Porous Organic Polymers as Active Electrode Materials for Energy Storage Applications.

Eco-friendly and efficient energy production and storage technologies are highly demanded to address the environmental and energy crises. Porous organic polymers (POPs) are a class of lightweight porous network materials covalently linked by organic building blocks, possessing high surface areas, tunable pores, and designable components and structures. Due to their unique structural and compositional advantages, POPs have recently emerged as promising electrode materials for energy storage devices, particularly in the realm of supercapacitors and ion batteries.

Flexible ultrathin Nitrogen-Doped carbon mediates the surface charge redistribution of a hierarchical tin disulfide nanoflake electrode for efficient capacitive deionization.

Constructing pseudocapacitive electrodes with high specific capacities is indispensable for increasing the large-scale application of capacitive deionization (CDI). However, the insufficient CDI rate and cycling performance of pseudocapacitive-based electrodes have led to a decline in their use due to the corresponding volumetric expansion and contraction that occurs during long-term CDI processes. Herein, hierarchical porous SnS nanoflakes are encapsulated inside an N-doped carbon (NC) matrix to achieve efficient CDI.

Single-atom electrocatalysts templated by MOF for determination of levodopa.

To overcome the problem of incorrect levodopa (LD) dosage in the treatment of Parkinson's disease, a new analytical tool is urgently needed for accurately determining the concentration of LD in human fluids. Herein, an effective and stable sensor based on a Co-single-atomic-site catalyst (Co-SASC)-modified glassy carbon electrode (Co-SASC/GCE) was developed for the determination of LD concentration. The physicochemical characterization of Co-SASC is systematically investigated.

A robust electrochemical sensing based on bimetallic metal-organic framework mediated MoC for simultaneous determination of acetaminophen and isoniazid.

Herein, a MoC/bimetallic zeolitic imidazolate framework-modified glassy carbon electrode (MoC@BMZIFs/GCE) was established as an electrochemical sensor for the simultaneous sensitive determination of acetaminophen (APAP) and isoniazid (INZ). The apparent morphology, structural composition, and electrochemical properties were comprehensively investigated. The outstanding electrocatalytic activity and conductivity endow the sensor desirable electrochemical performance toward APAP and INZ compared to the bare GCE, such as wide linear range, low detection limit, and high selectivity.

Ratiometric electrochemical sensing based on MoC for detection of acetaminophen.

In this work, MoO2 nanoparticles were synthesized and annealed to form Mo2C nanoparticles. This is the first report of a ratiometric electrochemical sensor (R-ECS) for the detection of acetaminophen (AP), in which Mo2C is used as the sensing agent and ferrocene (FC) is used as an internal reference. FC (100 μM) is added directly to the electrolyte solution for convenient operation.

A novel electrochemical sensor for determination of hydroxyl radicals in living cells by coupling nanoporous gold layer with self-assembled 6-(Ferrocenyl) hexanethiol.

The detection of hydroxyl radicals (•OH) in live cells is significant to study its physiological and pathological roles, while it is full of challenge due to the extremely low concentration and short lifetime of •OH. Herein, we have developed a novel electrochemical sensor based on 6-(Ferrocenyl) hexanethiol (6-FcHT) self-assembled nanoporous gold layer (NPGL) modified GE (6-FcHT/NPGL/GE), which can detect the release of •OH from living cells with high sensitivity and selectivity. The superior sensitivity can stem from the unique porous architecture of NPGL, which enlarged electrode surface area and expedited electron transportation during electrochemical reactions.