Synthesis and photophysical properties of pyrrole/polycyclic aromatic units hybrid fluorophores.

A series of pyrrole/polycyclic aromatic unit hybrid fluorophores was developed by a two-stage synthetic strategy. Their central aryl-substituted pyrrole cores were constructed by a Paal-Knorr pyrrole synthesis reaction. The reaction conditions and mechanism are also discussed in detail.

Orderly arranged NLO materials based on chromophore-containing dendrons on exfoliated layered templates.

Three chromophore-containing dendrons were intercalated into montmorillonite layered silicates via an ion-exchange process. Enlarged d spacings ranging from 50 to 126 A were achieved for these novel organoclays. After the organoclays were blended with a polyimide, the steric bulkiness of the dendrons and the interaction between dendron and polyimide resulted in an ordered morphology.