Preparation of bio-based flame retardants by modification of cottonseed meal with polyphosphate and boric acid and its durability to cotton fiber.

The durability and flame retardancy of cotton fabrics have been the focus of long-term research. In this paper, a method for preparing flame retardants through the direct modification of biomass was proposed, and the durable flame retardant of homologous cottonseed meal modified biomass flame retardants for cotton fabrics was achieved through biomass composition analysis and modeling. In this study, a cottonseed meal-phosphoric acid-boric acid synergistic bio-based flame retardant (CPB) was synthesized and characterized.

Ampicillin-derived carbon dots as the sensitive probe for the detection of Fe and Cu in living cells and water samples.

Water-soluble N-doped fluorescent (FL) carbon dots (ACDs) were successfully fabricated hydrothermally using ampicillin sodium as sole precursor. The produced ACDs exhibit satisfactory optical behavior, favorable photostability, and acceptable water solubility. With bright blue emission at 450 nm, the ACDs were utilized for multivariate sensing Fe and Cu based on the synergistic effect of the inner filter effect (IFE) and static quenching with detection limits of 0.

Development of an indirect ELISA for detecting Toxoplasma gondii IgG antibodies based on a recombinant TgIMP1 protein.

Toxoplasma gondii (T. gondii) is widely spread around the world, which can cause serious harm to immunosuppressed patients. Currently, the commercial test kits are poor at assessing T.

Reactive Flame-Retardant Cotton Fabric Coating: Combustion Behavior, Durability, and Enhanced Retardant Mechanism with Ion Transfer.

In recent years, we have witnessed numerous indoor fires caused by the flammable properties of cotton. Flame-retardant cotton deserves our attention. A novel boric acid and diethylenetriaminepenta (methylene-phosphonic acid) (DTPMPA) ammonium salt-based chelating coordination flame retardant (BDA) was successfully prepared for cotton fabrics, and a related retardant mechanism with ion transfer was investigated.

Research and Application Progress of Geopolymers in Adsorption: A Review.

Geopolymer is a porous inorganic material with a three-dimensional mesh structure, good mechanical properties, a simple preparation process (no sintering) and a low economic cost, and it is environmentally friendly. Geopolymer concrete has been widely used in the construction field, and many other studies have revealed that geopolymer will become one of the most promising inorganic materials with unique structure and properties. This paper provides a review of the development and current status of geopolymers and briefly explains the effects of material proportioning, experimental factors and activators on geopolymer performance.

Sustainable dyeing of ramie fiber with ternary reactive dye mixtures in liquid ammonia.

Liquid ammonia (LA) dyeing is a zero-effluent and sustainable dyeing technology investigated for textiles. In the present work, three bi-functional reactive dyes, Reactive Red 195 (R195), Reactive Yellow 145 (Y145), and Reactive Blue 194 (B194), were used to dye ramie fiber in liquid ammonia, and the dye exhaustion (%) and fixation (%) were compared with ramie fibers dyed with the same dyes in an aqueous dyeing method. Dyeing with a single reactive dye, a binary dye mixture, and a ternary dye mixture in liquid ammonia showed that all the dyes are highly compatible as they showed similar uptake.

Combination of Pre- and Post-Mercerization Processes for Cotton Fabric.

The dyeing process commonly deteriorates the luster of pre-mercerized cotton fabric, so post-mercerization processes are regularly applied to compensate for this. Herein, the influence of combining pre-mercerization with CS (caustic solution) or LA (liquid ammonia) and post-mercerization with CS or LA on the morphological structure, dyeing performance, tensile strength, and stiffness of woven cotton fabric was investigated. The crystallinity index values greatly decreased from 73.

Combination of wet fixation and drying treatments to improve dye fixation onto spray-dyed cotton fabric.

The conventional dyeing process requires a substantial amount of auxiliaries and water, which leaches hazardous colored effluents to the environment. Herein, a newly developed sustainable spray dyeing system has been proposed for cotton fabric in the presence of reactive dyes, which has the potential to minimize the textile dyeing industries environmental impact in terms of water consumption and save significant energy. The results suggest that fresh dye solution can be mixed with an alkali solution before spray dyeing to avoid the reactive dye hydrolysis phenomenon.

Thermo-Triggered In Situ Chitosan-Based Gelation System for Repeated and Enhanced Sonodynamic Therapy Post a Single Injection.

Sonodynamic therapy (SDT) by utilizing ultrasonic waves triggers the generation of reactive oxygen species (ROS) with the help of sonosensitizers to destruct deep-seated tumors has attracted great attention. However, the efficacy of SDT may not be robust enough due to the insufficient oxygen supply within solid tumors. Additionally, repeated injections and treatments, which are often required to achieve the optimal therapeutic responses, may cause additional side effects and patient incompliance.

Designing of a Phosphorus, Nitrogen, and Sulfur Three-Flame Retardant Applied in a Gel Poly--phenyleneisophthalamide Nanofiber Membrane for Advanced Safety Lithium-Sulfur Batteries.

Based on the urgent demand of non-flammable electrospun nanofiber separators and the strong adsorption to polysulfides through chemical doping in separators for Li-S cell, in this study, a phosphorus, nitrogen, and sulfur three-flame retardant (di-(2-(5,5-dimethyl-2-sulfido-1,3,2-dioxaphosphinan-2-yl)hydrazineyl)--ethylphosphinic) was synthesized and a high-performance flame-retarding poly--phenyleneisophthalamide (PMIA) membrane was successfully prepared through blend electrospinning with the flame retardant, it is regarded as a promising gel nanofiber membrane with advanced safety for the lithium-sulfur (Li-S) cell, and it was systematically explored and analyzed. It was presented that the modified PMIA electrospun membrane with the synthesized flame retardant possessed excellent flame retardation, outstanding thermal stability, and good mechanical strength. Meanwhile, the prepared membrane showed extraordinarily high uptake and preserving retention of the liquid electrolyte and enhanced ionic conductivity.

Intramolecular Arylation of Tertiary Enamides through Pd(OAc)-Catalyzed Dehydrogenative Cross-Coupling Reaction: Construction of Fused N-Heterocyclic Scaffolds and Synthesis of Isoindolobenzazepine Alkaloids.

Pd(OAc)-catalyzed intramolecular dehydrogenative cross-coupling reaction between tertiary enamides, which were derived from the condensation of 2-arylethylamines and methyl o-acetylbenzoate, and arenes enabled synthesis of 7,8-dihydro-5 H-benzo[4,5]azepino[2,1- a]isoindol-5-one derivatives under mild conditions. The synthetic method was applied in the total synthesis of aporhoeadane alkaloids palmanine, lennoxamine, and chilenamine in only three or four steps.

Synthesis of 2,3-Dihydro-1H-azepine and 1H-Azepin-2(3H)-one Derivatives From Intramolecular Condensation between Stable Tertiary Enamides and Aldehydes.

A new strategy to construct 2,3-dihydro-1H-azepine and 1H-azepin-2(3H)-one heterocyclic rings is reported based on emerging tertiary enamide synthons. Under very mild conditions employing BBr3 as a Lewis acid catalyst and P2O5 as an additive, tertiary enamides that contain a formyl group underwent highly efficient and scalable intramolecular cyclic condensation to afford diverse 2,3-dihydro-1H-azepine and 1H-azepin-2(3H)-one derivatives in 71-96% yields. The reaction proceeded most probably through a nucleophilic addition of enamides to aldehyde, deprotonation, and dehydration cascade.