Construction of Dual Active-Site NH-MIL-125(Ti) for Efficient Selective Oxidation of Cyclohexylamine to Cyclohexanone Oxime.

In this work, dual active-site Ti-incorporated metal-organic frameworks (MIL-125 and NH-MIL-125) were synthesized by a simple solvothermal process and applied to prepare cyclohexanone oxime from cyclohexylamine oxidation. A low-temperature thermal calcination strategy was used for the modulation of surface properties while maintaining the crystal structure and morphology. The results demonstrated that novel bifunctional NH-MIL-125@250 °C obtained from thermal calcination possessed a large surface area with both oxygen vacancies and surface hydroxyl-active sites, promoting the adsorption and activation of cyclohexylamine and oxygen molecules, respectively.

Gender Differences in the Difficulty in Disengaging from Threat among Children and Adolescents With Social Anxiety.

There is some research showing that social anxiety is related with attentional bias to threat. However, others fail to find this relationship and propose that gender differences may play a role. The aim of this study was to investigate the gender differences in the subcomponents of attentional bias to threat (hypervigilance and difficulty in disengaging) among children and adolescents with social anxiety.

[Eco-environment and nutrient accumulation of sharptooth oak stands in southern slope of Mt. Qinling].

Based on the date from chemical analysis of 10,785 botanical and 1489 edaphic samples, the amount of nutrients accumulated in soil layer (0-60 cm) of sharptooth oak stands, the total biomass of the stands and their contents of accumulated nutrients, and the amount of litter and its contents of accumulated nutrients in southern slope of Mt. Qinling were calculated. To a certain extent, the biomass and the nutrient accumulation of the stands were increased with stand densities and stand ages from thin to high or from young to old, similar to the utilization efficiency of the stands to soil nutrient elements and the trunk canopy ratio.