Thermoelectric Property Enhancement of Tellurium Nanowires by Surface Passivation.

The pursuit of high-performance thermoelectric materials is of paramount importance in addressing energy sustainability and environmental concerns. Here, we explore the multifaceted impact of sulfur passivation in the matrix of tellurium nanowires (TeNWs), encompassing environmental control, thermoelectric properties, and charge carrier mobility. In this study, we present the facile production of TeNWs using an aqueous solution synthesis approach.

Blocking Metallothionein-2 Expression by Copper-Doped Carbon Dots Induces Cellular Antioxidant System Collapse for Antitumor Therapy.

The insufficient antioxidant reserves in tumor cells play a critical role in reactive oxygen species (ROS)-mediated therapeutics. Metallothionein-2 (MT-2), an intracellular cysteine-rich protein renowned for its potent antioxidant properties, is intricately involved in tumor development and correlates with a poor prognosis. Consequently, MT-2 emerges as a promising target for tumor therapy.

Novel L-(CaP-ZnP)/SA Nanocomposite Hydrogel with Dual Anti-Inflammatory and Mineralization Effects for Efficient Vital Pulp Therapy.

Background: Vital pulp therapy (VPT) is considered a conservative treatment for preserving pulp viability in caries and trauma-induced pulpitis. However, Mineral trioxide aggregate (MTA) as the most frequently used repair material, exhibits limited efficacy under inflammatory conditions. This study introduces an innovative nanocomposite hydrogel, tailored to simultaneously target anti-inflammation and dentin mineralization, aiming to efficiently preserve vital pulp tissue.

Revisited and innovative perspectives of oral ulcer: from biological specificity to local treatment.

Mouth ulcers, a highly prevalent ailment affecting the oral mucosa, leading to pain and discomfort, significantly impacting the patient's daily life. The development of innovative approaches for oral ulcer treatment is of great importance. Moreover, a deeper and more comprehensive understanding of mouth ulcers will facilitate the development of innovative therapeutic strategies.

A hypoxia-activatable theranostic agent with intrinsic endoplasmic reticulum affinity and type-I photosensitivity.

A unique photosensitizer (PS), ERPS, with intrinsic endoplasmic reticulum (ER)-targeting ability and low oxygen-depletion type-I photosensitivity, is developed and used as a scaffold to construct an activatable theranostic agent for precise photodynamic therapy (PDT). The ER-targeted feature coupled with type-I photosensitivity endows ERPS with high phototoxicity toward tumor cells under both normoxic and hypoxic conditions. In addition, caging the phenol group of ERPS with a nitroreductase-sensitive triggering group provided a hypoxia-activatable PS (ERPSIm) that is encapsulated within a polymeric micelle to obtain a water-stable Im@NP nanoparticle for applications.

Reconfigurable spot size converter for the silicon photonics integrated circuit.

Spot size converter (SSC) plays a role of paramount importance in the silicon photonics integrated circuit. In this article, we report the design of a reconfigurable spot size converter used in the hybrid integration of a DFB laser diode with a silicon photonic waveguide. Our SSC consists of subwavelength gratings and thermal phase shifters.

Core bacterial community driven the conversion of fulvic acid components during composting with adding manganese dioxide.

Here, we revealed the effects of microbes on fulvic acid (FA) formation in composting by adding MnO. The results showed that the MnO promoted the formation of highly humified components (79.2% increased for component 2, and 45.

Factoring distinct materials and nitrogen-related microbes into assessments of nitrogen pollution risks during composting.

The aim of this study was to evaluate nitrogen pollution risks from distinct materials composting with the discrepancy of component, including chicken manure, municipal solid and straw waste (CM, MSW, SW). Results showed total nitrogen maximum mean concentrations were observed in CM (39.57 g/kg).

A Supramolecular Strategy to Engineering a Non-photobleaching and Near-Infrared Absorbing Nano-J-Aggregate for Efficient Photothermal Therapy.

The design of organic photothermal agents (PTAs) for applications face a demanding set of performance requirements, especially intense NIR-absorptivity and sufficient photobleaching resistance. J-aggregation offers a facile way to tune the optical properties of dyes, thus providing a general design platform for organic PTAs with the desired performance. Herein, we present a supramolecular strategy to build a water-stable, nonphotobleaching, and NIR-absorbing nano-PTA (J-NP) from J-aggregation of halogenated BODIPY dyes (BDP) for efficient photothermal therapy.

Halogen Effects-Induced Bright D-π-A Fluorophore as Scaffold for NIR Fluorogenic Probes with High Contrast.

Endowing fluorogenic probes with ultrahigh contrast is essential to increasing the accuracy of fluorescence sensing and imaging. Phenolate-based D-π-A fluorophores (A-D) belong to a big family of fluorophores and have attracted increasing attention in fluorogenic probe design. However, the intrinsic dilemma of weak intracellular emission of traditional A-D fluorophores resulted in low contrast during live cell imaging.

Low-threshold room-temperature continuous-wave optical lasing of single-crystalline perovskite in a distributed reflector microcavity.

Organic-inorganic halide perovskites have achieved remarkable success in various optoelectronic devices. A high-quality CHNHPbBr single-crystalline thin film has been directly grown in a micrometer gap between a pair of distributed reflectors with over 99.9% reflectivity, which naturally form a vertical cavity surface-emitting laser device with a single mode or several modes.

Universal Scaffold for an Activatable Photosensitizer with Completely Inhibited Photosensitivity.

Activatable photosensitizers (aPSs) sensitive to specific stimuli hold potential for targeting multiple disease biomarkers and are desirable for photodynamic therapy (PDT). Presented herein is the design of aPSs that can be activated and fully recover from an inhibited state in the presence of specific biomarker. A designed long-wavelength D-π-A photosensitizer, PS , with highly efficient photosensitivity for generation of O was used.

Centimeter-scale 2D perovskite (PEA)PbBr single crystal plates grown by a seeded solution method for photodetectors.

Large-sized single-crystal two-dimensional (2D) perovskites are highly desirable owing to their fundamental properties and intriguing ability to boost devices. Herein, 2-phenylethylammonium lead bromide [(PEA)PbBr] single crystals, which are a violet-light-emitting 2D perovskite material, with typical lateral sizes of about one centimeter were successfully grown using a seeded solution method. The single-crystal plates showed a well-defined shape (rectangle or hexagon), a natural thickness (300-500 μm) similar to that of conventional silicon and InP wafers, a large aspect ratio of ∼20, and a smooth surface (root mean square, ∼0.

Acetone vapour-assisted growth of 2D single-crystalline organic lead halide perovskite microplates and their temperature-enhanced photoluminescence.

We adopt an acetone vapour-assisted method to grow high quality single-crystalline microplates of two-dimensional (2D) perovskite, 2-phenylethylammonium lead bromide [(CHCHNH)PbBr]. The microplates, converted from the spin-coated films, are well-defined rectangles. Temperature dependent photoluminescence (PL) spectroscopy shows that the band gap PL is enhanced markedly with increasing temperature up to 218 K, accompanied by the quenching of the PL related to the trap states, which perhaps results from the exciton-phonon couplings.

A General Strategy Toward Highly Fluorogenic Bioprobes Emitting across the Visible Spectrum.

A general approach toward highly fluorogenic probes across the visible spectrum for various analytes offers significant potential for engineering a wide range of bioprobes with diverse sensing and imaging functions. Here we show a facile and general strategy that involves introducing a new fluorogenic mechanism in boron dipyrromethene (BODIPY) dyes, based on the principle of stimuli-triggered dramatic reduction in the electron-withdrawing capabilities of the meso-substituents of BODIPYs. The fluorogenic mechanism has been demonstrated to be applicable in various BODIPYs with emission maxima ranging from green to far red (509, 585, and 660 nm), and the synthetic strategy allows access to a panel of highly fluorogenic bioprobes for various biomolecules and enzymes (HO, HS, and protease) via introducing specific triggering motifs.

Fully Transparent Quantum Dot Light-Emitting Diode with a Laminated Top Graphene Anode.

A new method to employ graphene as top electrode was introduced, and based on that, fully transparent quantum dot light-emitting diodes (T-QLEDs) were successfully fabricated through a lamination process. We adopted the widely used wet transfer method to transfer bilayer graphene (BG) on polydimethylsiloxane/polyethylene terephthalate (PDMS/PET) substrate. The sheet resistance of graphene reduced to ∼540 Ω/□ through transferring BG for 3 times on the PDMS/PET.

Ultrasensitive Near-Infrared Photodetectors Based on a Graphene-MoTe-Graphene Vertical van der Waals Heterostructure.

Graphene and other layered materials, such as transition metal dichalcogenides, have rapidly established themselves as exceptional building blocks for optoelectronic applications because of their unique properties and atomically thin nature. The ability to stack them into van der Waals (vdWs) heterostructures with new functionality has opened a new platform for fundamental research and device applications. Nevertheless, near-infrared (NIR) photodetectors based on layered semiconductors are rarely realized.

[A brief analysis on the on-duty systems and dispatching systems in the Imperial Academy of Medicine of the Qing Dynasty].

The "on-duty systems" and "dispatching systems" in the Tai yi yuan (Imperial Academy of Medicine) of the Qing Dynasty served as the "prelude" of the medical officials to carry out their diagnoses and treatments. Mainly serving in the royal court, the "on-duty systems" included 3 sorts, viz., "specially selected on-duty", "interior on-duty" and "exterior on-duty".