Quantitative Determination the Role of the Intrabandgap States in Water Photooxidation over Hematite Electrodes.

The intrabandgap states on the hematite (α-FeO) electrodes are believed to play an important role in water photooxidation. Yet, it is not fully understood how the intrabandgap states are involved in the reaction. In this work, the intraband-gap states in water photooxidation on α-FeO electrodes are investigated by a combination of multiple (photo-) electrochemical techniques and spectroscopic methods.

Unconventional rate law of water photooxidation at TiO electrodes.

Photoelectrochemical oxidation of water over semiconductors is a promising route for the production of sustainable solar fuels. TiO water photooxidation has been intensively studied over the past 50 years, but its rate law and mechanism are still undetermined. The main challenges are that there is no appropriate reaction kinetic model currently, and that both the reaction rate constant and reactant photohole concentration/density are not readily quantified with respect to conventional chemical reactions.

Base-metal oxide semiconductor electrodes for PPCP degradation: Ti-doped α-FeO for sulfosalicylic acid oxidation as an example.

Sulfosalicylic acid is a typical pharmaceutical and personal care product with high toxicity, environmental persistence, and low biodegradability. Electrochemical oxidation has been demonstrated to be a promising way for hazardous organics treatment, but it is severely limited by the high cost and resource shortage of electrode materials. Base-metal oxide semiconductor anodes have the merits of low cost, diversity, and tunable energy levels for charge transfer, and thus may be alternatives to the electrodes for wastewater treatment.

Use of GLP1RAs and occurrence of respiratory disorders: A meta-analysis of large randomized trials of GLP1RAs.

Objectives: No large sample studies have been designed to evaluate the efficacy of glucagon-like peptide-1 receptor agonists (GLP1RAs) in the primary and secondary prevention of respiratory disorders. We aimed at evaluating the relationship between use of GLP1RAs and occurrence of 12 kinds of respiratory disorders.

Methods: Large randomized placebo-controlled trials of GLP1RAs were included.

Efficacy and safety of S-1 maintenance therapy in advanced non-small-cell lung cancer patients.

Background: Previous reports have demonstrated that S-1 has remarkable effects in the maintenance treatment of advanced non-small-cell lung cancer (NSCLC), and has less toxic and side effects than conventional drugs.

Aim: To investigate the efficacy and safety of S-1 maintenance therapy in patients with advanced NSCLC.

Methods: Ninety-four patients with NSCLC admitted to our hospital from September 2015 to April 2018 were included in the study and divided into the S-1 group (47 cases) and the gemcitabine group (47 cases) by random digital table method.

Understanding the enhanced photoelectrochemical water oxidation over Ti-doped α-FeO electrodes by electrochemical reduction pretreatment.

Water splitting using semiconductor photoelectrodes is a promising approach to solar hydrogen production. Previous studies have well-demonstrated that electrochemical reduction (ER) pretreatment of bare and Ti-doped α-Fe2O3 electrodes enhances water photooxidation efficiencies, however, the mechanism underlying this improvement remains poorly understood. In this study, this was quantitatively investigated by multiple photoelectrochemical techniques and transient absorption spectroscopy, using the doped electrodes as examples.

Catalytic Upgrading of Ethanol to n-Butanol: Progress in Catalyst Development.

Because n-butanol as a fuel additive has more advantageous physicochemical properties than those of ethanol, ethanol valorization to n-butanol through homo- or heterogeneous catalysis has received much attention in recent decades in both scientific and industrial fields. Recent progress in catalyst development for upgrading ethanol to n-butanol, which involves homogeneous catalysts, such as iridium and ruthenium complexes, and heterogeneous catalysts, including metal oxides, hydroxyapatite (HAP), and, in particular, supported metal catalysts, is reviewed herein. The structure-activity relationships of catalysts and underlying reaction mechanisms are critically examined, and future research directions on the design and improvement of catalysts are also proposed.

Charge carrier separation in nanostructured TiO2 photoelectrodes for water splitting.

There is intense interest in developing new novel nanostructured photoanodes for water splitting. It is therefore important that methods to analyze the effect of nanostructuring on water splitting yields are developed in order to rationalize the relative merits of this approach for different materials. In this study the dependence of charge separation efficiency (η(sep)) on potential during photoelectrochemical water splitting at pH 2 has been quantified in a model electrode system (nanocrystalline, mesoporous TiO2) using two independent methods.

Effect of surface Fe2O3 clusters on the photocatalytic activity of TiO2 for phenol degradation in water.

Surface modification of TiO(2) with Fe(2)O(3) clusters was made through chemisorption of ferric phthalocyaninetetracarboxylate onto TiO(2), followed by sintering in air to remove organic moiety. Solid characterization with electron paramagnetic resonance spectroscopy and other techniques showed that ferric oxides were highly dispersed on TiO(2) as a noncrystallized cluster, while TiO(2) phases remained unchanged. For phenol degradation in aerated aqueous suspension, only the sample containing less than 0.

Photocatalytic oxidation of arsenite over TiO2: is superoxide the main oxidant in normal air-saturated aqueous solutions?

TiO(2) photocatalytic oxidation (PCO) of As(III) in the normal air-saturated aqueous solutions has been widely studied. Yet no consensus has been achieved on the mechanism whether superoxide is the main oxidant, although many approaches have been taken. (Photo)electrochemical method can minimize changes to TiO(2) surface and could therefore not alter the normal mechanism.

[C2H4 reducing facility for controlled ecological life support system].

Objective: To develop an experimental facility for reducing C2H4 produced by plants' growing in the controlled ecological life support system (CELSS).

Method: Based on technical parameters and performance requirements, project planning, design drawing, fabrication, and debug were conducted. Then, an experimental test for reducing C2H4 was done by measuring the content of C2H4 in gases between the inlet and the outlet of the facility.

Characteristics of MnO2 catalytic ozonation of sulfosalicylic acid and propionic acid in water.

The characteristics of different types of MnO(2) catalytic ozonation of sulfosalicylic acid (SSal) and propionic acid (PPA) have been investigated in this paper. The experimental results show the dependence of catalytic activity of MnO(2) on organic compounds and the pH of solutions, but it is independent on the type of MnO(2). For example, three types of MnO(2) have not any catalytic activity when ozonation of PPA under the condition of this experiment.