The direct utilization of solar energy for the artificial photosynthesis of hydrogen peroxide (HO) provides a reliable approach for producing this high-value green oxidant. Here we report on the utility of high-entropy oxide (HEO) semiconductor as an all-in-one photocatalyst for visible light-driven HO production directly from HO and atmospheric O without the need of any additional cocatalysts or sacrificial agents. This high-entropy photocatalyst contains eight earth-abundant metal elements (Ti/V/Cr/Nb/Mo/W/Al/Cu) homogeneously arranged within a single rutile phase, and the intrinsic chemical complexity along with the presence of a high density of oxygen vacancies endow high-entropy photocatalyst with distinct broadband light harvesting capability.
View Article and Find Full Text PDFThe ivory shell (Babylonia areolata) is one of the most promising high quality marine products. However, ivory shell is susceptible to Vibrio harveyi infection during the culture period. In this study, we investigated the biochemical indicators, histological changes and transcriptomic response in the hepatopancreas of ivory shells from the PBS control group (PC) and infection group (A3) with 1 × 10 CFU/mL V.
View Article and Find Full Text PDFThe innate immunity of marine bivalves is challenged upon exposure to heat stress, especially with increases in the frequency and intensity of heat waves. TLR4 serves a classical pattern recognition receptor in recognizing pathogenic microorganisms and activating immune responses. In this study, three genes, , and , were characterized as homologs of genes in the TLR4-MyD88 signaling pathway in the selected scallop strain "Hongmo No.
View Article and Find Full Text PDFNanomaterials (Basel)
September 2022
Here, rational design electrodes are fabricated by mixing MXene with an aqueous solution of chloroauric acid (HAuCl). In order to prevent MXene from self-restacking, the groups of -OH on the surface of TiCT nanosheets underwent a one-step simultaneous self-reduction from AuCl-, generating spaces for rapid ion transit. Additionally, by using this procedure, MXene's surface oxidation can be decreased while preserving its physio-chemical properties.
View Article and Find Full Text PDFIn the past two decades, membrane technology has attracted considerable interest as a viable and promising method for water purification. Emerging organic micropollutants (EOMPs) in wastewater have trace, persistent, highly variable quantities and types, develop hazardous intermediates and are diffusible. These primary issues affect EOMPs polluted wastewater on an industrial scale differently than in a lab, challenging membranes-based EOMP removal.
View Article and Find Full Text PDFFlexible strain sensors based on 2D materials have been proven effective for wearable health monitoring devices, human motion detection, and fitness applications. These sensors are flexible, light, and user-friendly, but their sensitivity and detection range need to be enhanced. Among many 2D materials, MXene attracts much interest due to its remarkable properties, such as high electrical conductivity, excellent mechanical properties, flexibility, and good hydrophilicity.
View Article and Find Full Text PDFThe Kondo effect offers an important paradigm to understand strongly correlated many-body physics. Although under intensive study, some of the important properties of the Kondo effect, in systems where both itinerant coupling and localized coupling play significant roles, are still elusive. Here we report the evolution and universality of the two-stage Kondo effect, the simplest form where both couplings are important using single molecule transistor devices incorporating Manganese phthalocyanine molecules.
View Article and Find Full Text PDFIvory shell, Babylonia areolata, is one of the commercially important mariculture species in China and South East Asia. Survival varies in the artificial hatching and larval rearing of B. areolata.
View Article and Find Full Text PDFThe optical properties of graphene quantum dots (GQDs) were investigated theoretically. We focused on the photoinduced charge transfer and electron-hole coherence of single-layer graphene in the electronic transitions in the visible regions. Surface functionalization with donor or acceptor groups produced a red shift in the absorption spectrum, and electrons and holes were highly delocalized.
View Article and Find Full Text PDFThe small abalone Haliotis diversicolor is an economically important mollusk that is widely cultivated in Southern China. Gonad precocity may affect the aquaculture of small abalone. Polyamines, which are small cationic molecules essential for cellular proliferation, may affect gonadal development.
View Article and Find Full Text PDFExcellent field electron emission properties of a diamond/CoSi(2)/Si quantum well nanostructure are observed. The novel quantum well structure consists of high quality diamond emitters grown on bulk Si substrate with a nanosized epitaxial CoSi(2) conducting interlayer. The results show that the main emission properties were modified by varying the CoSi(2) thickness and that stable, low-field, high emission current and controlled electron emission can be obtained by using a high quality diamond film and a thicker CoSi(2) interlayer.
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