CTLA-4 rs231775 polymorphism with LADA risks: a systematic review and meta-analysis.

Although the polymorphisms of PTPN22 and the variants of CTLA-4 have been reported to be the susceptibility genes, which increased risk of latent autoimmune diabetes in adults (LADA), the results remained inconclusive. The aim of this meta-analysis was to evaluate the association between the polymorphisms of two genes and LADA. We performed a systematic review by identifying relevant studies and applied meta-analysis to pool gene effects.